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Published in: Journal of Materials Engineering and Performance 12/2018

29-08-2018

Effect of Oxygen Pressure on Thermoelectric Properties of p-Type CuAlO2 Films Fabricated by Pulsed Laser Deposition

Authors: Shrikant Saini, Paolo Mele, Shunsuke Osugi, Malik I. Adam

Published in: Journal of Materials Engineering and Performance | Issue 12/2018

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Abstract

We focus on the growth of p-type CuAlO2 thin films and its thermoelectric properties. Thin films are deposited by pulsed laser deposition technique on single-crystal sapphire substrates varying the oxygen partial pressure. Thin film deposited at oxygen partial pressure of 200 mTorr presents bigger grains (about 10 μm in size) and shows Seebeck coefficient as high as 270 µV/K with a conductivity of about 0.8 S/cm so that its power factor is about 5.7 µW/mK2 at 800 K, twice than observed in the film deposited at 60 mTorr of oxygen.

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Literature
1.
go back to reference D.M. Rowe, Thermoelectrics Handbook: Macro to Nano, CRC/Taylor & Francis, Boca Raton, 2006 D.M. Rowe, Thermoelectrics Handbook: Macro to Nano, CRC/Taylor & Francis, Boca Raton, 2006
2.
go back to reference Böttner, H., 2009. Thermoelectrics for High Temperatures: A Survey of State of the Art. MRS Online Proceedings Library Archive, 1166. Böttner, H., 2009. Thermoelectrics for High Temperatures: A Survey of State of the Art. MRS Online Proceedings Library Archive, 1166.
3.
go back to reference R. Venkatasubramanian, E. Siivola, T. Colpitts, and B. O’quinn, Thin-Film Thermoelectric Devices with High Room-Temperature Figures of Merit, Nature, 2001, 413(6856), p 597CrossRef R. Venkatasubramanian, E. Siivola, T. Colpitts, and B. O’quinn, Thin-Film Thermoelectric Devices with High Room-Temperature Figures of Merit, Nature, 2001, 413(6856), p 597CrossRef
4.
go back to reference K. Koumoto, I. Terasaki, and R. Funahashi, Complex Oxide Materials for Potential Thermoelectric Applications, MRS Bull., 2006, 31(3), p 206–210CrossRef K. Koumoto, I. Terasaki, and R. Funahashi, Complex Oxide Materials for Potential Thermoelectric Applications, MRS Bull., 2006, 31(3), p 206–210CrossRef
5.
go back to reference J.W. Fergus, Oxide Materials for High Temperature Thermoelectric Energy Conversion, J. Eur. Ceram. Soc., 2012, 32(3), p 525–540CrossRef J.W. Fergus, Oxide Materials for High Temperature Thermoelectric Energy Conversion, J. Eur. Ceram. Soc., 2012, 32(3), p 525–540CrossRef
6.
go back to reference M. Ohtaki, K. Araki, and K. Yamamoto, High Thermoelectric Performance of Dually Doped ZnO Ceramics, J. Electron. Mater., 2009, 38(7), p 1234–1238CrossRef M. Ohtaki, K. Araki, and K. Yamamoto, High Thermoelectric Performance of Dually Doped ZnO Ceramics, J. Electron. Mater., 2009, 38(7), p 1234–1238CrossRef
7.
go back to reference I. Terasaki, Y. Sasago, and K. Uchinokura, Large Thermoelectric Power in NaCo2O4 Single Crystals, Phys. Rev. B, 1997, 56(20), p R12685CrossRef I. Terasaki, Y. Sasago, and K. Uchinokura, Large Thermoelectric Power in NaCo2O4 Single Crystals, Phys. Rev. B, 1997, 56(20), p R12685CrossRef
