Top

Cellulose

Published in:

16-11-2017 | Original Paper

TiO₂-grafted cellulose via click reaction: an efficient heavy metal ions bioadsorbent from aqueous solutions

Authors: Zari Fallah, Hossein Nasr Isfahani, Mahmood Tajbakhsh, Hamed Tashakkorian, Abdoliman Amouei

Published in: Cellulose | Issue 1/2018

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

In this paper, preparation, characterization and adsorption properties of a new biocompatible cellulose-titania based nanocomposite (Cell-Com) made by the click reaction were investigated. FTIR, XRD, FESEM, BET, EDX and ICP-OES analyses were used to characterize the structure of Cell-Com. The adsorption behavior of the Cell-Com for the removal of Pb²⁺, Cd²⁺ and Zn²⁺ ions from aqueous solutions was performed by batch experiments. The effects of pH, contact time, adsorbent dose, initial metal ion concentration, temperature, coexisting ions and the regeneration performance of synthesized nanocomposite were evaluated. The optimal adsorption conditions was determined to be at pH 7.0, 60 min contact time, 10 mg adsorbent dose and 20 ppm initial metal ion concentration at 298 K. The equilibrium data was fitted well with the Langmuir isotherm among the examined isotherms and the maximum adsorption capacity of the bioadsorbent for Zn²⁺, Cd²⁺ and Pb²⁺ ions found to be 102.04, 102.05 and 120.48 mg g⁻¹, respectively. The pseudo-second order model was the best kinetic model to explain the adsorption kinetic data, suggesting chemical sorption as the rate-determining step of sorption mechanism. The ΔG°, ΔH° and ΔS° values were estimated from Van’t Hoff plot together with activation energy (E_a) determined using Arrhenius equation, displayed that the adsorption process is spontaneous and endothermic in nature. The synthesized nanocomposite showed high selectivity and interference resistance from coexisting ions for the adsorption of Pb²⁺ ion. The Cell-Com can be easily regenerated and reused without significant loss of adsorption capacity. Recovery and reusability of Cell-Com were performed after 4–5 repeated adsorption/desorption cycles in HCl or in EDTA solutions.

previous article Antimicrobial wound dressing film utilizing cellulose nanocrystal as drug delivery system for curcumin

next article Chitosan/partially sulfonated poly(vinylidene fluoride) blends as polymer electrolyte membranes for direct methanol fuel cell applications

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Available only for authorised users

Anirudhan TS, Rejeena SR (2011) Thorium(IV) removal and recovery from aqueous solutions using tannin-modified poly(glycidylmethacrylate)-grafted zirconium oxide densified cellulose. Ind Eng Chem Res 50:13288–13298. https://doi.org/10.1021/ie2015679 CrossRef

Anirudhan TS, Nima J, Sandeep S, Ratheesh VRN (2012) Development of an amino functionalized glycidylmethacrylate-grafted-titanium dioxide densified cellulose for the adsorptive removal of arsenic(V) from aqueous solutions. Chem Eng J 209:362–371. https://doi.org/10.1016/j.cej.2012.07.129 CrossRef

Bai J, Zhou B (2014) Titanium dioxide nanomaterials for sensor applications. Chem Rev 114:10131–10176. https://doi.org/10.1021/cr400625j CrossRefPubMed

Bezrodna T, Puchkovska G, Shymanovska V, Baran J, Ratajczak H (2004) IR-analysis of H-bonded H₂O on the pure TiO₂ surface. J Mol Struct 700:175–181. https://doi.org/10.1016/j.molstruc.2003.12.057 CrossRef

Bossa N, Carpenter AW, Kumar N, de Lannoy C-F, Wiesner M (2017) Cellulose nanocrystal zero-valent iron nanocomposites for groundwater remediation. Environ Sci Nano. https://doi.org/10.1039/C6EN00572A CrossRefPubMedPubMedCentral

d’Halluin M, Rull-Barrull J, Bretel G, Labrugère C, Le Grognec E, Felpin F-X (2017) Chemically modified cellulose filter paper for heavy metal remediation in water. ACS Sustain Chem Eng 5:1965–1973. https://doi.org/10.1021/acssuschemeng.6b02768 CrossRef

