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Journal of Materials Science: Materials in Electronics
Published in: Journal of Materials Science: Materials in Electronics 11/2017

07-02-2017

Density of states and impedance behaviour of transition metal substituted SrBi2Nb2O9 ferroelectric nanoceramics prepared by chemical process

Authors: Mrinal K. Adak, Debasis Dhak

Published in: Journal of Materials Science: Materials in Electronics | Issue 11/2017

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Abstract

Nanocrystalline layered perovskite Sr0.5A0.5Bi2Nb2O9 (A = Co2+, Ni2+, Cu2+) ferroelectric ceramics were synthesized through chemical process. The synthesized compounds were found to have tolerance values 0.90, 0.865 and 0.872 which are well within its limit. The electrical behaviour was thoroughly studied through impedance analysis within the temperature range between 400 °C and 500 °C after sintering the pressed pellet at 750 °C for 4h. Strong relaxation behaviour was found for Sr0.5Co0.5Bi2Nb2O9 and Sr0.5Cu0.5Bi2Nb2O9. The ac activation energy was calculated from the relaxation behaviour. All the studied samples showed grain conductivity behaviour only. The binding energy and density of states were studied with respect to temperature and frequency. The hopping behaviour was also studied and established a correlated barrier hopping model.
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Metadata
Title
Density of states and impedance behaviour of transition metal substituted SrBi2Nb2O9 ferroelectric nanoceramics prepared by chemical process
Authors
Mrinal K. Adak
Debasis Dhak
Publication date
07-02-2017
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 11/2017
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-017-6481-x

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