Top

Journal of Coatings Technology and Research

Published in:

10-05-2022 | Review Article

Overview on progress in polysaccharides and aliphatic polyesters as coating of water-soluble fertilizers

Authors: Taha El Assimi, Redouane Beniazza, Mustapha Raihane, Hicham Ben Youcef, Abdellatif El Meziane, Hans Kricheldorf, Mohammed Lahcini

Published in: Journal of Coatings Technology and Research | Issue 4/2022

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Nitrogen, phosphorus, and potassium are the major nutrients solicited in the fertilization process, and their supply is highly useful to improve agricultural productivity. The conventional fertilizers suffer from low efficacy due to the fast release of nutrients. For that, the coating of granular fertilizer is considered as the best way to enhance their efficiency. Nowadays, biodegradable polymers are replacing synthetic polymers and avoiding the accumulation of nondegradable plastic residues in arable land. Since the coating of fertilizers by sulfur was criticized, many research studies investigated the use of polysaccharide such as cellulose, chitosan, carrageenan, lignin, and starch or aliphatic polyesters such as polylactide and polycaprolactone as coating matrix for granular fertilizer coating to delay or control the dissolution rate of nutrients. This review starts by apprising the readers about the environmental impact of conventional fertilizers (uncoated) and then an overview on the use of all those biopolymers and their combination for the coating agent mineral fertilizer. Furthermore, the present contribution provides an outline on different coating processes solicited in the field and the slow-release fertilizers criteria.

next article Layered double hydroxides (LDHs) for coating applications

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Dawson, CJ, Hilton, J, “Fertiliser Availability in a Resource-Limited World: Production and Recycling of Nitrogen and Phosphorus.” Food Policy, 36 S14–S22. https://doi.org/10.1016/j.foodpol.2010.11.012 (2011)CrossRef

Brown, ME, Higgins, N, “Markets, Climate Change, and Food Security in West Africa.” Environ. Sci. Technol., 43 8016–8020 (2009)CrossRef

Azeem, B, Kushaari, K, Man, ZB, et al. “Review on Materials & Methods to Produce Controlled Release Coated Urea Fertilizer.” J. Control. Release, 181 11–21. https://doi.org/10.1016/j.jconrel.2014.02.020 (2014)CrossRef

Majeed, Z, Ramli, NK, Mansor, N, Man, Z, “A Comprehensive Review on Biodegradable Polymers and Their Blends Used in Controlled-Release Fertilizer Processes.” Rev. Chem. Eng., 31 69–95. https://doi.org/10.1515/revce-2014-0021 (2015)CrossRef

Shaviv, A, “Advances in Controlled-Release Fertilizers.” Adv. Agron., 71 1–49. https://doi.org/10.1016/S0065-2113(01)71011-5 (2001)CrossRef

Shaviv, A, Mikkelsen, RL, "Controlled-Release Fertilizers to Increase Efficiency of Nutrient Use and Minimize Environmental Degradation - A Review." Fertilizer Research, 1–12 (1995)

Trenkel, M, Controlled-Release and Stabilized Fertilizers in Agriculture. Published by the International Fertilizer Industry Association (IFA), Paris (1997)

Naz, MY, Sulaiman, SA, “Slow Release Coating Remedy for Nitrogen Loss from Conventional Urea: A Review.” J. Control. Release, 225 109–120. https://doi.org/10.1016/j.jconrel.2016.01.037 (2016)CrossRef

Tomaszewska, M, Jarosiewicz, A, “Controlled-Release NPK Fertilizer Encapsulated by Polymeric Membranes.” J. Agric. Food Chem., 51 413–417. https://doi.org/10.1021/JF020800O (2003)CrossRef

10.

Chen, J, Lü, S, Zhang, Z, et al. “Environmentally Friendly Fertilizers: A Review of Materials Used and Their Effects on the Environment.” Sci. Total Environ., 613–614 829–839. https://doi.org/10.1016/j.scitotenv.2017.09.186 (2018)CrossRef

11.

Trenkel, ME, Slow- and Controlled-Release and Stabilized Fertilizers: An Option for Enhancing Nutrient Use Efficiency in Agriculture. International Fertilizer Industry Association (IFA), Paris (2010)

12.