8.
go back to reference R. Funahashi and I. Matsubara, Thermoelectric Properties of Pb-and Ca-Doped (Bi2Sr2O4)x CoO2 Whiskers, Appl. Phys. Lett., 2001, 79(3), p 362–364CrossRef R. Funahashi and I. Matsubara, Thermoelectric Properties of Pb-and Ca-Doped (Bi2Sr2O4)x CoO2 Whiskers, Appl. Phys. Lett., 2001, 79(3), p 362–364CrossRef
9.
go back to reference Y. Masuda, D. Nagahama, H. Itahara, T. Tani, W.S. Seo, and K. Koumoto, Thermoelectric Performance of Bi-and Na-Substituted Ca3Co4O9 Improved Through Ceramic Texturing, J. Mater. Chem., 2003, 13(5), p 1094–1099CrossRef Y. Masuda, D. Nagahama, H. Itahara, T. Tani, W.S. Seo, and K. Koumoto, Thermoelectric Performance of Bi-and Na-Substituted Ca3Co4O9 Improved Through Ceramic Texturing, J. Mater. Chem., 2003, 13(5), p 1094–1099CrossRef
10.
go back to reference T. Itoh and I. Terasaki, Thermoelectric Properties of Bi2 3-xPbxSr2 6Co2Oy Single Crystals, Jpn. J. Appl. Phys., 2000, 39(12R), p 6658CrossRef T. Itoh and I. Terasaki, Thermoelectric Properties of Bi2 3-xPbxSr2 6Co2Oy Single Crystals, Jpn. J. Appl. Phys., 2000, 39(12R), p 6658CrossRef
11.
go back to reference S. Saini, H.S. Yaddanapudi, K. Tian, Y. Yin, D. Magginetti, and A. Tiwari, Terbium Ion Doping in Ca3Co4O9: A Step Towards High-Performance Thermoelectric Materials, Sci. Rep., 2017, 7, p 44621CrossRef S. Saini, H.S. Yaddanapudi, K. Tian, Y. Yin, D. Magginetti, and A. Tiwari, Terbium Ion Doping in Ca3Co4O9: A Step Towards High-Performance Thermoelectric Materials, Sci. Rep., 2017, 7, p 44621CrossRef
12.
go back to reference K. Park, K.Y. Ko, H.C. Kwon, and S. Nahm, Improvement in Thermoelectric Properties of CuAlO2 by Adding Fe2O3, J. Alloys Compd., 2007, 437(1–2), p 1–6CrossRef K. Park, K.Y. Ko, H.C. Kwon, and S. Nahm, Improvement in Thermoelectric Properties of CuAlO2 by Adding Fe2O3, J. Alloys Compd., 2007, 437(1–2), p 1–6CrossRef
13.
go back to reference H. Kawazoe, M. Yasukawa, H. Hyodo, M. Kurita, H. Yanagi, and H. Hosono, P-Type Electrical Conduction in Transparent Thin Films of CuAlO2, Nature, 1997, 389(6654), p 939CrossRef H. Kawazoe, M. Yasukawa, H. Hyodo, M. Kurita, H. Yanagi, and H. Hosono, P-Type Electrical Conduction in Transparent Thin Films of CuAlO2, Nature, 1997, 389(6654), p 939CrossRef
14.
go back to reference K. Koumoto, H. Koduka, and W.S. Seo, Thermoelectric Properties of Single Crystal CuAlO2 with a Layered Structure Electronic Supplementary Information (ESI) Available: Crystal Structure Of Delafossite-Type ABO2; SEM Image, XRD Patterns, ED and HRTEM Images of a CuAlO2 Single Crystal, J. Mater. Chem., 2001, 11(2), p 251–252CrossRef K. Koumoto, H. Koduka, and W.S. Seo, Thermoelectric Properties of Single Crystal CuAlO2 with a Layered Structure Electronic Supplementary Information (ESI) Available: Crystal Structure Of Delafossite-Type ABO2; SEM Image, XRD Patterns, ED and HRTEM Images of a CuAlO2 Single Crystal, J. Mater. Chem., 2001, 11(2), p 251–252CrossRef
15.
go back to reference M. Neumann-Spallart, S.P. Pai, and R. Pinto, PLD Growth of CuAlO2, Thin Solid Films, 2007, 515(24), p 8641–8644CrossRef M. Neumann-Spallart, S.P. Pai, and R. Pinto, PLD Growth of CuAlO2, Thin Solid Films, 2007, 515(24), p 8641–8644CrossRef
16.
