Top

Journal of Materials Science: Materials in Electronics

Published in:

06-04-2021

Fabrication, characterization, and malaria biomarker VOC-sensing properties of WO₃-doped polyaniline

Authors: P. Jisha, M. S. Suma, M. V. Murugendrappa, Sutar Rani Ananda

Published in: Journal of Materials Science: Materials in Electronics | Issue 8/2021

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

The polyaniline-WO₃ nanocomposite with 15% doping concentration is synthesized using in situ chemical polymerization. Structural and morphological characterizations were done using XRD, FESEM, HR-TEM, and FTIR. The bandgap energy of the synthesized nanocomposite with different doping concentrations of WO₃ was calculated using UV–Visible absorption spectra. Dielectric studies confirmed the non-Debye nature of the material. The synthesized polymer nanocomposite was used for making a spin-coated VOC sensor for the detection of 3-Carene and α-Pinene, the biomarker volatile organic compounds (VOCs) of malaria. The sensing layer was prepared by mixing polyaniline-WO₃ nanocomposite with Polyvinylidene fluoride (PVDF) using N-Methyl-2-pyrrolidone (NMP). The effect of VOCs at concentrations of 1.5 ppm, 3 ppm, and 4.5 ppm on the electrical resistance of the polymer nanocomposite films at room temperature during sensing characteristics was studied. The sensitivity and response time of the sensors with Taconic substrate were studied and by using the sensor an IoT-based portable device was developed. Sensing results confirmed that the polyaniline-WO₃ nanocomposite is suitable for making malaria biomarker VOC sensor.

previous article Investigation of cytotoxicity of superparamagnetic KFeO2 nanoparticles on MCF-7 cell lines for biomedical applications

next article Structural, optical and magnetic properties of Cd doped ZnO nanomaterials for optoelectronic device application

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 340 Zeitschriften

aus folgenden Fachgebieten:

Bauwesen + Immobilien
Business IT + Informatik
Finance + Banking
Management + Führung
Marketing + Vertrieb
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Available only for authorised users

R. Gangopadhyay, A.D. Chowdhury, A. De, Functionalized polyaniline nanowires for biosensing. Sensors Actuators, B Chem. 171–172, 777–785 (2012). https://doi.org/10.1016/j.snb.2012.05.071CrossRef

J.G. Wang, Y. Yang, Z.H. Huang, F. Kang, Interfacial synthesis of mesoporous MnO 2/polyaniline hollow spheres and their application in electrochemical capacitors. J. Power Sour. 204, 236–243 (2012). https://doi.org/10.1016/j.jpowsour.2011.12.057CrossRef

H. Kebiche, D. Debarnot, A. Merzouki, F. Poncin-Epaillard, N. Haddaoui, Relationship between ammonia sensing properties of polyaniline nanostructures and their deposition and synthesis methods. Anal. Chim. Acta. 737, 64–71 (2012). https://doi.org/10.1016/j.aca.2012.06.003CrossRef

Z. Liu, T. Yang, Y. Dong, X. Wang, A room temperature VOCs gas sensor based on a layer by layer multi-walled carbon nanotubes/poly-ethylene glycol composite. Sensors (Switzerland) (2018). https://doi.org/10.3390/s18093113CrossRef

Press, D., Polyaniline-based biosensors. 25–46 (2015)

A.Z. Berna, J.S. McCarthy, R.X. Wang, K.J. Saliba, F.G. Bravo, J. Cassells, B. Padovan, S.C. Trowell, Analysis of Breath Specimens for Biomarkers of Plasmodium falciparum Infection. J. Infect. Dis. 212, 1120–1128 (2015). https://doi.org/10.1093/infdis/jiv176CrossRef

M. Kelly, C. Su, C. Schaber, J.R. Crowley, F. Hsu, J.R. Carlson, R. Odom, Malaria parasites produce volatile mosquito attractants. MBio 6, 1–6 (2015). https://doi.org/10.1128/mBio.00235-15.EditorCrossRef