Cordell, D, Smit, AL, Rosemarin, A, Sustainable Use of Phosphorus. Wageningen University and Research Centre Stockholm Environment Institute (SEI) (2009)

13.

Satyaprakash, M, Nikitha, T, Reddi, EUB, Sadhana, B, Vani, SS, “Phosphorous and Phosphate Solubilising Bacteria and their Role in Plant Nutrition.” Int. J. Curr. Microbiol. Appl. Sci., 4 2133–2144. https://doi.org/10.20546/ijcmas.2017.604.251 (2017)CrossRef

14.

Chien, SH, Prochnow, LI, Cantarella, H, “Chapter 8 Recent Developments of Fertilizer Production and Use to Improve Nutrient Efficiency and Minimize Environmental Impacts.” Adv. Agron., 102 267–322 (2009)CrossRef

15.

Khan, FA, Ansari, AA, “Eutrophication: An Ecological Vision.” Bot. Rev., 71 449–482. https://doi.org/10.1663/0006-8101(2005)071[0449:EAEV]2.0.CO;2 (2005)CrossRef

16.

Conley, DJ, Paerl, HW, Howarth, RW, et al. “Controlling Eutrophication: Phosphorus and Nitrogen.” Science, 323 1014–1015 (2009)CrossRef

17.

Tolescu, C, Iovu, H, “Polymer Conditioned Fertilizers.” UPB Sci. Bull. Ser. B, 72 (2) 3–14 (2010)

18.

Devassine, M, Henry, F, Guerin, P, Briand, X, “Coating of Fertilizers by Degradable Polymers.” Int. J. Pharm., 242 399–404. https://doi.org/10.1016/S0378-5173(02)00225-9 (2002)CrossRef

19.

Robert, S, Sofocleous, PE, "Production of Slow Release Nitrogen Fertilizers by Improved Method of Coating Urea with Sulfur." US Patent. 1–9 (1975)

20.

Naz, MY, Sulaiman, SA, “Testing of Starch-Based Carbohydrate Polymer Coatings for Enhanced Urea Performance.” J. Coat. Technol. Res., 11 747–756. https://doi.org/10.1007/s11998-014-9590-y (2014)CrossRef

21.

Mulder, WJ, Gosselink, RJA, Vingerhoeds, MH, et al. “Lignin Based Controlled Release Coatings.” Ind. Crop. Prod., 34 915–920. https://doi.org/10.1016/j.indcrop.2011.02.011 (2011)CrossRef

22.

Chen, W, et al. “Modeling of Pan Coating Process: Prediction of Tablet Content Uniformity and Determination of Critical Process Parameters.” J. Pharm. Sci., 99 3213–3225. https://doi.org/10.1002/jps (2010)CrossRef

23.

Babadi, FE, Yunus, R, Abbasi, A, “Response Surface Method in the Optimization of a Rotary Pan-Equipped Process for Increased Efficiency of Slow-Release Coated Urea.” MDPI Process, 7 125. https://doi.org/10.3390/pr7030125 (2019)CrossRef

24.

Porter, S, Sackett, G, Liu, L, "Development, Optimization, and Scale-Up of Process Parameters: Pan Coating." In: Pharmaceutical Theory and Practice, pp. 953–996 (2017)

25.

Donida, MW, Rocha, SCS, “Coating of Urea with an Aqueous Polymeric Suspension in a Two-Dimensional Spouted Bed.” Drying Technol., 20 685–704. https://doi.org/10.1081/DRT-120002824 (2002)CrossRef

26.

Naz, MY, Sulaiman, SA, Ariwahjoedi, B, Shaari, KZK, “Natural Carbohydrate Polymer Coatings for Green Urea.” Surf. Eng., 31 486–491. https://doi.org/10.1179/1743294414Y.0000000381 (2014)CrossRef

27.

Othman, S, Wahab, AA, Raghavan, VR, "Numerical Study of the Plenum Chamber of a Swirling Fluidized Bed." In: International Conference on Mechanical & Manufacturing Engineering, pp. 21–23 (2008).