Dahl M, Liu Y, Yin Y (2014) Composite titanium dioxide nanomaterials. Chem Rev 114:9853–9889. https://doi.org/10.1021/cr400634p CrossRefPubMed

Elchinger P-H, Faugeras PA, Zerrouki C, Montplaisir D, Brouillette F, Zerrouki R (2012a) Tosylcellulose synthesis in aqueous medium. Green Chem 14:3126–3131. https://doi.org/10.1039/c2gc35592b CrossRef

Elchinger P-H, Montplaisir D, Zerrouki R (2012b) Starch-cellulose crosslinking—towards a new material. Carbohydr Polym 87:1886–1890. https://doi.org/10.1016/j.carbpol.2011.09.027 CrossRef

Eligwe CA, Okolue NB, Nwambu CO, Nwoko CIA (1999) Adsorption thermodynamics and kinetics of mercury(II), Cadmium(II) and lead(II) on lignite. Chem Eng Technol 22:45–49CrossRef

French AD (2014) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21:885–896. https://doi.org/10.1007/s10570-013-0030-4 CrossRef

French AD, Santiago Cintrón M (2013) Cellulose polymorphy, crystallite size, and the Segal Crystallinity Index. Cellulose 20:583–588. https://doi.org/10.1007/s10570-012-9833-y CrossRef

Freundlich HMF (1906) Uber die adsorption in losungen. Z Phys Chem 57A:385–470

Gan W, Gao L, Zhan X, Li J (2016) Preparation of thiol-functionalized magnetic sawdust composites as an adsorbent to remove heavy metal ions. RSC Adv 6:37600–37609. https://doi.org/10.1039/c6ra02285e CrossRef

Ghaemy M, Qasemi S, Ghassemi K, Bazzar M (2013) Nanostructured composites of poly (triazole-amide-imide) s and reactive titanium oxide by epoxide functionalization: thermal, mechanical, photophysical and metal ions adsorption properties. J Polym Res 20:278. https://doi.org/10.1007/s10965-013-0278-2 CrossRef

Godt J, Scheidig F, Grosse-Siestrup C, Esche V, Brandenburg P, Reich A, Groneberg DA (2006) The toxicity of cadmium and resulting hazards for human health. J Occup Med Toxicol 1:22. https://doi.org/10.1186/1745-6673-1-22 CrossRefPubMedPubMedCentral

Gu J, Hsieh YL (2015) Surface and structure characteristics, self-assembling, and solvent compatibility of holocellulose nanofibrils. ACS Appl Mater Interfaces 7:4192–4201. https://doi.org/10.1021/am5079489 CrossRefPubMed

Gurgel LVA, Gil LF (2009a) Adsorption of Cu(II), Cd(II) and Pb(II) from aqueous single metal solutions by succinylated twice-mercerized sugarcane bagasse functionalized with triethylenetetramine. Water Res 43:4479–4488. https://doi.org/10.1016/j.watres.2009.07.017 CrossRefPubMed

Gurgel LVA, Gil LF (2009b) Adsorption of Cu(II), Cd(II), and Pb(II) from aqueous single metal solutions by succinylated mercerized cellulose modified with triethylenetetramine. Carbohydr Polym 77:142–149. https://doi.org/10.1016/j.carbpol.2008.12.014 CrossRef

Hao J, Xu S, Xu N, Li D, Linhardt RJ, Zhang Z (2017) Impact of degree of oxidation on the physicochemical properties of microcrystalline cellulose. Carbohydr Polym 155:483–490. https://doi.org/10.1016/j.carbpol.2016.09.012 CrossRefPubMed

Ho YS (2004) Citation review of Lagergren kinetic rate equation on adsorption reactions. Scientometrics 59:171–177CrossRef

Ho YS (2006) Review of second-order models for adsorption systems. J Hazard Mater B 136:681–689. https://doi.org/10.1016/j.jhazmat.2005.12.043 CrossRef

Hua M, Zhang S, Pan B, Zhang W, Lv L, Zhang Q (2012) Heavy metal removal from water/wastewater by nanosized metal oxides: a review. J Hazard Mater 211:317–331. https://doi.org/10.1016/j.jhazmat.2011.10.016 CrossRefPubMed