C.L. Schaber, N. Katta, L.B. Bollinger, M. Mwale, R. Mlotha-mitole, I. Trehan, B. Raman, A.R.O. John, Breathprinting reveals malaria-associated biomarkers and mosquito attractants. J. Infect. Dis 63110, 1553–1560 (2018). https://doi.org/10.1093/infdis/jiy072CrossRef

K.A. Weerakoon, N. Hiremath, B.A. Chin, Polymer-based sensor array for phytochemical detection. Sens. Agric. Food Qual. Saf. IV. 8369, 83690C-83690C (2012). https://doi.org/10.1117/12.920512CrossRef

10.

B. Chen, C. Liu, M. Watanabe, K. Hayashi, Layer-by-layer structured AuNP sensors for terpene vapor detection. IEEE Sens. J. 13, 4212–4219 (2013). https://doi.org/10.1109/JSEN.2013.2264803CrossRef

11.

B. Chen, C. Liu, X. Sun, K. Hayashi, Molecularly imprinted polymer coated Au nanoparticle sensor for α-pinene vapor detection. Proc. IEEE Sensors. (2013). https://doi.org/10.1109/ICSENS.2013.6688152CrossRef

12.

C. Bin, L. Chuanjun, H. Kenshi, Selective terpene vapor detection using molecularly imprinted polymer coated Au nanoparticle LSPR sensor. IEEE Sens. J. 14, 3458–3464 (2014)CrossRef

13.

S.P. Lee, Terpene sensor array with bridge-type resistors by CMOS technology. IOP Conf. Ser. Mater. Sci. Eng. (2015). https://doi.org/10.1088/1757-899X/87/1/012065CrossRef

14.

S. Paczkowski, T. Sauerwald, A. Weiß, M. Bauer, D. Kohl, S. Schütz, Biomimetic gas sensors for large-scale drying of wood particles. Bioinspiration, Biomimetics, and Bioreplication. 7975, 797505 (2011). https://doi.org/10.1117/12.882421CrossRef

15.

N.A. Humairah, F. Fadlunisa, K.A. Histhiningtyas, I.A. Fatyadi, R. Roto, A. Kusumaatmaja, K. Triyana, Molecular imprinting polymer-based QCM sensor for detection of α-pinene. Key Eng. Mater. 840, 418–423 (2020)CrossRef

16.

X.W. Ma, M.Q. Su, H.X. Wu, Y.G. Zhou, S.B. Wang, Analysis of the volatile profile of core Chinese mango germplasm by headspace solid-phase microextraction coupled with gas chromatography-mass spectrometry. Molecules (2018). https://doi.org/10.3390/molecules23061480CrossRef

17.

L. Haocheng, A. Kejing, S. Su, Y. Yuanshan, J. Wu, G. Xiao, Y. Xu, Aromatic characterization of mangoes ( Mangifera indica L.) using solid phase extraction coupled with gas chromatography-mass spectrometry and olfactometry and sensory analyses. Foods 9, 1–20 (2020)

18.

S.B. Ali, B. Ghatak, S.D. Gupta, N. Debabhuti, P. Chakraborty, P. Sharma, A. Ghosh, B. Tudu, S. Mitra, M.P. Sarkar, N. Bhattacharyya, R. Bandyopadhyay, Detection of 3-Carene in mango using a quartz crystal microbalance sensor. Sensors Actuators, B Chem. 230, 791–800 (2016). https://doi.org/10.1016/j.snb.2016.03.005CrossRef

19.

B. Ghatak, S.B. Ali, A. Prasad, A. Ghosh, P. Sharma, B. Tudu, P. Pramanik, R. Bandyopadhyay, Application of polymethacrylic acid imprinted quartz crystal microbalance sensor for detection of 3-carene in mango. IEEE Sens. J. 18, 2697–2704 (2018). https://doi.org/10.1109/JSEN.2018.2794607CrossRef

20.