28.

Li, J, Wang, M, She, D, Zhao, Y, “Structural Functionalization of Industrial Softwood Kraft Lignin for Simple Dip-Coating of Urea as Highly Efficient Nitrogen Fertilizer.” Ind. Crops Prod., 109 255–265. https://doi.org/10.1016/j.indcrop.2017.08.011 (2017)CrossRef

29.

Li, T, Gao, B, Tong, Z, et al. “Chitosan and Graphene Oxide Nanocomposites as Coatings for Controlled-Release Fertilizer.” Water Air Soil Pollut., https://doi.org/10.1007/s11270-019-4173-2 (2019)CrossRef

30.

Tomaszewska, M, Jarosiewicz, A, Karakulski, K, “Physical and Chemical Characteristics of Polymer Coatings in CRF Formulation.” Desalination, 146 319–323 (2002)CrossRef

31.

Jarrell, WM, Boersma, L, “Release of Urea by Granules of Sulfur-Coated Urea.” Soil Sci. Soc. Am. J., 44 418–422. https://doi.org/10.2136/sssaj1980.03615995004400020042x (1980)CrossRef

32.

Shaviv, AVI, Raban, S, Zaidel, E, “Modeling Controlled Nutrient Release from Polymer Coated Fertilizers: Diffusion Release from Single Granules.” Environmental Sci. Technol., 37 2251–2256 (2003)CrossRef

33.

Shoji, S, Kanno, H, “Use of Polyolefin-Coated Fertilizers for Increasing Fertilizer Efficiency and Reducing Nitrate Leaching and Nitrous Oxide Emissions.” Fertil. Res., 39 147–152. https://doi.org/10.1007/BF00750913 (1994)CrossRef

34.

Shaviv, A, “Plant Response and Environmental Aspects as Affected by Rate and Pattern of Nitrogen Release from Controlled Release N Fertilizers.” Prog. Nitrogen Cycl. Stud., https://doi.org/10.1007/978-94-011-5450-5_48 (1996)CrossRef

35.

Wu, L, Liu, M, “Preparation and Characterization of Cellulose Acetate-Coated Compound Fertilizer with Controlled-Release and Water-Retention.” Polym. Adv. Technol., https://doi.org/10.1002/pat (2008)CrossRef

36.

Taylor, P, Zhang, L, Zhang, G, et al. “Preparation and Characterization of Carboxymethyl Cellulose/Polyvinyl Alcohol Blend Film as a Potential Coating Material.” Polym. Plast. Technol. Eng., https://doi.org/10.1080/03602559.2012.734361 (2013)CrossRef

37.

Costa, MME, Cabral-Albuquerque, ECM, Alves, TLM, et al. “Use of Polyhydroxybutyrate and Ethyl Cellulose for Coating of Urea Granules.” J. Agric. Food Chem., 61 9984–9991. https://doi.org/10.1021/jf401185y (2013)CrossRef

38.

Li, Y, Zhen, D, Liao, S, et al. “Controlled-Release Urea Encapsulated by Ethyl Cellulose/Butyl Acrylate/Vinyl Acetate Hybrid Latex.” Polish J. Chem. Technol., 20 108–112. https://doi.org/10.2478/pjct-2018-0062 (2018)CrossRef

39.

Kassem, I, Ablouh, EH, El Bouchtaoui, FZ, et al. “Cellulose Nanocrystals-Filled Poly(vinyl alcohol) Nanocomposites as Waterborne Coating Materials of NPK Fertilizer with Slow Release and Water Retention Properties.” Int. J. Biol. Macromol., 189 1029–1042. https://doi.org/10.1016/j.ijbiomac.2021.08.093 (2021)CrossRef

40.

Kassem, I, Ablouh, EH, El Bouchtaoui, FZ, et al. “Biodegradable all-Cellulose Composite Hydrogel as Eco-friendly and Efficient Coating Material for Slow-Release MAP Fertilizer.” Prog. Org. Coat., 162 10657. https://doi.org/10.1016/j.porgcoat.2021.106575 (2022)CrossRef

41.

