Top

Published in:

01-06-2023 | Research paper

Toluene combustion on MnO_x, CeO₂, and Mn-Ce-O solids prepared via citrate complexation, and citrate and urea combustion methods

Authors: Salima Rahou, Amel Benadda-Kordjani, Svetlana Ivanova, José Antonio Odriozola, Redouane Chebout, Hakim Mahzoul, Nabila Zouaoui

Published in: Journal of Nanoparticle Research | Issue 6/2023

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

MnO_x, CeO₂, and MnCe-O (Mn/Ce = 1) solids have been prepared via the citrate complexation and combustion method using citrate and urea precursors. The solids have been characterized by XRD, SEM-EDX, N₂-adsorption-desorption, UV-Vis spectroscopy, TPR, O₂-TPD, and XPS techniques. The catalytic reactivity of the manganese oxides was not affected by the preparation protocol. In the case of ceria and mixed oxides, the synthesis method greatly affected the structural and chemical properties, ultimately altering their reactivity. The citrate complexation method produced the most homogeneous and active mixed oxide, whereas the urea combustion method resulted in less active solids. The mixed oxide prepared via urea combustion was less active than the manganese single oxide; the decrease in activity was attributed to phase separation and the formation of Mn₃O₄ domains on the surface of ceria. In contrast, citrate complexation resulted in solids with the lowest particle size (~ 3 nm), the highest oxidation state for manganese, and the highest proportion of oxygen vacancies, which promote the oxidation reaction.

previous article DNA:TiO2 nanoparticle nanoassemblies: effect of temperature and nanoparticle concentration on aggregation

next article Synthesis and characterization of MSN/Fe3O4/Gd2O3 nanocomposite as theranostic systems

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Available only for authorised users

Spivey JJ (1987) Complete catalytic oxidation of volatile organics. Ind Eng Chem Res 26:2165–2180. https://doi.org/10.1021/ie00071a001CrossRef

Miao L, Wang J, Zhang P (2019) Review on manganese dioxide for catalytic oxidation of airborne formaldehyde. Appl Surf Sci 466:441–453. https://doi.org/10.1016/j.apsusc.2018.10.031CrossRef

Liu D, Li Q, Hou J, Zhao H (2021) Mixed-valent manganese oxide for catalytic oxidation of Orange II by activation of persulfate: heterojunction dependence and mechanism. Catal Sci Technol 11:3715–3723. https://doi.org/10.1039/d1cy00087jCrossRef

Li Y, Xiao L, Liu F, Dou Y, Liu S, Fan Y, Cheng G, Song W, Zhou J (2019) Core-shell structure Ag@Pd nanoparticles supported on layered MnO₂ substrate as toluene oxidation catalyst. J Nanoparticle Res 21(183):28–36. https://doi.org/10.1007/s11051-019-4467-8CrossRef

Yao HC, Yao YFY (1984) Ceria in automotive exhaust catalysts. I. Oxygen storage. J Catal 86:254–265. https://doi.org/10.1016/0021-9517(84)90371-3CrossRef

Duprez D, Descorme C, Birchem T, Rohart E (2001) Oxygen storage and mobility on model three-way catalysts. Top Catal 16(17):49–56. https://doi.org/10.1023/A:1016622612521CrossRef

Palmqvist AEC, Johansson EM, Järås SG, Muhammed M (1998) Total oxidation of methane over doped nanophase cerium oxides. Catal Letters 56:69–75. https://doi.org/10.1023/A:1019032306894CrossRef

Liao Y, Fu M, Chen L, Wu J, Huang B, Ye D (2013) Catalytic oxidation of toluene over nanorod-structured Mn-Ce mixed oxides. Catal Today 216:220–228. https://doi.org/10.1016/j.cattod.2013.06.017CrossRef

Sato T, Komanoya T (2009) Selective oxidation of alcohols with molecular oxygen catalyzed by Ru/MnO_x/CeO₂ under mild conditions. Catal Commun 10:1095–1098. https://doi.org/10.1016/j.catcom.2009.01.004CrossRef

10.

Hong WJ, Iwamoto S, Hosokawa S, Wada K, Kanai H, Inoue M (2011) Effect of Mn content on physical properties of CeO_x-MnO_y support and BaO-CeO_x-MnO_y catalysts for direct NO decomposition. J Catal 277:208–216. https://doi.org/10.1016/j.jcat.2010.11.007CrossRef

11.

