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Journal of Sol-Gel Science and Technology

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22-03-2022 | Original Paper: Sol-gel and hybrid materials with surface modification for applications

Preparation of pyridine Schiff base grafted ion-imprinted mesoporous sorbent for selective separation of Pb(II) from aqueous medium

Authors: Yingming Mao, Qiongxin Gou, Guohao Wu, Ying Yang, Ming Chen, Yuanyuan Zhang

Published in: Journal of Sol-Gel Science and Technology | Issue 2/2022

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Abstract

A pyridine Schiff base grafted ion-imprinted mesoporous silica adsorbent (IIMS-HAp) was designed and prepared using Pb(II) as the template ions. The as-synthesized IIMS-HAp exhibited the pH-dependent removal of Pb(II) in water, and the sorption data agreed well with pseudo-second-order kinetic and Langmuir isotherm models. The theoretical maximum adsorption capacity of IIMS-HAp toward Pb(II) was 70.27 mg/g at pH 6.0, which was higher than that of non-imprinted counterpart. Moreover, the adsorbent showed high extraction selectivity toward Pb(II) over other co-existed cations. Owing to the excellent reusability, IIMS-HAp can be employed as a selective adsorbent for the efficient removal of Pb(II) from aqueous solution.

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Title: Preparation of pyridine Schiff base grafted ion-imprinted mesoporous sorbent for selective separation of Pb(II) from aqueous medium
Authors: Yingming Mao
Qiongxin Gou
Guohao Wu
Ying Yang
Ming Chen
Yuanyuan Zhang
Publication date: 22-03-2022
Publisher: Springer US
Published in: Journal of Sol-Gel Science and Technology / Issue 2/2022
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-022-05764-6

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