Ishii D, Kanazawa Y, Tatsumi D, Matsumoto T (2007) Effect of solvent exchange on the pore structure and dissolution behavior of cellulose. J Appl Polym Sci 103:3976–3984. https://doi.org/10.1002/app.25424 CrossRef

Jamshaid A et al (2017) Cellulose-based materials for the removal of heavy metals from wastewater—an overview. ChemBioEng Rev 4:240–256. https://doi.org/10.1002/cben.201700002 CrossRef

Järup L (2003) Hazards of heavy metal contamination. Br Med Bull 68:167–182. https://doi.org/10.1093/bmb/ldg032 CrossRefPubMed

Jia K et al (2008) Adsorption of Pb²⁺, Zn²⁺, and Cd²⁺ from waters by amorphous titanium phosphate. J Colloid Interface Sci 318:160–166. https://doi.org/10.1016/j.jcis.2007.10.043 CrossRefPubMed

Jiang F, Han S, Hsieh YL (2013) Controlled defibrillation of rice straw cellulose and self-assembly of cellulose nanofibrils into highly crystalline fibrous materials. RSC Adv 3:12366–12375. https://doi.org/10.1039/c3ra41646a CrossRef

Jin C, Zhang X, Xin J, Liu G, Wu G, Kong Z, Zhang J (2017) Clickable synthesis of 1, 2, 4-triazole modified lignin-based adsorbent for the selective removal of Cd(II). ACS Sustain Chem Eng 5:4086–4093. https://doi.org/10.1021/acssuschemeng.7b00072 CrossRef

Jomova K, Valko M (2011) Advances in metal-induced oxidative stress and human disease. Toxicology 283:65–87. https://doi.org/10.1016/j.tox.2011.03.001 CrossRefPubMed

Jun Z, Shanjing Y, Dongqiang L (2009) Adsorbents for expanded bed adsorption: preparation and functionalization. Chin J Chem Eng 17(4):678–687. https://doi.org/10.1016/S1004-9541(08)60263-3 CrossRef

Kardam A, Raj KR, Srivastava S, Srivastava MM (2013) Nanocellulose fibers for biosorption of cadmium, nickel, and lead ions from aqueous solution. Clean Technol Environ Policy 16:385–393. https://doi.org/10.1007/s10098-013-0634-2 CrossRef

Karim Z, Hakalahti M, Tammelin T, Mathew AP (2017) In situ TEMPO surface functionalization of nanocellulose membranes for enhanced adsorption of metal ions from aqueous medium. RSC Adv 7:5232–5241. https://doi.org/10.1039/c6ra25707k CrossRef

Karimi L, Mirjalili M, Yazdanshenas ME, Nazari A (2010) Effect of nano TiO₂ on self-cleaning property of cross-linking cotton fabric with succinic acid under UV irradiation. Photochem Photobiol 86:1030–1037. https://doi.org/10.1111/j.1751-1097.2010.00756.x CrossRefPubMed

Klemm D, Kramer F, Moritz S, Lindstrom T, Ankerfors M, Gray D, Dorris A (2011) Nanocelluloses: a new family of nature-based materials. Angew Chem Int Ed 50:5438–5466. https://doi.org/10.1002/anie.201001273 CrossRef

Krishna Kumar AS, Kalidhasan S, Rajesh V, Rajesh N (2013) Adsorptive demercuration by virtue of an appealing interaction involving biopolymer cellulose and mercaptobenzothiazole. Ind Eng Chem Res 52:11838–11849. https://doi.org/10.1021/ie400921p CrossRef

Lamanna M, Leiton L, Vega IN, Rivas BL, D’Accorso N (2017) New copolymers with triazole pendant groups: synthesis, characterization and their application to remove heavy metals. Adv Mater Sci. https://doi.org/10.15761/AMS.1000120 CrossRef

Langmuir I (1916) The constitution and fundamental properties of solids and liquids. J Am Chem Soc 38:2221–2295CrossRef

Leleyter L, Rousseau C, Biree L, Baraud F (2012) Comparison of EDTA, HCl and sequential extraction procedures, for selected metals (Cu, Mn, Pb, Zn), in soils, riverine and marine sediments. J Geochem Explor 116–117:51–59. https://doi.org/10.1016/j.gexplo.2012.03.006 CrossRef