Zhang, M, Yang, J, “Preparation and Characterization of Multifunctional Slow Release Fertilizer Coated with Cellulose Derivatives.” Int. J. Polym. Mater. Polym. Biomater., 70 774–781. https://doi.org/10.1080/00914037.2020.1765352 (2021)CrossRef

42.

Wu, L, Liu, M, “Preparation and Properties of Chitosan-Coated NPK Compound Fertilizer with Controlled-Release and Water-Retention.” Carbohydr. Polym., 72 240–247. https://doi.org/10.1016/j.carbpol.2007.08.020 (2008)CrossRef

43.

Chen, C, Tao, S, Qiu, X, et al. “Long-Alkane-Chain Modified N-phthaloyl Chitosan Membranes with Controlled Permeability.” Carbohydr. Polym., 91 269–276. https://doi.org/10.1016/j.carbpol.2012.08.042 (2013)CrossRef

44.

Wang, X, Lü, S, Gao, C, et al. “Biomass-Based Multifunctional Fertilizer System Featuring Controlled-Release Nutrient, Water-Retention and Amelioration of Soil.” RSC Adv., 4 18382–18390. https://doi.org/10.1039/c4ra00207e (2014)CrossRef

45.

Lubkowski, K, “Coating Fertilizer Granules with Biodegradable Materials for Controlled Fertilizer Release.” Environ. Eng. Manag. J., 13 2573–2581 (2014)CrossRef

46.

El Assimi, T, et al. “Sustainable Coating Material Based on Chitosan-Clay Composite and Paraffin Wax for Slow-Release DAP Fertilizer.” Int. J. Biol. Macromol., 161 492–502. https://doi.org/10.1016/j.ijbiomac.2020.06.074 (2020)CrossRef

47.

Eddarai, EM, et al. “Chitosan-Kaolinite Clay Composite as Durable Coating Material for Slow Release NPK Fertilizer.” Int. J. Biol. Macromol., 195 424–432. https://doi.org/10.1016/j.ijbiomac.2021.12.055 (2022)CrossRef

48.

Peng, Z, Chen, F, “Synthesis and Properties of Lignin-Based Polyurethane Hydrogels.” Int. J. Polym. Mater., 60 674–683. https://doi.org/10.1080/00914037.2010.551353 (2011)CrossRef

49.

Fertahi, S, Bertrand, I, Amjoud, M, “Properties of Coated Slow-Release Triple Superphosphate (TSP) Fertilizers Based on Lignin and Carrageenan Formulations.” ACS Sustain. Chem. Eng., 7 10371–10382. https://doi.org/10.1021/acssuschemeng.9b00433 (2019)CrossRef

50.

Fertahi, S, Bertrand, I, Ilsouk, M, et al. “Impact of Plasticizers on Lignin-Carrageenan Formulation Properties and on Phosphorus Release from a Coated Triple Superphosphate Fertilizer.” Ind. Eng. Chem. Res., 59 14172–14179. https://doi.org/10.1021/acs.iecr.0c03143 (2020)CrossRef

51.

Dos Santos, ACS, Henrique, HM, Cardoso, VL, Reis, MHM, “Slow Release Fertilizer Prepared with Lignin and Poly(vinyl acetate) Bioblend.” Int. J. Biol. Macromol., 185 543–550. https://doi.org/10.1016/j.ijbiomac.2021.06.169 (2021)CrossRef

52.

Tomaszewska, M, Jarosiewicz, A, “Polysulfone Coating with Starch Addition in CRF Formulation.” Desalination, 163 247–252 (2004)CrossRef

53.

Han, X, Chen, S, Hu, X, “Controlled-Release Fertilizer Encapsulated by Starch/Polyvinyl Alcohol Coating.” Desalination, 240 21–26. https://doi.org/10.1016/j.desal.2008.01.047 (2009)CrossRef

54.

Naz, MY, Sulaiman, SA, Ariwahjoedi, B, et al. “Characterization of Modified Tapioca Starch Solutions and Their Sprays for High Temperature Coating Applications.” Sci. World J., https://doi.org/10.1155/2014/375206 (2014)CrossRef

55.

