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Journal of Materials Science: Materials in Electronics

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16-04-2021

Synthesis and photoluminescence properties of color-tunable Y₂SiWO₈: Dy³⁺, Sm³⁺ phosphor

Authors: Shengjia Wang, Chenchen Xu, Xuebin Qiao

Published in: Journal of Materials Science: Materials in Electronics | Issue 9/2021

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Abstract

Dy³⁺, Sm³⁺ co-doped Y₂SiWO₈ (YSiWO) phosphors were synthesized through the sol–gel method. The crystal structure, morphology, photoluminescence spectra and thermal stability of the phosphors have been thoroughly studied. The Dy³⁺ dopant concentration is fixed at 2 mol% in co-doped samples. It is noticeable that energy transfer from Dy³⁺ to Sm³⁺ is apparent under the 365 nm excitation. The energy transfer mechanisms of Dy³⁺ → Dy³⁺ (YSiWO: Dy³⁺), Sm³⁺ → Sm³⁺ (YSiWO: Sm³⁺) and Dy³⁺ → Sm³⁺ (YSiWO: Dy³⁺, Sm³⁺) are extensively studied, respectively. Upon the 365 nm excitation, the co-doped phosphor shows the color-tunable emission varying from blue-green to white via adjusting Sm³⁺ concentration. The YSiWO: 0.02Dy³⁺, 0.06Sm³⁺ phosphor exhibits an ideal warm white emission with CIE coordinates of (0.362, 0.323) and CCT of 4129 K. This phosphor is also found to possess the remarkable thermal stability. In summary, the YSiWO: Dy³⁺, Sm³⁺ white-emitting phosphor may have potential use in w-LEDs.

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Title: Synthesis and photoluminescence properties of color-tunable Y2SiWO8: Dy3+, Sm3+ phosphor
Authors: Shengjia Wang
Chenchen Xu
Xuebin Qiao
Publication date: 16-04-2021
Publisher: Springer US
Published in: Journal of Materials Science: Materials in Electronics / Issue 9/2021
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-021-05898-3

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