Li G, Li L, Boerio-Goates J, Woodfield BF (2005) High purity anatase TiO₂ nanocrystals: near room-temperature synthesis, grain growth kinetics, and surface hydration chemistry. J Am Chem Soc 127:8659–8666. https://doi.org/10.1021/ja050517g CrossRefPubMed

Li MC, Wu Q, Song K, Lee SY, Yan Q, Wu Y (2015a) Cellulose nanoparticles: structure morphology rheology relationship. ACS Sustain Chem Eng 3(5):821–832. https://doi.org/10.1021/acssuschemeng.5b00144 CrossRef

Li Y, Cao L, Li L, Yang C (2015b) In situ growing directional spindle TiO₂ nanocrystals on cellulose fibers for enhanced Pb²⁺ adsorption from water. J Hazard Mater 289:140–148. https://doi.org/10.1016/j.jhazmat.2015.02.051 CrossRefPubMed

Li X, Bian C, Meng X, Xiao FS (2016a) Design and synthesis of an efficient nanoporous adsorbent for Hg²⁺ and Pb²⁺ ions in water. J Mater Chem A 4:5999–6005. https://doi.org/10.1039/c6ta00987e CrossRef

Li Y, Li L, Cao L, Yang C (2016b) Promoting dynamic adsorption of Pb²⁺ in a single pass flow using fibrous nano-TiO₂/cellulose membranes. Chem Eng J 283:1145–1153. https://doi.org/10.1016/j.cej.2015.08.068 CrossRef

Li M, Liu Z, Wang L, James TD, Xiao H-N, Zhu W (2017) Glutamic acid-modified cellulose fibrous composite for adsorption of heavy metal ions from single and binary solutions. Mater Chem Front. https://doi.org/10.1039/C7QM00210F CrossRef

Liang L, Astruc D (2011) The copper(I)-catalyzed alkyne-azide cycloaddition (CuAAC) “click” reaction and its applications. An overview. Coord Chem Rev 255:2933–2945. https://doi.org/10.1016/j.ccr.2011.06.028 CrossRef

Liu C, Baumann H (2005) New 6-butylamino-6-deoxycellulose and 6-deoxy-6-pyridiniumcellulose derivatives with highest regioselectivity and completeness of reaction. Carbohydr Res 340:2229–2235. https://doi.org/10.1016/j.carres.2005.07.018 CrossRefPubMed

Liu J et al (2014) Welan gum-modified cellulose bead as an effective adsorbent of heavy metal ions (Pb²⁺, Cu²⁺, and Cd²⁺) in aqueous solution. Sep Sci Technol 49:1096–1103. https://doi.org/10.1080/01496395.2013.872658 CrossRef

Luo Y, Xu J, Huang J (2014) Hierarchical nanofibrous anatase-titania–cellulose composite and its photocatalytic property. CrystEngComm 16:464–471. https://doi.org/10.1039/c3ce41906a CrossRef

Maatar W, Boufi S (2015) Poly(methacylic acid-co-maleic acid) grafted nanofibrillated cellulose as a reusable novel heavy metal ions adsorbent. Carbohydr Polym 126:199–207. https://doi.org/10.1016/j.carbpol.2015.03.015 CrossRefPubMed

Mahfoudhi N, Boufi S (2017) Nanocellulose as a novel nanostructured adsorbent for environmental remediation: a review. Cellulose. https://doi.org/10.1007/s10570-017-1194-0 CrossRef

Mansour Lakouraj M, Norouzian RS, Balo S (2015) Preparation and cationic dye adsorption of novel Fe₃O₄ supermagnetic/thiacalix[4]arene tetrasulfonate self-doped/polyaniline nanocomposite: kinetics, isotherms, and thermodynamic study. J Chem Eng Data 60:2262–2272. https://doi.org/10.1021/acs.jced.5b00080 CrossRef

Martina K, Baricco F, Berlier G, Caporaso M, Cravotto G (2014) Efficient green protocols for preparation of highly functionalized β-cyclodextrin-grafted silica. ACS Sustain Chem Eng 2:2595–2603. https://doi.org/10.1021/sc500546e CrossRef

