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Published in: Journal of Materials Science 9/2018

16-01-2018 | Chemical routes to materials

Preparation of monodisperse cross-linked poly(glycidyl methacrylate)@Fe3O4@diazoresin magnetic microspheres with dye removal property

Authors: Bing Yu, Bo Yang, Guoling Li, Hailin Cong

Published in: Journal of Materials Science | Issue 9/2018

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Abstract

This article presented a versatile and robust adsorbent with both magnetic property and high adsorption capacity on the basis of poly(glycidyl methacrylate)@Fe3O4@diazoresin (PGMA@Fe3O4@DR) magnetic microspheres. The morphology, composition and magnetic properties of the magnetic microspheres were characterized by scanning electron microscope, Fourier transform infrared spectroscopy, thermogravimetric analysis and the hysteresis loop measurements, respectively. The obtained microspheres were applied in the adsorption of dye in the wastewater. The effects of adsorption time, initial dye concentration, pH value and other conditions were explored. Results show that the magnetic microspheres were able to remove more than 98.5% of dyes in water under optimized conditions. The use of diazoresin not only protects the Fe3O4 particles from being corroded at different pH values, but also greatly improves the adsorption capacity.

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Literature
1.
go back to reference Borges GA, Silva LP, Penido JA, de Lemos LR, Mageste AB, Rodrigues GD (2016) A method for dye extraction using an aqueous two-phase system: effect of co-occurrence of contaminants in textile industry wastewater. J Environ Manag 183(1):196–203CrossRef Borges GA, Silva LP, Penido JA, de Lemos LR, Mageste AB, Rodrigues GD (2016) A method for dye extraction using an aqueous two-phase system: effect of co-occurrence of contaminants in textile industry wastewater. J Environ Manag 183(1):196–203CrossRef
2.
go back to reference Dashamiri S, Ghaedi M, Dashtian K, Rahimi MR, Goudarzi A, Jannesar R (2016) Ultrasonic enhancement of the simultaneous removal of quaternary toxic organic dyes by CuO nanoparticles loaded on activated carbon: central composite design, kinetic and isotherm study. Ultrason Sonochem 31:546CrossRef Dashamiri S, Ghaedi M, Dashtian K, Rahimi MR, Goudarzi A, Jannesar R (2016) Ultrasonic enhancement of the simultaneous removal of quaternary toxic organic dyes by CuO nanoparticles loaded on activated carbon: central composite design, kinetic and isotherm study. Ultrason Sonochem 31:546CrossRef
3.
go back to reference Liang C, Sun S, Li F, Ong Y, Chung T (2014) Treatment of highly concentrated wastewater containing multiple synthetic dyes by a combined process of coagulation/flocculation and nanofiltration. J Membr Sci 469:306–315CrossRef Liang C, Sun S, Li F, Ong Y, Chung T (2014) Treatment of highly concentrated wastewater containing multiple synthetic dyes by a combined process of coagulation/flocculation and nanofiltration. J Membr Sci 469:306–315CrossRef
4.
go back to reference Song W, Gao B, Xu X, Xing L, Han S, Duan P, Song W, Jia R (2016) Adsorption–desorption behavior of magnetic amine/Fe3O4 functionalized biopolymer resin towards anionic dyes from wastewater. Bioresour Technol 210:123–130CrossRef Song W, Gao B, Xu X, Xing L, Han S, Duan P, Song W, Jia R (2016) Adsorption–desorption behavior of magnetic amine/Fe3O4 functionalized biopolymer resin towards anionic dyes from wastewater. Bioresour Technol 210:123–130CrossRef
5.
