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Polymer Bulletin
Published in: Polymer Bulletin 12/2018

07-05-2018 | Original Paper

Influence of solid polymer electrolyte preparation methods on the performance of (PEO–PMMA)–LiBF4 films for lithium-ion battery applications

Authors: Priyanka Dhatarwal, R. J. Sengwa

Published in: Polymer Bulletin | Issue 12/2018

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Abstract

Classical solution-cast and ultrasonic–microwave-irradiated solution-cast methods have been used for the preparation of solid polymer electrolyte (SPE) films comprising polymer matrix of poly(ethylene oxide) and poly(methyl methacrylate) blend and lithium tetrafluoroborate (LiBF4) ionic salt. These films have been characterized by employing the X-ray diffraction, Fourier transform infrared spectroscopy, dielectric relaxation spectroscopy, and electrochemical analyser. It is observed that the temperature-dependent ionic conductivity of these predominantly amorphous solid ion–dipolar complexes is governed by their dielectric permittivity and the relaxation times of various dynamical processes. The relaxation times and the dc ionic conductivity of these electrolyte materials obey the Arrhenius behaviour, whereas the normalized ac conductivity exhibits the time–temperature superposition scaling. The influence of sample preparation methods on the performance of SPE films and the suitability of these materials for the lithium-ion batteries has been explored by noting the relative changes in their structural, dielectric, electrical, ionic conductivity, and the electrochemical parameters.
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Metadata
Title
Influence of solid polymer electrolyte preparation methods on the performance of (PEO–PMMA)–LiBF4 films for lithium-ion battery applications
Authors
Priyanka Dhatarwal
R. J. Sengwa
Publication date
07-05-2018
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 12/2018
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-018-2354-6

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