Masoumi A, Hemmati K, Ghaemy M (2016) Low-cost nanoparticles sorbent from modified rice husk and a copolymer for efficient removal of Pb(II) and crystal violet from water. Chemosphere 146:253–262. https://doi.org/10.1016/j.chemosphere.2015.12.017 CrossRefPubMed

Massin J, Ducasse L, Toupance T, Cl Olivier (2014) Tetrazole as a new anchoring group for the functionalization of Tio₂ nanoparticles: a joint experimental and theoretical study. J Phys Chem C 118:10677–10685. https://doi.org/10.1021/jp502488g CrossRef

Meng X, Edgar KJ (2016) “Click” reactions in polysaccharide modification. Prog Polym Sci 53:52–85. https://doi.org/10.1016/j.progpolymsci.2015.07.006 CrossRef

Miao C, Hamad WY (2013) Cellulose reinforced polymer composites and nanocomposites: a critical review. Cellulose 20:2221–2262. https://doi.org/10.1007/s10570-013-0007-3 CrossRef

Mohammadinezhad A, Nasseri MA, Salimi M (2014) Cellulose as an efficient support for Mn(salen)Cl: application for catalytic oxidation of sulfides to sulfoxides. RSC Adv 4:39870–39874. https://doi.org/10.1039/c4ra06450j CrossRef

Morawski AW, Kusiak-Nejman E, Przepiórski J, Kordala R, Pernak J (2013) Cellulose-TiO₂ nanocomposite with enhanced UV–Vis light absorption. Cellulose 20:1293–1300. https://doi.org/10.1007/s10570-013-9906-6 CrossRef

Moses JE, Moorhouse AD (2007) The growing applications of click chemistry. Chem Soc Rev 36:1249–1262. https://doi.org/10.1039/b613014n CrossRefPubMed

O’Connell DW, Birkinshaw C, O’Dwyer TF (2008) Heavy metal adsorbents prepared from the modification of cellulose: a review. Bioresour Technol 99:6709–6724. https://doi.org/10.1016/j.biortech.2008.01.036 CrossRefPubMed

Olivera S, Muralidhara HB, Venkatesh K, Guna VK, Gopalakrishna K, Kumar Y (2016) Potential applications of cellulose and chitosan nanoparticles/composites in wastewater treatment: a review. Carbohydr Polym 153:600–618. https://doi.org/10.1016/j.carbpol.2016.08.017 CrossRefPubMed

Özlem Kocabaş-Ataklı Z, Yürüm Y (2013) Synthesis and characterization of anatase nanoadsorbent and application in removal of lead, copper and arsenic from water. Chem Eng J 225:625–635. https://doi.org/10.1016/j.cej.2013.03.106 CrossRef

Park H, Park Y, Kim W, Choi W (2013) Surface modification of TiO₂ photocatalyst for environmental applications. J Photochem Photobiol C Photochem Rev 15:1–20. https://doi.org/10.1016/j.jphotochemrev.2012.10.001 CrossRef

Peng P, Cao X, Peng F, Bian J, Xu F, Sun R (2012) Binding cellulose and chitosan via click chemistry: synthesis, characterization, and formation of some hollow tubes. J Polym Sci A Polym Chem 50:5201–5210. https://doi.org/10.1002/pola.26371 CrossRef

Peng Q et al (2014) Unique lead adsorption behavior of activated hydroxyl group in two-dimensional titanium carbide. J Am Chem Soc 136:4113–4116. https://doi.org/10.1021/ja500506k CrossRefPubMed

Pierre-Antoine F, Francois B, Rachida Z (2012) Crosslinked cellulose developed by CuAAC, a route to new materials. Carbohydr Res 356:247–251. https://doi.org/10.1016/j.carres.2011.10.028 CrossRefPubMed

Pujari SP, Scheres L, Marcelis ATM, Zuilhof H (2014) Covalent surface modification of oxide surfaces. Angew Chem Int Ed 53:2–36. https://doi.org/10.1002/anie.201306709 CrossRef

Qin X et al (2016) A green technology for the synthesis of cellulose succinate for efficient adsorption of Cd(II) and Pb(II) ions. RSC Adv 6:26817–26825. https://doi.org/10.1039/c5ra27280g CrossRef

Rahman ML, Sarkar SM, Yusoff MM, Abdullah MH (2016) Efficient removal of transition metal ions using poly(amidoxime) ligand from polymer grafted kenaf cellulose. RSC Adv 6:745–757. https://doi.org/10.1039/c5ra18502e CrossRef