go back to reference Jiang D, Amano Y, Machida M (2017) Removal and recovery of phosphate from water by calcium-silicate composites-novel adsorbents made from waste glass and shells. Environ Sci Pollut R 24(9):8210–8218CrossRef Jiang D, Amano Y, Machida M (2017) Removal and recovery of phosphate from water by calcium-silicate composites-novel adsorbents made from waste glass and shells. Environ Sci Pollut R 24(9):8210–8218CrossRef
6.
go back to reference Gupta VK, Gupta B, Rastogi A, Agarwal S, Nayak A (2011) A comparative investigation on adsorption performances of mesoporous activated carbon prepared from waste rubber tire and activated carbon for a hazardous azo dye—acid blue 113. J Hazard Mater 186(1):891–901CrossRef Gupta VK, Gupta B, Rastogi A, Agarwal S, Nayak A (2011) A comparative investigation on adsorption performances of mesoporous activated carbon prepared from waste rubber tire and activated carbon for a hazardous azo dye—acid blue 113. J Hazard Mater 186(1):891–901CrossRef
7.
go back to reference Bedin KC, Martins AC, Cazetta AL, Pezoti O, Almeida VC (2016) KOH-activated carbon prepared from sucrose spherical carbon: adsorption equilibrium, kinetic and thermodynamic studies for methylene blue removal. Chem Eng J 286:476–484CrossRef Bedin KC, Martins AC, Cazetta AL, Pezoti O, Almeida VC (2016) KOH-activated carbon prepared from sucrose spherical carbon: adsorption equilibrium, kinetic and thermodynamic studies for methylene blue removal. Chem Eng J 286:476–484CrossRef
8.
go back to reference Fernandez ME, Nunell GV, Bonelli PR, Cukierman AL (2014) Activated carbon developed from orange peels: batch and dynamic competitive adsorption of basic dyes. Ind Crop Prod 62:437–445CrossRef Fernandez ME, Nunell GV, Bonelli PR, Cukierman AL (2014) Activated carbon developed from orange peels: batch and dynamic competitive adsorption of basic dyes. Ind Crop Prod 62:437–445CrossRef
9.
go back to reference Gokce Y, Aktas Z (2014) Nitric acid modification of activated carbon produced from waste tea and adsorption of methylene blue and phenol. Appl Surf Sci 313:352–359CrossRef Gokce Y, Aktas Z (2014) Nitric acid modification of activated carbon produced from waste tea and adsorption of methylene blue and phenol. Appl Surf Sci 313:352–359CrossRef
10.
go back to reference Nekouei F, Nekouei S, Tyagi I, Gupta VK (2015) Kinetic, thermodynamic and isotherm studies for acid blue 129 removal from liquids using copper oxide nanoparticle-modified activated carbon as a novel adsorbent. J Mol Liq 201:124–133CrossRef Nekouei F, Nekouei S, Tyagi I, Gupta VK (2015) Kinetic, thermodynamic and isotherm studies for acid blue 129 removal from liquids using copper oxide nanoparticle-modified activated carbon as a novel adsorbent. J Mol Liq 201:124–133CrossRef
11.
go back to reference Fu J, Chen Z, Wang M, Liu S, Zhang J, Zhang J, Han R, Xu Q (2015) Adsorption of methylene blue by a high-efficiency adsorbent (polydopamine microspheres): kinetics, isotherm, thermodynamics and mechanism analysis. Chem Eng J 259:53–61CrossRef Fu J, Chen Z, Wang M, Liu S, Zhang J, Zhang J, Han R, Xu Q (2015) Adsorption of methylene blue by a high-efficiency adsorbent (polydopamine microspheres): kinetics, isotherm, thermodynamics and mechanism analysis. Chem Eng J 259:53–61CrossRef
12.
go back to reference Meng L, Chan Y, Wang H, Dai Y, Wang X, Zou J (2016) Recycling of iron and silicon from drinking water treatment sludge for synthesis of magnetic iron oxide@SiO2 composites. Environ Sci Pollut R 23(6):5122–5133CrossRef Meng L, Chan Y, Wang H, Dai Y, Wang X, Zou J (2016) Recycling of iron and silicon from drinking water treatment sludge for synthesis of magnetic iron oxide@SiO2 composites. Environ Sci Pollut R 23(6):5122–5133CrossRef
13.