Muslim, S, Salman, Fitriani, L, et al. “Use of Bioblend Polystyrene/Starch for Coating Urea Granules as Slow Release Fertilizer.” J. Chem. Pharm. Res., 7 478–484 (2015)

56.

Qiao, D, Liu, H, Yu, L, et al. “Preparation and Characterization of Slow-Release Fertilizer Encapsulated by Starch-Based Superabsorbent Polymer.” Carbohydr. Polym., 147 146–154. https://doi.org/10.1016/j.carbpol.2016.04.010 (2016)CrossRef

57.

Sofyane, A, Ablouh, E, Lahcini, M, et al. “Slow-Release Fertilizers Based on Starch Acetate/Glycerol/Polyvinyl Alcohol Biocomposites for Sustained Nutrient Release.” Mater. Today Proc., https://doi.org/10.1016/j.matpr.2020.05.319 (2020)CrossRef

58.

Zafar, N, Niazi, MBK, Sher, F, et al. “Starch and Polyvinyl Alcohol Encapsulated Biodegradable Nanocomposites for Environment Friendly Slow Release of Urea Fertilizer.” Chem. Eng. J. Adv., 7 100123. https://doi.org/10.1016/j.ceja.2021.100123 (2021)CrossRef

59.

Wang, Y, Liu, M, Ni, B, Xie, L, “κ-Carrageenan-Sodium Alginate Beads and Superabsorbent Coated Nitrogen Fertilizer with Slow-Release, Water-Retention, and Anticompaction Properties.” Ind. Eng. Chem. Res., 51 1413–1422. https://doi.org/10.1021/ie2020526 (2012)CrossRef

60.

Fertahi, S, Bertrand, I, Ilsouk, M, et al. “New Generation of Controlled Release Phosphorus Fertilizers Based on Biological Macromolecules: Effect of Formulation Properties on Phosphorus Release.” Int. J. Biol. Macromol., 143 153–162. https://doi.org/10.1016/j.ijbiomac.2019.12.005 (2020)CrossRef

61.

Bao, CY, Cellulose Acetate/Plasticizer Systems: Structure, Morphology and Dynamics, Polymers. Université Claude Bernard - Lyon I (2015)

62.

Rinaudo, M, Pavlov, G, Desbrières, J, “Influence of Acetic Acid Concentration on the Solubilization of Chitosan.” Polymer, 40 7029–7032. https://doi.org/10.1016/S0032-3861(99)00056-7 (1999)CrossRef

63.

Chen, C, Gao, Z, Qiu, X, Hu, S, “Enhancement of the Controlled-Release Properties of Chitosan Membranes by Crosslinking with Suberoyl Chloride.” Molecules, 18 7239–7252. https://doi.org/10.3390/molecules18067239 (2013)CrossRef

64.

Duval, A, Lawoko, M, “A Review on Lignin-Based Polymeric, Micro- and Nano-structured Materials.” React. Funct. Polym., 85 78–96. https://doi.org/10.1016/j.reactfunctpolym.2014.09.017 (2014)CrossRef

65.

Wang, S, Li, C, Copeland, L, et al. “Starch Retrogradation: A Comprehensive Review.” Compr. Rev. Food Sci. Food Saf., 14 568–585. https://doi.org/10.1111/1541-4337.12143 (2015)CrossRef

66.

Zobel, HF, “Molecules to Granules: A Comprehensive Starch Review.” Starch - Stärke, 40 44–50. https://doi.org/10.1002/star.19880400203 (1988)CrossRef

67.

Necas, J, Bartosikova, L, “Carrageenan: A Review.” Veterinarni Medicina, 58 187–205. https://doi.org/10.17221/6758-VETMED (2013)CrossRef

68.

Madhavan Nampoothiri, K, Nair, NR, John, RP, “An Overview of the Recent Developments in Polylactide (PLA) Research.” Bioresour. Technol., 101 8493–8501. https://doi.org/10.1016/j.biortech.2010.05.092 (2010)CrossRef

69.

Di Lorenzo, ML, Androsch, R, Industrial Applications of Poly(lactic acid). Adv. Polym. Sci., Springer (2018)

70.

