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30.11.2023 | Original Article

Electrolyte effect on electrochemical behaviors of manganese fluoride material for aqueous asymmetric and symmetric supercapacitors

verfasst von: Zheng-Hua He, Jian-Fei Gao, Ling-Bin Kong

Erschienen in: Rare Metals | Ausgabe 3/2024

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Abstract

Exploring wide voltage window materials is not only an available measure to enhance the energy density of hybrid supercapacitor (HSCs), but also avoids the dynamic mismatch caused by different energy storage mechanisms of two electrodes in assembled symmetrical HSC. However, there are few reports about the wide potential window materials except Bi₂O₃ and VO₂. Therefore, the MnF₂ synthesized by solvothermal reaction was served as the electrode for HSC. The MnF₂ exhibited electrochemical activity in alkaline solution in three-electrode system, especially with a wide potential window from −0.8 to + 0.5 V in 2 mol·L⁻¹ NaOH. Furthermore, the assembled MnF₂//MnF₂ symmetrical HSC had a potential window of 1.5 V, and it exhibited outstanding long-cycle capability. Meanwhile, when MnF₂ was taken as the negative and positive respectively, the potential windows of asymmetric devices CoMoO₄//MnF₂ and MnF₂//Activated Carbon (AC) could reach 1.3 and 1.45 V, respectively, showing excellent cycle stability. This work shows that MnF₂ material has great research value in HSC, and provides a new research direction for developing high-performance devices.

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Vorheriger Artikel Ultra-high-rate Bi anode encapsulated in 3D lignin-derived carbon framework for sodium-ion hybrid capacitors

Nächster Artikel Vertically grown MoS2 nanosheets on graphene with defect-rich structure for efficient sodium storage

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Titel: Electrolyte effect on electrochemical behaviors of manganese fluoride material for aqueous asymmetric and symmetric supercapacitors
verfasst von: Zheng-Hua He
Jian-Fei Gao
Ling-Bin Kong
Publikationsdatum: 30.11.2023
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 3/2024
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-023-02515-6

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