go back to reference Wu H, Shi Y, Guo X, Zhao S, Du J, Jia H, He L, Du L (2016) Determination and removal of sulfonamides and quinolones from environmental water samples using magnetic adsorbents. J Sep Sci 39(22):4398–4407CrossRef Wu H, Shi Y, Guo X, Zhao S, Du J, Jia H, He L, Du L (2016) Determination and removal of sulfonamides and quinolones from environmental water samples using magnetic adsorbents. J Sep Sci 39(22):4398–4407CrossRef
14.
go back to reference Zhang Y, Shen S, Wang S, Huang J, Su P, Wang Q, Zhao B (2014) A dual function magnetic nanomaterial modified with lysine for removal of organic dyes from water solution. Chem Eng J 239:250–256CrossRef Zhang Y, Shen S, Wang S, Huang J, Su P, Wang Q, Zhao B (2014) A dual function magnetic nanomaterial modified with lysine for removal of organic dyes from water solution. Chem Eng J 239:250–256CrossRef
15.
go back to reference Shariati S, Faraji M, Yamini Y, Rajabi AA (2011) Fe3O4 magnetic nanoparticles modified with sodium dodecyl sulfate for removal of safranin O dye from aqueous solutions. Desalination 270(1–3):160–165CrossRef Shariati S, Faraji M, Yamini Y, Rajabi AA (2011) Fe3O4 magnetic nanoparticles modified with sodium dodecyl sulfate for removal of safranin O dye from aqueous solutions. Desalination 270(1–3):160–165CrossRef
16.
go back to reference Yan H, Li H, Yang H, Li A, Cheng R (2013) Removal of various cationic dyes from aqueous solutions using a kind of fully biodegradable magnetic composite microsphere. Chem Eng J 223:402–411CrossRef Yan H, Li H, Yang H, Li A, Cheng R (2013) Removal of various cationic dyes from aqueous solutions using a kind of fully biodegradable magnetic composite microsphere. Chem Eng J 223:402–411CrossRef
17.
go back to reference Amara D, Grinblat J, Margel S (2010) Synthesis of magnetic iron and iron oxide micrometre-sized composite particles of narrow size distribution by annealing iron salts entrapped within uniform porous poly(divinylbenzene) microspheres. J Mater Chem 20(10):1899–1906CrossRef Amara D, Grinblat J, Margel S (2010) Synthesis of magnetic iron and iron oxide micrometre-sized composite particles of narrow size distribution by annealing iron salts entrapped within uniform porous poly(divinylbenzene) microspheres. J Mater Chem 20(10):1899–1906CrossRef
18.
go back to reference Zhang Y, Su P, Huang J, Wang Q, Zhao B (2015) A magnetic nanomaterial modified with poly-lysine for efficient removal of anionic dyes from water. Chem Eng J 262:313–318CrossRef Zhang Y, Su P, Huang J, Wang Q, Zhao B (2015) A magnetic nanomaterial modified with poly-lysine for efficient removal of anionic dyes from water. Chem Eng J 262:313–318CrossRef
19.
go back to reference Zhang C, Qiu L, Ke F, Zhu Y, Yuan Y, Xu G, Jiang X (2013) A novel magnetic recyclable photocatalyst based on a core–shell metal–organic framework Fe3O4@MIL-100(Fe) for the decolorization of methylene blue dye. J Mater Chem A 1(45):14329–14334CrossRef Zhang C, Qiu L, Ke F, Zhu Y, Yuan Y, Xu G, Jiang X (2013) A novel magnetic recyclable photocatalyst based on a core–shell metal–organic framework Fe3O4@MIL-100(Fe) for the decolorization of methylene blue dye. J Mater Chem A 1(45):14329–14334CrossRef
20.
go back to reference Chen H, Deng C, Zhang X (2010) Synthesis of Fe3O4@SiO2@PMMA core–shell–shell magnetic microspheres for highly efficient enrichment of peptides and proteins for MALDI-ToF MS analysis. Angew Chem Int Ed 49(3):607–611CrossRef Chen H, Deng C, Zhang X (2010) Synthesis of Fe3O4@SiO2@PMMA core–shell–shell magnetic microspheres for highly efficient enrichment of peptides and proteins for MALDI-ToF MS analysis. Angew Chem Int Ed 49(3):607–611CrossRef
21.
