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Erschienen in: Journal of Sol-Gel Science and Technology 2/2022

22.03.2022 | Original Paper: Sol-gel and hybrid materials with surface modification for applications

Preparation of pyridine Schiff base grafted ion-imprinted mesoporous sorbent for selective separation of Pb(II) from aqueous medium

verfasst von: Yingming Mao, Qiongxin Gou, Guohao Wu, Ying Yang, Ming Chen, Yuanyuan Zhang

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 2/2022

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Abstract

A pyridine Schiff base grafted ion-imprinted mesoporous silica adsorbent (IIMS-HAp) was designed and prepared using Pb(II) as the template ions. The as-synthesized IIMS-HAp exhibited the pH-dependent removal of Pb(II) in water, and the sorption data agreed well with pseudo-second-order kinetic and Langmuir isotherm models. The theoretical maximum adsorption capacity of IIMS-HAp toward Pb(II) was 70.27 mg/g at pH 6.0, which was higher than that of non-imprinted counterpart. Moreover, the adsorbent showed high extraction selectivity toward Pb(II) over other co-existed cations. Owing to the excellent reusability, IIMS-HAp can be employed as a selective adsorbent for the efficient removal of Pb(II) from aqueous solution.

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Metadaten
Titel
Preparation of pyridine Schiff base grafted ion-imprinted mesoporous sorbent for selective separation of Pb(II) from aqueous medium
verfasst von
Yingming Mao
Qiongxin Gou
Guohao Wu
Ying Yang
Ming Chen
Yuanyuan Zhang
Publikationsdatum
22.03.2022
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 2/2022
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-022-05764-6

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