P. Jisha, M.S. Suma, M.V. Murugendrappa, Synthesis and characterization of WO₃-doped polyaniline to sense biomarker VOCs of Malaria. Appl. Nanosci. (2020). https://doi.org/10.1007/s13204-020-01551-3CrossRef

21.

P. Jisha, M.S. Suma, M.V. Murugendrappa, K. Raj, A study on the effect of PVDF on the structural and transport properties of polyaniline. Int. J. Polym. Anal. Charact. 25, 176–187 (2020). https://doi.org/10.1080/1023666X.2020.1779431CrossRef

22.

A. Mostafaei, A. Zolriasatein, Synthesis and characterization of conducting polyaniline nanocomposites containing ZnO nanorods. Prog. Nat. Sci. Mater. Int. 22, 273–280 (2012). https://doi.org/10.1016/j.pnsc.2012.07.002CrossRef

23.

S. Bhadra, J.H. Lee, Synthesis of Higher Soluble Nanostructured Polyaniline by Vapor-Phase Polymerization and Determination of its Crystal Structure. (2009). https://doi.org/10.1002/appCrossRef

24.

V.D. Mote, Y. Purushotham, B.N. Dole, Williamson-Hall analysis in estimation of lattice strain in nanometer-sized ZnO particles. J. Theor. Appl. Phys. (2012). https://doi.org/10.1186/2251-7235-6-6CrossRef

25.

M. Reka Devi, A. Saranya, J. Pandiarajan, J. Dharmaraja, N. Prithivikumaran, N. Jeyakumaran, Fabrication, spectral characterization, XRD and SEM studies on some organic acids doped polyaniline thin films on glass substrate. J. King Saud Univ. - Sci. 31, 1290–1296 (2019). https://doi.org/10.1016/j.jksus.2018.02.008CrossRef

26.

E. Kumar, P. Selvarajan, D. Muthuraj, Preparation and characterization of polyaniline/cerium dioxide (CeO₂) nanocomposite via in situ polymerization. J. Mater. Sci. 47, 7148–7156 (2012). https://doi.org/10.1007/s10853-012-6655-0CrossRef

27.

P. Ahuja, S.K. Ujjain, I. Arora, M. Samim, Hierarchically Grown NiO-Decorated Polyaniline-Reduced Graphene Oxide Composite for Ultrafast Sunlight-Driven Photocatalysis. ACS Omega 3, 7846–7855 (2018). https://doi.org/10.1021/acsomega.8b00765CrossRef

28.

M. Trchová, J. Stejskal, Polyaniline: the infrared spectroscopy of conducting polymer nanotubes (IUPAC Technical Report). Pure Apll. Chem. 83, 1803–1817 (2011). https://doi.org/10.1351/PAC-REP-10-02-01CrossRef

29.

V. Chaudhary, A. Kaur, Enhanced room temperature sulfur dioxide sensing behaviour of in situ polymerized polyaniline-tungsten oxide nanocomposite possessing honeycomb morphology. RSC Adv. 5, 73535–73544 (2015). https://doi.org/10.1039/c5ra08275gCrossRef

30.

W. He, Y. Zhao, Y. Xiong, Bilayer polyaniline-WO₃ thin-film sensors sensitive to NO2. ACS Omega 5, 9744–9751 (2020). https://doi.org/10.1021/acsomega.9b04122CrossRef

31.

D. Srivastava, R.K. Shukla, electrochemical properties and band gap variation of polyaniline due to the presence of ZnO. Proc. Natl Acad. Sci. India Sect. A Phys. Sci. 90, 309–318 (2020). https://doi.org/10.1007/s40010-019-00612-9CrossRef

32.

R. Kumar, B.C. Yadav, Fabrication of Polyaniline (PANI)—Tungsten oxide (WO₃) Composite for Humidity Sensing Application. J. Inorg. Organomet. Polym. Mater. 26, 1421–1427 (2016). https://doi.org/10.1007/s10904-016-0412-9CrossRef

33.

