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Polymer Bulletin
Erschienen in: Polymer Bulletin 4/2017

18.08.2016 | Original Paper

Ionic conductivity and conduction mechanism studies on cellulose based solid polymer electrolytes doped with ammonium carbonate

verfasst von: M. I. H. Sohaimy, M. I. N. Isa

Erschienen in: Polymer Bulletin | Ausgabe 4/2017

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Abstract

The present work deals with the formation of solid polymer electrolytes (SPE) from carboxy methylcellulose (CMC) and doped with ammonium carbonate ((NH4)2CO3). The CMC–(NH4)2CO3 SPE was characterized with electrical impedance spectroscopy (EIS) and transference number measurement (TNM) to understand its electrical and conduction mechanism. Fourier transform infrared (FTIR) were conducted to correlate the complexation of the SPE with conductivity and conduction mechanism. Complexation appears to occur mainly in CMC carboxyl group (C=O). The highest ionic conductivity obtained is 7.71 × 10−6 Scm−1 for samples incorporated with 7 wt% of (NH4)2CO3. Lowest activation energy, E a achieved is 0.21 eV corresponds to the highest conductivity sample. Ionic conductivity measurement at elevated temperature follows Arrhenius model. Dielectric study of the sample shows dependence to temperature, but not to the frequency. CMC–(NH4)2CO3 SPE sample with the highest conductivity has transference number, \(t_{ + }\) of 0.98 proving of its conduction is predominantly cation. Quantum mechanical tunneling (QMT) was the best model to explain the conduction mechanism of the highest conductivity sample.
Vorheriger Artikel Synthesis and characterization of semi-conductive, thermally stable imine polymers containing methyl silane group
Nächster Artikel Properties of UV protective films of poly(vinyl-chloride)/TiO2 nanocomposites for food packaging

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Metadaten
Titel
Ionic conductivity and conduction mechanism studies on cellulose based solid polymer electrolytes doped with ammonium carbonate
verfasst von
M. I. H. Sohaimy
M. I. N. Isa
Publikationsdatum
18.08.2016
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 4/2017
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-016-1781-5

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