Sabzi M, Mirabedini SM, Zohuriaan-Mehr J, Atai M (2009) Surface modification of TiO₂ nano-particles with silane coupling agent and investigation of its effect on the properties of polyurethane composite coating. Prog Org Coat 65:222–228. https://doi.org/10.1016/j.porgcoat.2008.11.006 CrossRef

Sadeghifar H, Filpponen I, Clarke SP, Brougham DF, Argyropoulos DS (2011) Production of cellulose nanocrystals using hydrobromic acid and click reactions on their surface. J Mater Sci 46:7344–7355. https://doi.org/10.1007/s10853-011-5696-0 CrossRef

Scherrer P (1918) Bestimmung der Größe und der inneren Struktur von Kolloidteilchen mittels Röntgenstrahlen. Nachr Ges Wiss Gottingen 2:98–100

Seidlerová J, Šafařík I, Rozumová L, Šafaříková M, Motyka O (2016) TiO₂-Based Sorbent of Lead Ions. Procedia Mater Sci 12:147–152. https://doi.org/10.1016/j.mspro.2016.03.026 CrossRef

Shahadat M, Teng TT, Rafatullah M, Arshad M (2015) Titanium-based nanocomposite materials: a review of recent advances and perspectives. Colloids Surf B 126:121–137. https://doi.org/10.1016/j.colsurfb.2014.11.049 CrossRef

Shirke BS, Korake PV, Hankare PP, Bamane SR, Garadkar KM (2011) Synthesis and characterization of pure anatase TiO₂ nanoparticles. J Mater Sci Mater Electron 22:821–824. https://doi.org/10.1007/s10854-010-0218-4 CrossRef

Su Y, Liu J, Yue Q, Li Q, Gao B (2015) Adsorption of lead and nickel ions by semi-interpenetrating network hydrogel based on wheat straw cellulose: kinetics, equilibrium, and thermodynamics. Soft Mater 13:225–236. https://doi.org/10.1080/1539445x.2015.1074923 CrossRef

Sun X, Yang L, Li Q, Zhao J, Li X, Wang X, Liu H (2014) Amino-functionalized magnetic cellulose nanocomposite as adsorbent for removal of Cr(VI): synthesis and adsorption studies. Chem Eng J 241:175–183. https://doi.org/10.1016/j.cej.2013.12.051 CrossRef

Tao P, Viswanath A, Li Y, Siegel RW, Benicewicz BC, Schadler LS (2013) Bulk transparent epoxy nanocomposites filled with poly (glycidyl methacrylate) brush-grafted TiO₂ nanoparticles. Polymer 54:1639–1646. https://doi.org/10.1016/j.polymer.2013.01.032 CrossRef

Temkin MJ, Pyzhev V (1940) Kinetics of ammonia synthesis on promoted iron catalysts. Acta Physicochim URSS 12:217–222

Thommes J, Halfar M, Lenz S, Kula MR (1995) Purification of monoclonal antibodies from whole hybridoma fermentation broth by fluidized bed adsorption. Biotechnol Bioeng 45:205–211CrossRef

Urankar D, Pinter B, Pevec A, De Proft F, Turel I, Košmrlj J (2010) Click-triazole N₂ coordination to transition-metal ions is assisted by a pendant pyridine substituent. Inorg Chem 49:4820–4829. https://doi.org/10.1021/ic902354e CrossRefPubMed

Vanhatalo K, Maximova N, Perander AM, Johansson LS, Haimi E, Dahl O (2016) Comparison of conventional and lignin-rich microcrystalline cellulose. BioResources 11(2):4037–4054CrossRef

Weber WJ, Morris JC (1963) Kinetics of adsorption on carbon from solution. J Sanit Eng Div 89(2):31–60

Wu CH, Kuo CY, Andy Hong PK, Chen MJ (2015) Removal of copper by surface-modified celluloses: kinetics, equilibrium, and thermodynamics. Desalin Water Treat 55(5):1253–1263. https://doi.org/10.1080/19443994.2014.926461 CrossRef