go back to reference J.C. Lee, S.Y. Um, Y.W. Heo, J.H. Lee, and J.J. Kim, Phase Development and Crystallization of CuAlO2 Thin Films Prepared by Pulsed Laser Deposition, J. Eur. Ceram. Soc., 2010, 30(2), p 509–512CrossRef J.C. Lee, S.Y. Um, Y.W. Heo, J.H. Lee, and J.J. Kim, Phase Development and Crystallization of CuAlO2 Thin Films Prepared by Pulsed Laser Deposition, J. Eur. Ceram. Soc., 2010, 30(2), p 509–512CrossRef
17.
go back to reference H. Luo, M. Jain, T.M. McCleskey, E. Bauer, A.K. Burrell, and Q. Jia, Optical and Structural Properties of Single Phase Epitaxial p-Type Transparent Oxide Thin Films, Adv. Mater., 2007, 19(21), p 3604–3607CrossRef H. Luo, M. Jain, T.M. McCleskey, E. Bauer, A.K. Burrell, and Q. Jia, Optical and Structural Properties of Single Phase Epitaxial p-Type Transparent Oxide Thin Films, Adv. Mater., 2007, 19(21), p 3604–3607CrossRef
18.
go back to reference J.H. Shy and B.H. Tseng, Characterization of CuAlO2 Thin Film Prepared by Rapid Thermal Annealing of an Al2O3/Cu2O/Sapphire Structure, J. Phys. Chem. Solids, 2005, 66(11), p 2123–2126CrossRef J.H. Shy and B.H. Tseng, Characterization of CuAlO2 Thin Film Prepared by Rapid Thermal Annealing of an Al2O3/Cu2O/Sapphire Structure, J. Phys. Chem. Solids, 2005, 66(11), p 2123–2126CrossRef
19.
go back to reference K. Ueda, T. Hase, H. Yanagi, H. Kawazoe, H. Hosono, H. Ohta, M. Orita, and M. Hirano, Epitaxial Growth of Transparent p-type Conducting CuGaO2 Thin Films on Sapphire (001) Substrates by Pulsed Laser Deposition, J. Appl. Phys., 2001, 89(3), p 1790–1793CrossRef K. Ueda, T. Hase, H. Yanagi, H. Kawazoe, H. Hosono, H. Ohta, M. Orita, and M. Hirano, Epitaxial Growth of Transparent p-type Conducting CuGaO2 Thin Films on Sapphire (001) Substrates by Pulsed Laser Deposition, J. Appl. Phys., 2001, 89(3), p 1790–1793CrossRef
20.
go back to reference A.N. Banerjee, S. Kundoo, and K.K. Chattopadhyay, Synthesis and Characterization of p-type Transparent Conducting CuAlO2 Thin Film by DC Sputtering, Thin Solid Films, 2003, 440(1–2), p 5–10CrossRef A.N. Banerjee, S. Kundoo, and K.K. Chattopadhyay, Synthesis and Characterization of p-type Transparent Conducting CuAlO2 Thin Film by DC Sputtering, Thin Solid Films, 2003, 440(1–2), p 5–10CrossRef
21.
go back to reference A.N. Banerjee, R. Maity, P.K. Ghosh, and K.K. Chattopadhyay, Thermoelectric Properties and Electrical Characteristics of Sputter-Deposited p-CuAlO2 Thin Films, Thin Solid Films, 2005, 474(1–2), p 261–266CrossRef A.N. Banerjee, R. Maity, P.K. Ghosh, and K.K. Chattopadhyay, Thermoelectric Properties and Electrical Characteristics of Sputter-Deposited p-CuAlO2 Thin Films, Thin Solid Films, 2005, 474(1–2), p 261–266CrossRef
22.
go back to reference I. Sinnarasa, Y. Thimont, L. Presmanes, A. Barnabé, and P. Tailhades, Thermoelectric and Transport Properties of Delafossite CuCrO2: Mg Thin Films Prepared by RF Magnetron Sputtering, Nanomaterials, 2017, 7(7), p 157CrossRef I. Sinnarasa, Y. Thimont, L. Presmanes, A. Barnabé, and P. Tailhades, Thermoelectric and Transport Properties of Delafossite CuCrO2: Mg Thin Films Prepared by RF Magnetron Sputtering, Nanomaterials, 2017, 7(7), p 157CrossRef
23.
