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Shape Memory and Superelasticity
Published in: Shape Memory and Superelasticity 1/2024

12-12-2023 | ORIGINAL RESEARCH ARTICLE

Magnetic Field-Induced Martensitic Phase Transition in Cr-Substituted Ni–Mn–Sb + B Shape Memory Alloys

Authors: M. Ayyildiz, G. Kirat, M. A. Aksan

Published in: Shape Memory and Superelasticity | Issue 1/2024

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Abstract

In this paper, the Ni50−yCryMn37Sb13 + B2 (y = 0, 3, 5 and 7) Heusler system was fabricated by the conventional arc-melting method. Samples with low Cr-content (y = 0 and 3) exhibited a mixed phase of 4O and 10 M at room temperature, while the samples with y = 5 and 7 Cr-content crystallized to L21 phase with \({\text{Fm}}\overline{3}\text{m }\) space group. The martensitic transition temperature decreased with increasing Cr-content in the system. The temperature-dependent magnetization results at a magnetic field of 100 Oe revealed an intermartensitic phase transition. The temperature-dependent magnetization measurements under 104 Oe (1 T) demonstrated a phase transition from ferromagnetic austenite to weakly magnetic martensite between 300 and 200 K, depending on the substitution level. The presence of hysteresis in the M–H curves confirmed a magnetic field-induced transformation in the samples. The field cooled (FC) M–H hysteresis loops shifted to the negative axis, which indicates exchange bias (EB) effect in the samples. Arrott plots provided evidence for a first-order magnetic phase transition in the fabricated samples.
previous article Effects of Point Defects on the Monoclinic Angle of the B19″ Phase in NiTi-Based Shape Memory Alloys
next article On the Impact of γ´ Precipitates on the Transformation Temperatures in Fe–Ni–Co–Al–Ti–B Shape Memory Alloy Wires
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Metadata
Title
Magnetic Field-Induced Martensitic Phase Transition in Cr-Substituted Ni–Mn–Sb + B Shape Memory Alloys
Authors
M. Ayyildiz
G. Kirat
M. A. Aksan
Publication date
12-12-2023
Publisher
Springer US
Published in
Shape Memory and Superelasticity / Issue 1/2024
Print ISSN: 2199-384X
Electronic ISSN: 2199-3858
DOI
https://doi.org/10.1007/s40830-023-00471-9

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