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Journal of Materials Science: Materials in Electronics

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01-04-2009

Tolerance factor and the stability discussion of ABO₃-type ilmenite

Authors: XiangChun Liu, Rongzi Hong, Changsheng Tian

Published in: Journal of Materials Science: Materials in Electronics | Issue 4/2009

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Abstract

The tolerance factor of ABO₃-type ilmenite by analyzing the ABO₃ ilmenite crystal structure is established. Combining with the electronegativity difference and octahedral factor of ABO₃ structure, regularities governing the formation and the stability of ilmenite-type compounds are discussed. The tolerance factor equation was proved appropriate for ilmenite structure by analyzing the structure stability of some ilmenite compounds. According to the results of statistically analyzing the tolerance factor and electronegativity difference of the present ABO₃-type ilmenite, the experience tolerance factor value and experience electronegativity difference value to form stable ilmenite compound were obtained, that is, t > 0.80 and e > 1.465, and the lowest limit of the octahedral factor \( \left( {R_M /R_{O^{2 - } } } \right) \) for ilmenite formation is 0.48.

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Title: Tolerance factor and the stability discussion of ABO3-type ilmenite
Authors: XiangChun Liu
Rongzi Hong
Changsheng Tian
Publication date: 01-04-2009
Publisher: Springer US
Published in: Journal of Materials Science: Materials in Electronics / Issue 4/2009
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-008-9728-8

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