Tang X, Chen J, Li Y, Li Y, Xu Y, Shen W (2006) Complete oxidation of formaldehyde over Ag/MnO_x-CeO₂ catalysts. Chem Eng Journal 118:119–125. https://doi.org/10.1016/j.cej.2006.02.002CrossRef

12.

Shi L, Chu W, Qu F, Luo S (2007) Low-temperature catalytic combustion of methane over MnO_x-CeO₂ mixed oxide catalysts: effect of preparation method. Catal Letters 113:59–64. https://doi.org/10.1007/s10562-006-9012-6CrossRef

13.

Sudarsanam P, Hillary B, Deepa DK, Amin MH, Mallesham B, Benjaram MR, Suresh KB (2015) Highly efficient cerium dioxide nanocube-based catalysts for low temperature diesel soot oxidation: the cooperative effect of cerium- and cobalt-oxides. Catal Sci Technol 5:3496–3500. https://doi.org/10.1039/c5cy00525fCrossRef

14.

Nagasawa T, Matsumoto K, Minegishi N, Kosaka H (2021) Structural Characterization of ceria-supported Pt nanoparticles by flame-assisted spray pyrolysis using a burner diffusion flame. Energy and Fuels 35:12380–12391. https://doi.org/10.1021/acs.energyfuels.1c01296CrossRef

15.

Issa G, Dimitrov M, Ivanova R, Kormunda M, Kovacheva D, Tsoncheva T (2022) Mixed oxides of cerium and manganese as catalysts for total oxidation of ethyl acetate: effect of preparation procedure. React Kinet Mech Catal 135:105–121. https://doi.org/10.1007/s11144-021-02135-0CrossRef

16.

Chen J, Chen X, Yan D, Jiang M, XuW YH, Jia H (2019) A facile strategy of enhancing interaction between cerium and manganese oxides for catalytic removal of gaseous organic contaminants. Appl Catal B Environ 250:396–407. https://doi.org/10.1016/j.apcatb.2019.03.042CrossRef

17.

Yan B, Zhu ÆH (2008) Controlled synthesis of CeO₂ nanoparticles using novel amphiphilic cerium complex precursors. J Nanoparticle Res 10:1279–1285. https://doi.org/10.1007/s11051-008-9371-6CrossRef

18.

Yang S, Zhou F, Liu Y, Zhang L, Chen Y, Wang H, Tian Y, Zhang C, Liu D (2019) Morphology effect of ceria on the performance of CuO/CeO₂ catalysts for hydrogen production by methanol steam reforming. Int J Hydrogen Energy 44:7252–7261. https://doi.org/10.1016/j.ijhydene.2019.01.254CrossRef

19.

Farooq U, Phul R, Alshehri SM, Ahmed J, Ahmad T (2019) Electrocatalytic and enhanced photocatalytic applications of sodium niobate nanoparticles developed by citrate precursor route. Sci Rep 9:1–17. https://doi.org/10.1038/s41598-019-40745-wCrossRef

20.

Huang Y, Cheng X, Li Y, Shi D, Li G, Xu K (2018) Effect of sol-gel combustion synthesis of nanoparticles on thermal properties of KNO₃-NaNO₃. Sol Energy Mater Sol Cells 188:190–201. https://doi.org/10.1016/j.solmat.2018.09.006CrossRef

21.

Ravishankar TN, Ramakrishnappa T, Nagaraju G, Rajanaika H (2015) Synthesis and characterization of CeO₂ nanoparticles via solution combustion method for photocatalytic and antibacterial activity studies. Chemistry Open 4:146–154. https://doi.org/10.1002/open.201402046CrossRef

22.

Ghahramani Z, Arabi AM, Shafiee Afarani M, Mahdavian M (2020) Solution combustion synthesis of cerium oxide nanoparticles as corrosion inhibitor. Int J Appl Ceram Technol 17:1514–1521. https://doi.org/10.1111/ijac.13365CrossRef

23.

Lei Z, Hao S, Yang J, Zhang L, Fang B, Wei K, Lingbo Q, Jin S, Wei C (2021) Study on denitration and sulfur removal performance of Mn-Ce supported fly ash catalyst. Chemosphere 270:128646. https://doi.org/10.1016/j.chemosphere.2020.128646CrossRef

24.

