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Journal of Materials Science

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01-03-2017 | Original Paper

MOF-templated thermolysis for porous CuO/Cu₂O@CeO₂ anode material of lithium-ion batteries with high rate performance

Authors: Lijuan Wang, Xiaojie Wang, Zhaohui Meng, Hongjiang Hou, Baokuan Chen

Published in: Journal of Materials Science | Issue 12/2017

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Abstract

Novel porous CuO/Cu₂O@CeO₂ anode has been successfully synthesized from a Cu-based metal–organic framework (Cu-MOF) via a simple two-step pyrolysis method. The CeO₂ protective layer greatly improves the electronic conductivity, can buffer the volume change and can provide pathways for electron transport and Li⁺ diffusion. The results demonstrate that the electrochemical performance of CuO/Cu₂O anode can be significantly improved by the design. The CuO/Cu₂O@CeO₂ electrode delivers a large specific capacity of 473 mAh g⁻¹ at 0.3 A g⁻¹, and exhibits excellent rate capacity with 250 mAh g⁻¹ at 2 A g⁻¹ and good cyclic performance with a capacity of 592.3 mAh g⁻¹ after 100 cycles at 0.2 A g⁻¹.

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Title: MOF-templated thermolysis for porous CuO/Cu2O@CeO2 anode material of lithium-ion batteries with high rate performance
Authors: Lijuan Wang
Xiaojie Wang
Zhaohui Meng
Hongjiang Hou
Baokuan Chen
Publication date: 01-03-2017
Publisher: Springer US
Published in: Journal of Materials Science / Issue 12/2017
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-017-0949-1

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