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Polymer Bulletin
Published in: Polymer Bulletin 5/2018

19-07-2017 | Original Paper

Waterborne polyurethane/Fe3O4-synthetic talc composites: synthesis, characterization, and magnetic properties

Authors: Leonardo M. dos Santos, Rosane Ligabue, Angela Dumas, Christophe Le Roux, Pierre Micoud, Jean-François Meunier, François Martin, Marta Corvo, Pedro Almeida, Sandra Einloft

Published in: Polymer Bulletin | Issue 5/2018

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Abstract

Nano-Fe3O4-synthetic talc gel was used as filler in the synthesis of waterborne polyurethane/Fe3O4-synthetic talc nanocomposites. This filler presents numerous edges (Si–O and Mg–O) and OH groups easily forming hydrogen bonds and polar interaction with water conferring hydrophilic character, consequently improving filler dispersion within a water-based matrix. Yet, the use of waterborne polyurethane (WPU) as matrix must be highlighted due to its environmentally friendly characteristics and low toxicity compared to solvent-based product. Fe3O4-synthetic talc-nanofillers were well dispersed into the polyurethane matrix even at high filler content as supported by XRD and TEM analyses. NMR indicates the interaction of filler OH groups with the matrix. For all nanocomposites, one can see a typical ferromagnetic behavior below Curie temperature (about 120 K) and a superparamagnetic behavior above this temperature. The use of Fe3O4-synthetic talc for obtaining magnetic nanocomposites resulted in improved materials with superior mechanical properties compared to solvent-based nanocomposites.
previous article Novel poly(vinyl chloride) nanocomposite films containing α-Al2O3 nanoparticles capped with vitamin B1: preparation, morphological, and thermal characterization
next article Tailoring strategies of polyalkylene glycol ester for varied lube applications