go back to reference P. Mele, S. Saini, H. Honda, K. Matsumoto, K. Miyazaki, H. Hagino, and A. Ichinose, Effect of Substrate on Thermoelectric Properties of Al-Doped ZnO Thin Films, Appl. Phys. Lett., 2013, 102(25), p 253903CrossRef P. Mele, S. Saini, H. Honda, K. Matsumoto, K. Miyazaki, H. Hagino, and A. Ichinose, Effect of Substrate on Thermoelectric Properties of Al-Doped ZnO Thin Films, Appl. Phys. Lett., 2013, 102(25), p 253903CrossRef
24.
go back to reference S. Saini, P. Mele, H. Honda, D.J. Henry, P.E. Hopkins, L. Molina-Luna, K. Matsumoto, K. Miyazaki, and A. Ichinose, Enhanced Thermoelectric Performance of Al-Doped ZnO Thin Films on Amorphous Substrate, Jpn. J. Appl. Phys., 2014, 53(6), p 060306CrossRef S. Saini, P. Mele, H. Honda, D.J. Henry, P.E. Hopkins, L. Molina-Luna, K. Matsumoto, K. Miyazaki, and A. Ichinose, Enhanced Thermoelectric Performance of Al-Doped ZnO Thin Films on Amorphous Substrate, Jpn. J. Appl. Phys., 2014, 53(6), p 060306CrossRef
25.
go back to reference S. Saini, P. Mele, H. Honda, T. Suzuki, K. Matsumoto, K. Miyazaki, A. Ichinose, L.M. Luna, R. Carlini, and A. Tiwari, Effect of Self-Grown Seed Layer on Thermoelectric Properties of ZnO Thin Films, Thin Solid Films, 2016, 605, p 289–294CrossRef S. Saini, P. Mele, H. Honda, T. Suzuki, K. Matsumoto, K. Miyazaki, A. Ichinose, L.M. Luna, R. Carlini, and A. Tiwari, Effect of Self-Grown Seed Layer on Thermoelectric Properties of ZnO Thin Films, Thin Solid Films, 2016, 605, p 289–294CrossRef
28.
go back to reference J.P. Gong, M. Kawasaki, K. Fujito, R. Tsuchiya, M. Yoshimoto, and H. Koinuma, Investigation of Precipitate Formation on Laser-Ablated YBa 2 Cu3O7 − δ Thin Films, Phys. Rev. B, 1994, 50(5), p 3280CrossRef J.P. Gong, M. Kawasaki, K. Fujito, R. Tsuchiya, M. Yoshimoto, and H. Koinuma, Investigation of Precipitate Formation on Laser-Ablated YBa 2 Cu3O7 − δ Thin Films, Phys. Rev. B, 1994, 50(5), p 3280CrossRef
29.
go back to reference P. Kofstad, Nonstoichiometry, Diffusion, and Electrical Conductivity in Binary Metal Oxides, Wiley, New York, 1972, p 19 P. Kofstad, Nonstoichiometry, Diffusion, and Electrical Conductivity in Binary Metal Oxides, Wiley, New York, 1972, p 19
30.
go back to reference V. Ponnambalam and U.V. Varadaraju, Observation of Variable-Range Hopping up to 900 K in the YLaxBa2−x Cu3O7−δ System, Phys. Rev. B, 1995, 52(22), p 16213CrossRef V. Ponnambalam and U.V. Varadaraju, Observation of Variable-Range Hopping up to 900 K in the YLaxBa2−x Cu3O7−δ System, Phys. Rev. B, 1995, 52(22), p 16213CrossRef
31.
go back to reference M. Cutler and N.F. Mott, Observation of Anderson Localization in an Electron Gas, Phys. Rev., 1969, 181, p 1336CrossRef M. Cutler and N.F. Mott, Observation of Anderson Localization in an Electron Gas, Phys. Rev., 1969, 181, p 1336CrossRef
Metadata
Title
Effect of Oxygen Pressure on Thermoelectric Properties of p-Type CuAlO2 Films Fabricated by Pulsed Laser Deposition
Authors
Shrikant Saini
Paolo Mele
Shunsuke Osugi
Malik I. Adam
Publication date
29-08-2018
Publisher
Springer US
Published in
Journal of Materials Engineering and Performance / Issue 12/2018
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-018-3601-6

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