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30-11-2023 | Original Article

Electrolyte effect on electrochemical behaviors of manganese fluoride material for aqueous asymmetric and symmetric supercapacitors

Authors: Zheng-Hua He, Jian-Fei Gao, Ling-Bin Kong

Published in: Rare Metals | Issue 3/2024

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Abstract

Exploring wide voltage window materials is not only an available measure to enhance the energy density of hybrid supercapacitor (HSCs), but also avoids the dynamic mismatch caused by different energy storage mechanisms of two electrodes in assembled symmetrical HSC. However, there are few reports about the wide potential window materials except Bi₂O₃ and VO₂. Therefore, the MnF₂ synthesized by solvothermal reaction was served as the electrode for HSC. The MnF₂ exhibited electrochemical activity in alkaline solution in three-electrode system, especially with a wide potential window from −0.8 to + 0.5 V in 2 mol·L⁻¹ NaOH. Furthermore, the assembled MnF₂//MnF₂ symmetrical HSC had a potential window of 1.5 V, and it exhibited outstanding long-cycle capability. Meanwhile, when MnF₂ was taken as the negative and positive respectively, the potential windows of asymmetric devices CoMoO₄//MnF₂ and MnF₂//Activated Carbon (AC) could reach 1.3 and 1.45 V, respectively, showing excellent cycle stability. This work shows that MnF₂ material has great research value in HSC, and provides a new research direction for developing high-performance devices.

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Title: Electrolyte effect on electrochemical behaviors of manganese fluoride material for aqueous asymmetric and symmetric supercapacitors
Authors: Zheng-Hua He
Jian-Fei Gao
Ling-Bin Kong
Publication date: 30-11-2023
Publisher: Nonferrous Metals Society of China
Published in: Rare Metals / Issue 3/2024
Print ISSN: 1001-0521
Electronic ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-023-02515-6

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