Xiong Y et al (2017) A 3D titanate aerogel with cellulose as the adsorption-aggregator for highly efficient water purification. J Mater Chem A 5:5813–5819. https://doi.org/10.1039/C6TA10638B CrossRef

Xue G (1987) Chemical reactions of an epoxy-functional silane in aqueous solution. Die Angew Makromol Chem 151:85–93CrossRef

Yadav P, Chacko S, Kumar G, Ramapanicker R, Verma V (2015) Click chemistry route to covalently link cellulose and clay. Cellulose 22:1615–1624. https://doi.org/10.1007/s10570-015-0594-2 CrossRef

Yang R, Aubrecht KB, Ma H, Wang R, Grubbs RB, Hsiao BS, Chu B (2014) Thiol-modified cellulose nanofibrous composite membranes for chromium(VI) and lead(II) adsorption. Polymer 55:1167–1176. https://doi.org/10.1016/j.polymer.2014.01.043 CrossRef

Yu X, Tong S, Ge M, Wu L, Zuo J, Cao C, Song W (2013) Adsorption of heavy metal ions from aqueous solution by carboxylated cellulose nanocrystals. J Environ Sci 25:933–943. https://doi.org/10.1016/s1001-0742(12)60145-4 CrossRef

Zhang J, Li L, Li Y, Yang C (2017) Microwave-assisted synthesis of hierarchical mesoporous nano-TiO₂/cellulose composites for rapid adsorption of Pb²⁺. Chem Eng J 313:1132–1141. https://doi.org/10.1016/j.cej.2016.11.007 CrossRef

Zhao X, Lv L, Pan B, Zhang W, Zhang S, Zhang Q (2011) Polymer-supported nanocomposites for environmental application: a review. Chem Eng J 170:381–394. https://doi.org/10.1016/j.cej.2011.02.071 CrossRef

Zhao J, Milanova M, Warmoeskerken MMCG, Dutschka V (2012) Surface modification of TiO₂ nanoparticles with silane coupling agents. Colloids Surf A Physicochem Eng Asp 413:273–279. https://doi.org/10.1016/j.colsurfa.2011.11.033 CrossRef

Zhong LS, Hu JS, Wan LJ, Song WG (2008) Facile synthesis of nanoporous anatase spheres and their environmental applications. Chem Commun. https://doi.org/10.1039/b718300c CrossRef

Zhong L, Peng X, Yang D, Sun R (2012) Adsorption of heavy metals by a porous bioadsorbent from lignocellulosic biomass reconstructed in an ionic liquid. J Agric Food Chem 60:5621–5628. https://doi.org/10.1021/jf301182x CrossRefPubMed

Zhou Y, Hu X, Zhang M, Zhuo X, Niu J (2013) Preparation and characterization of modified cellulose for adsorption of Cd(II), Hg(II), and acid fuchsin from aqueous solutions. Ind Eng Chem Res 52:876–884. https://doi.org/10.1021/ie301742h CrossRef

Zhou Y, Fu S, Zhang L, Zhan H, Levit MV (2014) Use of carboxylated cellulose nanofibrils-filled magnetic chitosan hydrogel beads as adsorbents for Pb(II). Carbohydr Polym 101:75–82. https://doi.org/10.1016/j.carbpol.2013.08.055 CrossRefPubMed

Title: TiO2-grafted cellulose via click reaction: an efficient heavy metal ions bioadsorbent from aqueous solutions
Authors: Zari Fallah
Hossein Nasr Isfahani
Mahmood Tajbakhsh
Hamed Tashakkorian
Abdoliman Amouei
Publication date: 16-11-2017
Publisher: Springer Netherlands
Published in: Cellulose / Issue 1/2018
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-017-1563-8

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Other articles of this Issue 1/2018

Effect of fibril length, aspect ratio and surface charge on ultralow shear-induced structuring in micro and nanofibrillated cellulose aqueous suspensions

Cellulose nanocrystals as reinforcements for collagen-based casings with low gas transmission

Study of humidity-responsive behavior in chiral nematic cellulose nanocrystal films for colorimetric response

Synthesis of cellulose acetate propionate and cellulose acetate butyrate in a CO2/DBU/DMSO system

Exploring the composition of raw and delignified Colombian fique fibers, tow and pulp

The role of mechanical action in the process of the thermomechanical isolation of lignin