Murariu, M, Dubois, P, “PLA Composites: From Production to Properties.” Adv. Drug Deliv. Rev., 107 17–46. https://doi.org/10.1016/j.addr.2016.04.003 (2016)CrossRef

71.

Bordes, P, Pollet, E, Avérous, L, “Nano-biocomposites: Biodegradable Polyester/Nanoclay Systems.” Prog. Polym. Sci., 34 125–155. https://doi.org/10.1016/j.progpolymsci.2008.10.002 (2009)CrossRef

72.

Le Borgne, A, Prud, RE, Sarasua, J-R, et al. “Crystallization and Melting Behavior of Polylactides.” Macromolecules, 31 3895 (1998)CrossRef

73.

Park, KI, Xanthos, M, “A Study on the Degradation of Polylactic Acid in the Presence of Phosphonium Ionic Liquids.” Polym. Degrad. Stab., 94 834–844. https://doi.org/10.1016/j.polymdegradstab.2009.01.030 (2009)CrossRef

74.

Schliecker, G, Schmidt, C, Fuchs, S, Kissel, T, “Characterization of a Homologous Series of d,l-lactic acid Oligomers; A Mechanistic Study on the Degradation Kinetics In Vitro.” Biomaterials, 24 3835–3844. https://doi.org/10.1016/S0142-9612(03)00243-6 (2003)CrossRef

75.

Elsawy, MA, Kim, KH, Park, JW, Deep, A, “Hydrolytic Degradation of Polylactic Acid (PLA) and Its Composites.” Renew. Sustain. Energy Rev., 79 1346–1352. https://doi.org/10.1016/j.rser.2017.05.143 (2017)CrossRef

76.

Li, S, Tenon, M, Garreau, H, et al. “Enzymatic Degradation of Stereocopolymers Derived from L-, DL- and Meso-lactides.” Polym. Degrad. Stab., 67 85–90. https://doi.org/10.1016/S0141-3910(99)00091-9 (2000)CrossRef

77.

Mark, JE, Polymer Data Handbook. Oxford University Press, New York (1999)

78.

Peponi, L, Navarro-baena, I, Báez, JE, et al. “Effect of the Molecular Weight on the Crystallinity of PCL-b-PLLA Di-block Copolymers.” Polymer (Guildf), 53 4561–4568. https://doi.org/10.1016/j.polymer.2012.07.066 (2012)CrossRef

79.

Colin, GP, Zhong, G, “Modification of the Rates of Chain Cleavage of Polycaprolactone and Related Polyesters in the Solid State.” J. Control. Release, 4 283–292 (1987)CrossRef

80.

Jerome, R, Henrioulle-granville, M, Boutevin, B, Robin, JJS, “Telechelic Polymers Synthesis, Characterization and Applications.” Prog. Polym. Sci., 16 837–906 (1992)CrossRef

81.

Degke, P, Dubois, P, Jkrrne, R, “Thermal Stability and Viscoelastic Properties.” Macromol. Chem., 1995 1985–1995 (1997)

82.

Braud, C, et al. “Capillary Zone Electrophoresis in Normal or Reverse Polarity Separation Modes for the Analysis of Hydroxyl Acid Oligomers in Neutral Phosphate Buffer.” J. Chromatogr. B Biomed. Sci. Appl., 706 73–82 (1998)CrossRef

83.

Mahapatro, A, Kumar, A, Gross, RA, “Mild, Solvent-Free ω-Hydroxy Acid Polycondensations Catalyzed by Candida antarctica Lipase B.” Biomacromolecules, 5 62–68. https://doi.org/10.1021/bm0342382 (2004)CrossRef

84.

Boujemaoui, A, Carlsson, L, Malmstro, E, et al. “Facile Preparation Route for Nanostructured Composites: Surface- Initiated Ring-Opening Polymerization of ε -Caprolactone from High- Surface-Area Nanopaper.” ACS Appl. Mater. Interfaces, 4 3191–3198 (2012)CrossRef

85.