Xiao X, Wang J, Jia X, Ma C, Qiao W, Ling L (2021) Low-temperature selective catalytic reduction of NO_x with NH₃ over Mn-Ce composites synthesized by polymer-assisted deposition. ACS Omega 6:12801–12812. https://doi.org/10.1021/acsomega.1c01123CrossRef

25.

Zhu X, Liu S, Cai Y, Gao X, Zhou J, Zheng C, Tu X (2016) Post-plasma catalytic removal of methanol over Mn-Ce catalysts in an atmospheric dielectric barrier discharge. Appl Catal B Environ 183:124–132. https://doi.org/10.1016/j.apcatb.2015.10.013CrossRef

26.

He F, Chen Y, Zhao P, Liu S (2016) Effect of calcination temperature on the structure and performance of CeO_xMnO_x/TiO₂ nanoparticles for the catalytic combustion of chlorobenzene. J Nanoparticle Res 18(19):2269–2276. https://doi.org/10.1007/s11051-016-3428-8CrossRef

27.

Delimaris D, Ioannides T (2008) VOC oxidation over MnO_x-CeO₂ catalysts prepared by a combustion method. Appl Catal B Environ 84:303–312. https://doi.org/10.1016/j.apcatb.2008.04.006CrossRef

28.

Marinsek M, Zupan K, Jadran M (2002) Ni-YSZ cermet anodes prepared by citrate/nitrate combustion synthesis. J Power Sources 106:178–188. https://doi.org/10.1016/S0378-7753(01)01056-4CrossRef

29.

Hattori T, Nishiyama S, Kishi Y, Iwadate Y (1993) Characterization of perovskite-type GdFeO₃ powders prepared by amorphous citrate process. J Mater Sci Lett 12:883–885. https://doi.org/10.1007/BF00455606CrossRef

30.

Juárez RE, Lamas DG, Lascalea GE, Walsöe de Reca NE (2000) Synthesis of nanocrystalline zirconia powders for TZP ceramics by a nitrate-citrate combustion route. J of the Euro Cera Soc 20:133–138. https://doi.org/10.1016/S0955-2219CrossRef

31.

Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KSW (2015) Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure Appl Chem 87:1051–1069. https://doi.org/10.1515/pac-2014-1117CrossRef

32.

Li TY, Chiang SJ, Liaw BJ, Chen YZ (2011) Catalytic oxidation of benzene over CuO/Ce_1-xMn_xO₂ catalysts. Appl Catal B Environ 103:143–148. https://doi.org/10.1016/j.apcatb.2011.01.020CrossRef

33.

Cui M, Li Y, Wang X, Wang J, Shen M (2013) Effect of preparation method on MnO_x-CeO₂ catalysts for NO oxidation. J Rare Earths 31:572–576. https://doi.org/10.1016/S1002-0721(12)60322-6CrossRef

34.

Li H, Lu G, Dai Q, Wang Y, Guo Y, Guo Y (2011) Efficient low-temperature catalytic combustion of trichloroethylene over flower-like mesoporous Mn-doped CeO₂ microspheres. Appl Catal B Environ 102:475–483. https://doi.org/10.1016/.apcatb.2010.12.029CrossRef

35.

Rao T, Shen M, Jia L, Hao J, Wang J (2007) Oxidation of ethanol over Mn-Ce-O and Mn-Ce-Zr-O complex compounds synthesized by sol-gel method. Catal Commun 8:1743–1747. https://doi.org/10.1016/j.catcom.2007.01.036CrossRef

36.

Tok AIY, Du SW, Boey FYC, Chong WK (2007) Hydrothermal synthesis and characterization of rare earth doped ceria nanoparticles. Mater Sci Eng A 466:223–229. https://doi.org/10.1016/j.msea.2007.02.083CrossRef

37.

Zhao Q, Shih WH (2002) Effects of processing parameters on the surface area of Mn₂O₃ at elevated temperatures. Microporous Mesoporous Mater 53:81–86. https://doi.org/10.1016/S1387-1811(02)00326-8CrossRef

38.

Gnanam S, Rajendran V (2013) Facile hydrothermal synthesis of alpha manganese sesquioxide (α-Mn₂O₃) nanodumb-bells: structural, magnetic, optical and photocatalytic properties. J Alloys Compd 550:463–470. https://doi.org/10.1016/j.jallcom.2012.10.172CrossRef

39.

