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Journal of Materials Science: Materials in Electronics
Published in: Journal of Materials Science: Materials in Electronics 9/2021

10-04-2021

Room-temperature multiferrocity and magnetodielectric properties of ternary BiFeO3–Bi0.5Na0.5TiO3–CaTiO3 ceramics across the rhombohedral–orthorhombic phase boundary

Authors: W. J. Huang, J. J. Yang, M. F. Shu, J. Wu, L. H. Yin, W. H. Song, P. Tong, X. B. Zhu, J. Yang, Y. P. Sun

Published in: Journal of Materials Science: Materials in Electronics | Issue 9/2021

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Abstract

A novel ternary solid solution (1-y)((1-x)BiFeO3–xBi0.5Na0.5TiO3)–yCaTiO3 (0 ≤ x ≤ 0.3, 0.15 ≤ y ≤ 0.25) is designed to present a rhombohedral–orthorhombic morphotropic phase boundary (MPB) with enhanced ferroelectricity, canted ferromagnetism, and room-temperature magnetoelectric responses. The addition of Bi0.5Na0.5TiO3 can generate a distinct MPB region and make BiFeO3–CaTiO3-based ceramics more denser. Therefore, superior ferroelectric properties with the remanent polarization of 37µC/cm2 can be obtained in the x = 0.3, y = 0.15 sample with the presence of rhombohedral–orthorhombic MPB. However, weak ferromagnetism is observed in both the rhombohedral and orthorhombic phases due to a destruction of the spiral spin structure of BiFeO3. The MPB with canted ferromagnetism is constructed. The maximum magnetoelectric interaction constant is found in the MPB compositions with x = 0.2, y = 0.2 which is related with the multiferroic phase boundary.
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Metadata
Title
Room-temperature multiferrocity and magnetodielectric properties of ternary BiFeO3–Bi0.5Na0.5TiO3–CaTiO3 ceramics across the rhombohedral–orthorhombic phase boundary
Authors
W. J. Huang
J. J. Yang
M. F. Shu
J. Wu
L. H. Yin
W. H. Song
P. Tong
X. B. Zhu
J. Yang
Y. P. Sun
Publication date
10-04-2021
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 9/2021
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-021-05729-5

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