Lahcini, M, Elhakioui, S, Szopinski, D, et al. “Harnessing Synergies in Tin-Clay Catalyst for the Preparation of Poly(e-caprolactone)/Halloysite Nanocomposites.” Eur. Polym. J., 81 1–11. https://doi.org/10.1016/j.eurpolymj.2016.05.014 (2016)CrossRef

86.

El Assimi, T, Blažic, R, El Kadib, A, et al. “Synthesis of Poly(ε-caprolactone)-Grafted Guar Gum by Surface-Initiated Ring-Opening Polymerization.” Carbohydr. Polym., 220 95–102. https://doi.org/10.1016/j.carbpol.2019.05.049 (2019)CrossRef

87.

Mohamed, RM, Yusoh, K, “A Review on the Recent Research of Polycaprolactone (PCL).” Adv. Mater. Res., 1134 249–255. https://doi.org/10.4028/www.scientific.net/amr.1134.249 (2015)CrossRef

88.

Jintakanon, N, Opaprakasit, P, Petchsuk, A, Opaprakasit, M, “Controlled-Release Materials for Fertilizer Based on Lactic Acid Polymers.” Adv. Mat. Res., 57 905–908. https://doi.org/10.4028/www.scientific.net/AMR.55-57.905 (2008)CrossRef

89.

Djamaan, A, Suardi, M, Mayerni, R, et al. “Formulation of Slow-Release NPK Double-Coated Granules Using Bioblend Polymer by Spray.” Iraqi J. Agric. Sci., 49 1032–1040 (2018)

90.

Suardi, M, Rahmayulis, Ben ES, Djamaan, A, “Slow-Release NPK Double-Coating Granules Using Bioblends Polystyrene—Polycaprolactone as a Coating Polymer.” J. Agric. Vet. Sci., 13 59–64. https://doi.org/10.9790/2380-1301035964 (2020)CrossRef

91.

El Assimi, T, et al. “Poly(ε-caprolactone)-g-guar Gum and poly(ε-caprolactone)-g-halloysite Nanotubes as Coatings for Slow-release DAP Fertilizer.” J. Polym. Environ., 28 2078–2090. https://doi.org/10.1007/s10924-020-01750-7 (2020)CrossRef

92.

Wang, X, Zhang, X, Han, X, et al. “Performance Adjustable Porous Polylactic Acid-Based Membranes for Controlled Release Fertilizers.” J. Appl. Polym. Sci., https://doi.org/10.1002/app.49649 (2020)CrossRef

93.

Xia, X, Zhang, F, Yang, L, et al. “Low-Temperature Flowable Poly(lactic acid)/Polycaprolactone Blends for the Solvent-Free Preparation of Slow-Released Urea Fertilizer in a Thermal Shear Field.” Ind. Eng. Chem. Res., 59 (47) 20601–20611. https://doi.org/10.1021/acs.iecr.0c04419 (2020)CrossRef

94.

El Assimi, T, Bla, R, Vidovi, E, et al. “Progress in Organic Coatings Polylactide/Cellulose Acetate Biocomposites as Potential Coating Membranes for Controlled and Slow Nutrients Release from Water-Soluble Fertilizers.” Prog. Org. Coat., 156 106255. https://doi.org/10.1016/j.porgcoat.2021.106255 (2021)CrossRef

Title: Overview on progress in polysaccharides and aliphatic polyesters as coating of water-soluble fertilizers
Authors: Taha El Assimi
Redouane Beniazza
Mustapha Raihane
Hicham Ben Youcef
Abdellatif El Meziane
Hans Kricheldorf
Mohammed Lahcini
Publication date: 10-05-2022
Publisher: Springer US
Published in: Journal of Coatings Technology and Research / Issue 4/2022
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-022-00613-1

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 4/2022

The nano building blocks approach for modification of surface properties of nanocomposite inorganic–organic films

Micrometric array integrated with slippery liquid-infused porous surface for improved anti-icing durability

Marine biofouling resistance rating using image analysis

Effect of coating pigment type on paper printability with water-based inks

Study on surface wetting property regulation of greenhouse film and its antifogging performance

Influence of chain length of organic modifiers in hydrophobization process on epoxy resin properties

Premium Partners