Zhang X, Li H, Hou F, Yang Y, Dong H, Liu N, Wang Y, Cui L (2017) Synthesis of highly efficient Mn₂O₃ catalysts for CO oxidation derived from Mn-MIL-100. Appl Surf Sci 411:27–33. https://doi.org/10.1016/j.apsusc.2017.03.179CrossRef

40.

Dai Y, Wang X, Dai Q, Li D (2012) Effect of Ce and La on the structure and activity of MnOx catalyst in catalytic combustion of chlorobenzene. Appl Catal B Environ 111–112:141–149. https://doi.org/10.1016/j.apcatb.2011.09.028CrossRef

41.

Parashar M, Shukla VK, Singh R (2020) Metal oxides nanoparticles via sol–gel method: a review on synthesis, characterization and applications. J Mater Sci Mater Electron 31:3729–3749. https://doi.org/10.1007/s10854-020-02994-8CrossRef

42.

Singh AK, Dhiman TK, Lakshmi VSGB, Solanki PR (2021) Dimanganese trioxide (Mn₂O₃) based label-free electrochemical biosensor for detection of Aflatoxin-B1. Bioelectrochemistry 137:107684. https://doi.org/10.1016/j.bioelechem.2020.107684CrossRef

43.

Jampaiah D, Tur KM, Ippolito SJ, Sabri YM, Tardio J, Bhargava SK, Reddy BM (2013) Structural characterization and catalytic evaluation of transition and rare earth metal doped ceria-based solid solutions for elemental mercury oxidation. RSC Adv 3:12963–12974. https://doi.org/10.1039/c3ra41441hCrossRef

44.

Ranga RG, Ranjan SH (2001) XRD and UV-Vis diffuse reflectance analysis of CeO₂-ZrO₂ solid solutions synthesized by combustion method. Proc Indian Acad Sci Chem Sci 113:651–658. https://doi.org/10.1007/BF02708797CrossRef

45.

Gonzalez CM, Reina TR, Ivanova S, Centeno MA, Odriozola JA (2014) Pt vs. Au in water-gas shift reaction. J Catal 314:1–9. https://doi.org/10.1016/j.jcat.2014.03.014CrossRef

46.

Seo J, Gowda A, Babu SV (2018) Almost complete removal of ceria particles down to 10nm size from silicon dioxide surfaces. ECS J Solid State Sci Technol 7:P243–P252. https://doi.org/10.1149/2.0131805jssCrossRef

47.

Lian J, Liu P, Jin C, Shi Z, Luo X, Liu Q (2019) Perylene diimide-functionalized CeO₂ nanocomposite as a peroxidase mimic for colorimetric determination of hydrogen peroxide and glutathione. Microchim Acta 90:6247–6252. https://doi.org/10.1021/acs.analchem.8b00885CrossRef

48.

Ma L, Wang X, Wang J, Zhang J, Yin C, Fan L, Zhang D (2021) Graphene oxide-cerium oxide hybrids for enhancement of mechanical properties and corrosion resistance of epoxy coatings. J Mater Sci 56:10108–10123. https://doi.org/10.1007/s10853-021-05932-zCrossRef

49.

Wang J, Wan C, Cheng DG, Chen F, Zhan X (2021) Unveiling the morphology dependence of ceria nanocrystals for boosting low-temperature cyclohexane oxidative dehydrogenation. Appl Surf Sci 565:150–609. https://doi.org/10.1016/j.apsusc.2021.150609CrossRef

50.

Grissa R, Martinez H, Cotte S, Galipaud J, Pecquenard B, Le Cras F (2017) Thorough XPS analyses on overlithiated manganese spinel cycled around the 3V plateau. Appl Surf Sci 411:449–456. https://doi.org/10.1016/j.apsusc.2017.03.205CrossRef

51.

Bigiani L, Maccato C (2020) MnO₂ nanomaterials functionalized with Ag and SnO₂: an XPS study MnO₂ nanomaterials functionalized with Ag and SnO₂ : An XPS study. Surface Science Spectra 27:024005. https://doi.org/10.1116/6.0000332CrossRef

52.

Wenxiang T, Xiaofeng WU, Gang LIU, Shuangde LI (2015) Preparation of hierarchical layer-stacking Mn-Ce composite oxide for catalytic total oxidation of VOCs. J Rare Earths 33:62–69. https://doi.org/10.1016/S1002-0721(14)60384-7CrossRef

53.