C. Rayssi, S. El Kossi, J. Dhahri, K. Khirouni, Frequency and temperature-dependence of dielectric permittivity and electric modulus studies of the solid solution Ca0.85Er0.1Ti1-: XCo4 x /3O3 (0 ≤ x ≤ 0.1). RSC Adv. 8, 17139–17150 (2018). https://doi.org/10.1039/c8ra00794bCrossRef

34.

S. Alialy, H. Tecimer, H. Uslu, Ş Altindal, A comparative study on electrical characteristics of Au/N-Si schottky diodes, with and without bi-doped PVA interfacial layer in dark and under illumination at room temperature. J. Nanomed. Nanotechnol. (2013). https://doi.org/10.4172/2157-7439.1000167CrossRef

35.

X. Chen, J.K. Tseng, I. Treufeld, M. Mackey, D.E. Schuele, R. Li, M. Fukuto, E. Baer, L. Zhu, Enhanced dielectric properties due to space charge-induced interfacial polarization in multilayer polymer films. J. Mater. Chem. C. 5, 10417–10426 (2017). https://doi.org/10.1039/c7tc03653aCrossRef

36.

N.H. Mohammed, Effect of MgO nano-oxide additions on the superconductivity and dielectric properties of Cu_0.25Tl_0.75Ba₂Ca₃Cu₄O₁₂-δ superconducting phase. J. Supercond. Nov. Magn. 25, 45–53 (2012). https://doi.org/10.1007/s10948-011-1207-4CrossRef

37.

M. Mumtaz, M. Touqeer, M.N. Khan, Effects of MnFe₂O₄ nanoparticles on dielectric properties of Cu_0.5Tl_0.5Ba₂Ca₂Cu₃O_1.0−δ superconducting phase. J. Mater. Sci. Mater. Electron. (2018). https://doi.org/10.1007/s10854-018-9829-yCrossRef

38.

M. Mumtaz, L. Ali, M.N. Khan, M.U. Sajid, Tuning of dielectric parameters of (NiFe₂O₄)x/CuTl-1223 nano-superconductor composites by temperature and frequency. J. Supercond. Nov. Magn. 29, 1181–1186 (2016). https://doi.org/10.1007/s10948-016-3393-6CrossRef

39.

B. Quan, X. Liang, G. Ji, Y. Cheng, W. Liu, J. Ma, Y. Zhang, D. Li, G. Xu, Dielectric polarization in electromagnetic wave absorption: Review and perspective. J. Alloys Compd. 728, 1065–1075 (2017). https://doi.org/10.1016/j.jallcom.2017.09.082CrossRef

40.

D.R. Bijwea, S.S. Yawaleb, A.C. Kumbharkhanec, H. Pengd, D.S. Yawalee, S.P. Yawalea, Complex dielectric behavior of doped polyaniline conducting polymer at microwave frequencies using time domain reflectometry. Rev. Mex. Fis. 65, 590–600 (2019)CrossRef

41.

W. Ji, H. Deng, C. Guo, C. Sun, X. Guo, F. Chen, Q. Fu, The effect of filler morphology on the dielectric performance of polyvinylidene fluoride (PVDF) based composites. Compos. Part A Appl. Sci. Manuf. 118, 336–343 (2019). https://doi.org/10.1016/j.compositesa.2019.01.011CrossRef

42.

I. Bekri-Abbes, E. Srasra, Electrical and dielectric properties of polyaniline and polyaniline/montmorillonite nanocomposite prepared by solid reaction using spectroscopy impedance. J. Nanomater. (2015). https://doi.org/10.1155/2015/516902CrossRef

43.

S.M. Chauhan, J. Mahida, B.S. Chakrabarty, dielectric property and conductivity study of polyaniline – CaF 2 nanocomposites. J. Nanotechnol. Adv. Mater. 17, 9–17 (2016)

44.

P. Kar, A. Choudhury, Electrical and Dielectric Properties of Polyaniline Doped with Carboxyl-Functionalized Multiwalled Carbon Nanotube. Adv. Polym.Technol. 32, 760–770 (2012). https://doi.org/10.1002/advCrossRef

45.