go back to reference Reddy DHK, Lee S (2013) Application of magnetic chitosan composites for the removal of toxic metal and dyes from aqueous solutions. Adv Colloid Interface 201:68–93CrossRef Reddy DHK, Lee S (2013) Application of magnetic chitosan composites for the removal of toxic metal and dyes from aqueous solutions. Adv Colloid Interface 201:68–93CrossRef
22.
go back to reference Zhang X, Zeng T, Wang S, Niu H, Wang X, Cai Y (2015) One-pot synthesis of C18-functionalized core–shell magnetic mesoporous silica composite as efficient sorbent for organic dye. J Colloid Interf Sci 448:189–196CrossRef Zhang X, Zeng T, Wang S, Niu H, Wang X, Cai Y (2015) One-pot synthesis of C18-functionalized core–shell magnetic mesoporous silica composite as efficient sorbent for organic dye. J Colloid Interf Sci 448:189–196CrossRef
23.
go back to reference Ma H, Li J, Liu W, Miao M, Cheng B, Zhu S (2015) Novel synthesis of a versatile magnetic adsorbent derived from corncob for dye removal. Bioresour Technol 190:13–20CrossRef Ma H, Li J, Liu W, Miao M, Cheng B, Zhu S (2015) Novel synthesis of a versatile magnetic adsorbent derived from corncob for dye removal. Bioresour Technol 190:13–20CrossRef
24.
go back to reference Yu B, Zhang H, Cong H, Gu C, Gao L, Yang B, Usman M (2017) Diazoresin modified monodisperse porous poly(glycidylmethacrylate-co-divinylbenzene) microspheres as the stationary phase for high performance liquid chromatography. New J Chem 41(11):4637–4643CrossRef Yu B, Zhang H, Cong H, Gu C, Gao L, Yang B, Usman M (2017) Diazoresin modified monodisperse porous poly(glycidylmethacrylate-co-divinylbenzene) microspheres as the stationary phase for high performance liquid chromatography. New J Chem 41(11):4637–4643CrossRef
26.
go back to reference Yang J, Hao D, Bi C, Su Z, Wang L, Ma G (2010) Rapid synthesis of uniform magnetic microspheres by combing premix membrane emulsification and in situ formation techniques. Ind Eng Chem Res 49(13):6047–6053CrossRef Yang J, Hao D, Bi C, Su Z, Wang L, Ma G (2010) Rapid synthesis of uniform magnetic microspheres by combing premix membrane emulsification and in situ formation techniques. Ind Eng Chem Res 49(13):6047–6053CrossRef
27.
go back to reference Hwang CW, Kwak N, Hwang TS (2013) Preparation of poly(GMA-co-PEGDA) microbeads modified with iminodiacetic acid and their indium adsorption properties. Chem Eng J 226:79–86CrossRef Hwang CW, Kwak N, Hwang TS (2013) Preparation of poly(GMA-co-PEGDA) microbeads modified with iminodiacetic acid and their indium adsorption properties. Chem Eng J 226:79–86CrossRef
28.
go back to reference Cao TB, Yang SM, Cao J, Zhang MF, Huang CH, Cao WX (2001) Nanoassembly film of carboxylic polyaniline with photosensitive diazoresin and its photoelectric conversion properties. J Phys Chem B 105(48):11941–11944CrossRef Cao TB, Yang SM, Cao J, Zhang MF, Huang CH, Cao WX (2001) Nanoassembly film of carboxylic polyaniline with photosensitive diazoresin and its photoelectric conversion properties. J Phys Chem B 105(48):11941–11944CrossRef
29.
go back to reference Han J, Du Z, Zou W, Li H, Zhang C (2014) Fabrication of interfacial functionalized porous polymer monolith and its adsorption properties of copper ions. J Hazard Mater 276:225–231CrossRef Han J, Du Z, Zou W, Li H, Zhang C (2014) Fabrication of interfacial functionalized porous polymer monolith and its adsorption properties of copper ions. J Hazard Mater 276:225–231CrossRef
Metadata
Title
Preparation of monodisperse cross-linked poly(glycidyl methacrylate)@Fe3O4@diazoresin magnetic microspheres with dye removal property
Authors
Bing Yu
Bo Yang
Guoling Li
Hailin Cong
Publication date
16-01-2018
Publisher
Springer US
Published in
Journal of Materials Science / Issue 9/2018
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2018-9

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