Wu Z, Jiang B, Liu Y (2008) Effect of transition metals addition on the catalyst of manganese/titania for low-temperature selective catalytic reduction of nitric oxide with ammonia. Appl Catal B: Environ 79:347–355. https://doi.org/10.1016/j.apcatb.2007.09.039CrossRef

54.

Xingyi W, Qian K, Dao L (2009) Catalytic combustion of chlorobenzene over MnO_x -CeO₂ mixed oxide catalysts. Appl Catal B Environ 86:166–175. https://doi.org/10.1016/j.apcatb.2008.08.009CrossRef

55.

Zhang P, Lu H, Zhou Y, Zhang L, Wu Z, Yang S, Shi H, Zhu Q, Chen Y, Dai S (2015) Mesoporous MnCeO_x solid solutions for low temperature and selective oxidation of hydrocarbons. Nat Commun 6:8446. https://doi.org/10.1038/ncomms9446CrossRef

56.

Wang X, Kang Q, Li D (2008) Low-temperature catalytic combustion of chlorobenzene over MnO_x-CeO₂ mixed oxide catalysts. Catal Commun 9:2158–2162. https://doi.org/10.1016/j.catcom.2008.04.021CrossRef

57.

Wang Z, Shen G, Li J, Liu H, Wang Q, Chen Y (2013) Catalytic removal of benzene over CeO₂-MnO_x composite oxides prepared by hydrothermal method. Appl Catal B Environ 139:253–259. https://doi.org/10.1016/j.apcatb.2013.02.030CrossRef

58.

Andreoli S, Deorsola FA, Pirone R (2015) MnO_x-CeO₂ catalysts synthesized by solution combustion synthesis for the low-temperature NH₃-SCR. Catal. Today 253:199–206. https://doi.org/10.1016/j.apcatb.2013.02.030CrossRef

59.

Kapteljn F, Smgoredjo L, Andreml A (1994) Activity and selectivity of pure manganese oxides in the selective catalytic reduction of nitric oxide with ammonia. Appl Catal B Environ 3:173–189. https://doi.org/10.1016/0926-3373(93)E0034-9CrossRef

60.

Chen H, Sayari A, Adnot A, Larachi F (2001) Composition-activity effects of Mn-Ce -O composites on phenol catalytic wet oxidation. Appl Catal B Environ 32:195–204. https://doi.org/10.1016/S0926-3373(01)00136-9CrossRef

61.

Fernández-García M, Martínez-Arias A, Iglesias-Juez A, Belver C, Hungria AB, Conesa JC, Soria J (2000) Structural characteristics and redox behavior of CeO₂-ZrO₂/Al₂O₃ supports. J Catal 194:385–392. https://doi.org/10.1006/jcat.2000.2931CrossRef

62.

Binet C, Daturi M, Lavalley J (1999) IR study of polycrystalline ceria properties in oxidised and reduced states. Catal Tod 50:207–225. https://doi.org/10.1016/S0920-5861(98)00504-5CrossRef

63.

Trovarelli A (2002) Catalysis by ceria and related materials. Imperial College Press, LondonCrossRef

64.

Chen Y, Zheng H, Guo Z, Zhou C, Wang C, Borgna A, Yang Y (2011) Pd catalysts supported on MnCeO_x mixed oxides and their catalytic application in solvent-free aerobic oxidation of benzyl alcohol: support composition and structure sensitivity. J Catal 283:34–44. https://doi.org/10.1016/j.jcat.2011.06.021CrossRef

65.

Machida M, Uto M, Kurogi D, Kijima T (2000) MnO_x-CeO₂ binary oxides for catalytic NO_x sorption at low temperatures. Sorptive Removal of NOx. Chem Mater 12:3158–3164. https://doi.org/10.1021/cm000207CrossRef

66.

Zhang C, Wang C, Zhan W, Guo Y, Guo Y, Lu G, Baylet A, Giroir-Fendler A (2013) Catalytic oxidation of vinyl chloride emission over LaMnO₃ and LaB_0.2Mn_0.8O₃ (B=Co, Ni, Fe) catalysts. Appl Catal B Environ 129:509–516. https://doi.org/10.1016/j.apcatb.2012.09.056CrossRef

67.

