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Historical Introduction to Gold Colloids, Clusters and Nanoparticles Read chapter Read first chapter

2014 | OriginalPaper | Chapter

Phosphine-Coordinated Pure-Gold Clusters: Diverse Geometrical Structures and Unique Optical Properties/Responses

Author : Katsuaki Konishi

Published in: Gold Clusters, Colloids and Nanoparticles I

Publisher: Springer International Publishing

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Abstract

Synthetic techniques, geometrical structures, and electronic absorption spectra of phosphine-coordinated pure-gold molecular clusters (PGCs) accumulated over 40 years are comprehensively collected especially for those with unambiguous X-ray crystal structures available. Inspection of the electronic absorption spectra from geometrical aspects reveals that their optical properties are highly dependent on the cluster geometries rather than the nuclearity. Recent examples of unusual clusters that show unique color/photoluminescence properties and their utilization for stimuli-responsive modules are also presented.

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previous chapter Historical Introduction to Gold Colloids, Clusters and Nanoparticles
next chapter Gold Nanoclusters: Size-Controlled Synthesis and Crystal Structures
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Metadata
Title
Phosphine-Coordinated Pure-Gold Clusters: Diverse Geometrical Structures and Unique Optical Properties/Responses
Author
Katsuaki Konishi
Copyright Year
2014
Book
Gold Clusters, Colloids and Nanoparticles I

Print ISBN: 978-3-319-07847-2

Electronic ISBN: 978-3-319-07848-9

Copyright Year: 2014

DOI
https://doi.org/10.1007/430_2014_143

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