S. Pandey, Highly sensitive and selective chemiresistor gas/vapor sensors based on polyaniline nanocomposite: A comprehensive review. J. Sci. Adv. Mater. Devices. 1, 431–453 (2016). https://doi.org/10.1016/j.jsamd.2016.10.005CrossRef

46.

G. Gaikwad, P. Patil, D. Patil, J. Naik, Synthesis and evaluation of gas sensing properties of PANI based graphene oxide nanocomposites. Mater. Sci. Eng. B. 218, 14–22 (2017). https://doi.org/10.1016/j.mseb.2017.01.008CrossRef

47.

I.S. Zaine, Z.M. Zabidi, A.N. Alias, M.H. Jumali, Effect of polyaniline doping on structural and vapor sensing properties of tungsten organometallic thin film. Adv. Mater. Res. 658, 237–241 (2013)CrossRef

48.

J.N. Pereira, P. Vieira, A. Ferreira, A.J. Paleo, J.G. Rocha, S. Lanceros-Méndez, Piezoresistive effect in spin-coated polyaniline thin films. J. Polym. Res. 19, 6 (2012). https://doi.org/10.1007/s10965-011-9815-zCrossRef

49.

O.A. Al-Hartomy, S. Khasim, A. Roy, A. Pasha, Highly conductive polyaniline/graphene nano-platelet composite sensor towards detection of toluene and benzene gases. Appl. Phys. A Mater. Sci. Process. 125, 1–9 (2019). https://doi.org/10.1007/s00339-018-2317-7CrossRef

50.

M. Kikuchi, N. Tsuru, S. Shiratori, Recognition of terpenes using molecular imprinted polymer coated quartz crystal microbalance in air phase. Sci. Technol. Adv. Mater. 7, 156–161 (2006). https://doi.org/10.1016/j.stam.2005.12.004CrossRef

51.

N. Iqbal, G. Mustafa, A. Rehman, A. Biedermann, B. Najafi, P.A. Lieberzeit, F.L. Dickert, QCM-Arrays for sensing terpenes in fresh and dried herbs via bio-mimetic MIP layers. Sensors. 10, 6361–6376 (2010). https://doi.org/10.3390/s100706361CrossRef

52.

N. Afsarimanesh, M.E.E. Alahi, S.C. Mukhopadhyay, M. Kruger, Development of IoT-Based Impedometric Biosensor for Point-of-Care Monitoring of Bone Loss. IEEE. J. Emerg. Sel. Top. Circuits Syst. 8, 211–220 (2018). https://doi.org/10.1109/JETCAS.2018.2819204CrossRef

Title: Fabrication, characterization, and malaria biomarker VOC-sensing properties of WO3-doped polyaniline
Authors: P. Jisha
M. S. Suma
M. V. Murugendrappa
Sutar Rani Ananda
Publication date: 06-04-2021
Publisher: Springer US
Published in: Journal of Materials Science: Materials in Electronics / Issue 8/2021
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-021-05794-w

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Springer Professional "Wirtschaft"

Other articles of this Issue 8/2021

On the examination of temperature-dependent possible current-conduction mechanisms of Au/(nanocarbon-PVP)/n-Si Schottky barrier diodes in wide range of voltage

Synergistic effects of Ca2+ and high-valence Nb5+ co-doping on the structural, optical and magnetic properties of BiFeO3

Synthesis and characterization of phase-stabilized Gd2FeMnO6 double-Perovskite compound

Hydrothermal temperature dependence of CaWO4 nanoparticles: structural, optical, morphology and photocatalytic activity

Fabrication of quantum dot-sensitized solar cells with multilayer TiO2/PbS(X)/CdS/CdSe/ZnS/SiO2 photoanode and optimization of the PbS nanocrystalline layer

Enhanced optical, morphological, dielectric, and conductivity properties of gold nanoparticles doped with PVA/CMC blend as an application in organoelectronic devices