Zhang Y, Qin Z, Wang G, Zhu H, Dong M, Li S, Wu Z, Wu Z, Zhang J, Hu T, Fan W, Wang J (2013) Catalytic performance of MnO_x-NiO composite oxide in lean methane combustion at low temperature. Appl Catal B Environ 129:172–181. https://doi.org/10.1016/j.apcatb.2012.09.021CrossRef

68.

Li J, Li L, Cheng W, Wu F, Lu X, Li Z (2014) Controlled synthesis of diverse manganese oxide-based catalysts for complete oxidation of toluene and carbon monoxide. Chem Eng J 244:59–67. https://doi.org/10.1016/j.cej.2014.01.041CrossRef

69.

Döbber D, Kießling D, Schmitz W, Wendt G (2004) MnO_x/ZrO₂ catalysts for the total oxidation of methane and chloromethane. Appl Catal B Environ 52:135–143. https://doi.org/10.1016/j.apcatb.2004.02.012CrossRef

70.

Kim HJ, Choi S, Inyang HI (2008) Catalytic oxidation of toluene in contaminant emission control systems using Mn-Ce/γ-Al₂O₃. Environ Technol 29:559–569. https://doi.org/10.1080/09593330801984597CrossRef

71.

Zhang C, Chu W, Chen F, Li L, Jiang R, Yan J (2020) Effects of cerium precursors on surface properties of mesoporous CeMnO_x catalysts for toluene combustion. J Rare Earths 38:70–75. https://doi.org/10.1016/j.jre.2019.04.013CrossRef

72.

Du J, Qu Z, Dong C, Song L, Qin Y, Huang N (2018) low-temperature abatement of toluene over Mn-Ce oxides catalysts synthesized by a modified hydrothermal approach. Appl Surf Sci 433:1025–1035. https://doi.org/10.1016/j.apsusc.2017.10.116CrossRef

73.

Wang F, Dai H, Deng J, Bai G, Ji K, Liu Y (2012) Manganese oxides with rod-, wire-, tube-, and flower-like morphologies: highly effective catalysts for the removal of toluene. Environ Sci Technol 46:4034–4041. https://doi.org/10.1021/es204038jCrossRef

74.

Lamaita L, Peluso MA, Sambeth JE, Thomas HJ (2005) Synthesis and characterization of manganese oxides employed in VOCs abatement. Appl Catal B Environ 61:114–119. https://doi.org/10.1016/j.apcatb.2005.03.014CrossRef

75.

Zhou G, Lan H, Wang H, Xie H, Zhang G, Zheng X (2014) Catalytic combustion of PVOCs on MnO x catalysts. J Mol Catal A Chem 393:279–288. https://doi.org/10.1016/j.molcata.2014.06.028CrossRef

76.

López JM, Gilbank AL, García T, Solsona B, Agouram S, Torrente-murciano L (2015) The prevalence of surface oxygen vacancies over the mobility of bulk oxygen in nanostructured ceria for the total toluene oxidation. Appl Catal B Environ 174–175:403–412. https://doi.org/10.1016/j.apcatb.2015.03.017CrossRef

77.

Zhang X, Li H, Song Z, Liu W, Liu Z, Mo D, Gao H, Zhang M (2022) In situ DRIFT spectroscopy study into the reaction mechanism of toluene over CeMo catalysts. J Environ Chem Eng 10:108895. https://doi.org/10.1016/j.jece.2022.108895CrossRef

Title: Toluene combustion on MnOx, CeO2, and Mn-Ce-O solids prepared via citrate complexation, and citrate and urea combustion methods
Authors: Salima Rahou
Amel Benadda-Kordjani
Svetlana Ivanova
José Antonio Odriozola
Redouane Chebout
Hakim Mahzoul
Nabila Zouaoui
Publication date: 01-06-2023
Publisher: Springer Netherlands
Published in: Journal of Nanoparticle Research / Issue 6/2023
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-023-05759-6

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 6/2023

Assessment of gemcitabine hydrochloride-based nanotherapeutics in cancer: a proof of concept study

A nanotherapeutic approach for fighting the odds against the malignant disorders

On surface pre-melting of metallic nanoparticles: molecular dynamics study

Effect of AgS/SiO QDs surface structure on luminescence photostability

Synthesis and characterization of MSN/Fe3O4/Gd2O3 nanocomposite as theranostic systems

In situ transmission electron microscopy to monitor phase transitions in metal-organic frameworks

Premium Partners