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Appendix
Available only for authorised users
Literature
1.
Kirchberg S, Rudolph M, Ziegmann G, Peuker UA (2012) Nanocomposites based on technical polymers and sterically functionalized soft magnetic magnetite nanoparticles: synthesis, processing, and characterization. J Nanomater 2012:1–8CrossRef
2.
Mohammadi A, Barikani M, Lakouraj MM (2016) Biocompatible polyurethane/thiacalix[4]arenes functionalized Fe3O4 magnetic nanocomposites: synthesis and properties. Mater Sci Eng C Mater Biol Appl 66:106–118CrossRef
3.
Yan F, Li J, Zhang J, Liu F, Yang W (2009) Preparation of Fe3O4/polystyrene composite particles from monolayer oleic acid modified Fe3O4 nanoparticles via miniemulsion polymerization. J Nanopart Res 11:289–296CrossRef
4.
Balakrishnan S, Bonder MJ, Hadjipanayis GC (2009) Particle size effect on phase and magnetic properties of polymer-coated magnetic nanoparticles. J Magn Magn Mater 321:117–122CrossRef
5.
Giri SK, Pradhan GC, Das N (2014) Thermal, electrical and tensile properties of synthesized magnetite/polyurethane nanocomposites using magnetite nanoparticles derived from waste iron ore tailing. J Polym Res 21:446CrossRef
6.
Dallas P, Georgakilas V, Niarchos D, Komninou P, Kehagias T, Petridis D (2006) Synthesis, characterization and thermal properties of polymer/magnetite nanocomposites. Nanotechnology 17:2046–2053CrossRef
7.
Dumas A, Gardes E, Le Roux C, Martin F, Micoud P (2013) Process for preparing a magnetic talcous composition and magnetic talcous composition. PCT Int. Pat. Appl. WO 2013093376 A1 June 27 2013 Fr. Pat. Appl. FR 2984872 A1 June 28 2013
8.
Dumas A, Le Roux C, Martin F, Micoud P (2013) Process for preparing a composition comprising synthetic mineral particles and composition. PCT Int. Pat. Appl. WO 2013004979 A1 Jan 10 2013 Fr. Pat. FR 2977580 B1 August 16 2013
9.
dos Santos LM, Ligabue R, Dumas A, Le Roux C, Micoud P, Meunier J-F, Martin F, Einloft S (2015) New magnetic nanocomposites: polyurethane/Fe3O4-synthetic talc. Eur Polym J 69:38–49CrossRef
10.
Dias G, Prado MA, Carone C, Ligabue R, Dumas A, Martin F, Le Roux C, Micoud P, Einloft S (2015) Synthetic silico-metallic mineral particles (SSMMP) as nanofillers: comparing the effect of different hydrothermal treatments on the PU/SSMMP nanocomposites properties. Polym Bull 7:2991–3006CrossRef
11.
Dias G, Prado MA, Carone C, Ligabue R, Dumas A, Martin F, Le Roux C, Micoud P, Einloft S (2016) Comparing different synthetic talc as fillers for polyurethane nanocomposites. Macromol Symp 367:136–142CrossRef
12.
Prado MA, Dias G, Carone C, Ligabue R, Dumas A, Martin F, Le Roux C, Micoud P, Einloft S (2015) Synthetic Ni-talc as filler for producing polyurethane nanocomposites. J Appl Polym Sci 132:41854CrossRef
13.
Yousfi M, Livi S, Dumas A, Le Roux C, Crépin-Leblond J, Greenhill-Hooper M, Duchet-Rumeau J (2013) Use of new synthetic talc as reinforcing nanofillers for polypropylene and polyamide 6 systems: thermal and mechanical properties. J Colloid Interf Sci 403:29–42CrossRef
14.
Yousfi M, Livi S, Dumas A, Crépin-Leblond J, Greenhill-Hooper M, Duchet-Rumeau J (2014) Compatibilization of polypropylene/polyamide 6 blends using new synthetic nanosized talc fillers: morphology, thermal and mechanical properties. J Appl Polym Sci 131:40453
15.
Dumas A, Claverie M, Slostowski C, Aubert G, Careme C, Le Roux C, Micoud P, Martin F, Aymonier C (2016) Fast-geomimicking using chemistry in supercritical water. Angew Chem 128:1–5CrossRef
16.
Wang G, Ma G, Hou CA, Guan T, Ling L, Wang B (2014) Preparation and properties of waterborne polyurethane/nanosilica composites: a diol as extender with triethoxysilane group. J Appl Polym Sci 131(15):1–7
17.
Chen S, Chen S, Zhao G, Chen J (2015) Fabrication and properties of novel superparamagnetic, well-dispersed waterborne polyurethane/Ni-Zn ferrite nanocomposites. Comp Sci Tech 119:108–114CrossRef
18.
Zhang S, Li Y, Peng L, Li Q, Chen S, Hou K (2013) Synthesis and characterization of novel waterborne polyurethane nanocomposites with magnetic and electrical properties. Compos Part A 55:94–101CrossRef
19.
Soares RR, Carone C, Einloft S, Ligabue R, Monteiro WF (2014) Synthesis and characterization of waterborne polyurethane/ZnO composites. Polym Bull 71:829–838CrossRef
20.
Dumas A, Martin F, Le Roux C, Micoud P, Petit S, Ferrage E, Brendlé J, Grauby O, Greenhill-Hooper M (2013) Phyllosilicates synthesis: a way of accessing edges contributions in NMR and FTIR spectroscopies. Example of synthetic talc. Phys Chem Miner 40:361–373CrossRef
21.
Tang E, Cheng G, Ma X (2006) Preparation of nano-ZnO/PMMA composite particles via grafting of the copolymer onto the surface of zinc oxide nanoparticles. Powder Technol 161:209–214CrossRef
22.
Da Silva V, Dos Santos LM, Subda S, Ligabue R, Seferin M, Carone C, Einloft S (2013) Synthesis and characterization of polyurethane/titanium dioxide nanocomposites obtained by in situ polymerization. Polym Bull 70:1819–1833CrossRef
23.
Lippmaa E, Magi M, Samoson A, Tarmac M, Engelhardt G (1980) Structural studies of silicates by solid-state high-resolution 29Si NMR. J Am Chem Soc 102:4889–4893CrossRef
24.
Wang T-L, Ou C-C, Yang C-H (2008) Synthesis and properties of organic/inorganic hybrid nanoparticles prepared using atom transfer radical polymerization. J Appl Polym Sci 109:3421–3430CrossRef
25.
Sardon H, Irusta L, Santamaría P, Fernández-Berridi MJ (2012) Thermal and mechanical behaviour of self-curable waterborne hybrid polyurethanes functionalized with (3-aminopropyl)triethoxysilane (APTES). J Polym Res 19:545–546CrossRef
26.
Jena KK, Sahoo S, Narayan R, Aminabhavi TM, Raju KVSN (2011) Novel hyperbranched waterborne polyurethane-urea/silica hybrid coatings and their characterizations. Polym Int 60:1504–1513CrossRef
27.
Chesnel K, Trevino M, Cai Y, Hancock JM, Smith SJ, Harrison RG (2014) Particle size effects on the magnetic behaviour of 5 to 11 nm Fe3O4 nanoparticles coated with oleic acid. J Phys Conf Ser 521:012004CrossRef
28.
Mohapatra J, Nigam S, Gupta J, Mitra A, Aslam M, Bahadur D (2015) Enhancement of magnetic heating efficiency in size controlled MFe2O4 (M=Mn, Fe, Co and Ni) nanoassemblies. RSC Adv 5:14311–14321CrossRef
29.
Lei L, Xia Z, Zhang L, Zhang Y, Zhong L (2016) Preparation and properties of amino-functional reduced graphene oxide/waterborne polyurethane hybrid emulsions. Prog Org Coat 97:19–27CrossRef
30.
Sabzi M, Mirabedini SM, Zohuriaan-Mehr J, Atai M (2009) Surface modification of TiO2 nano-particles with silane coupling agent and investigation of its effect on the properties of polyurethane composite coating. Prog Org Coat 65:222–228CrossRef
31.
Lorandi NP, Ornaghi MOHCH Jr (2016) Dynamic mechanical analysis (DMA) of polymeric composite materials. Sci Cum Ind 4:48–60CrossRef
32.
Serkis M, Špírková M, Hodan J, Kredatusová J (2016) Nanocomposites made from thermoplastic waterborne polyurethane and colloidal silica. The influence of nanosilica type and amount on the functional properties. Prog Org Coat 101:342–349CrossRef
33.
Gu X, Chen G, Zhao M, Watson SS, Nguyen T, Chin JW, Martin JW (2012) Critical role of particle/polymer interface in photostability of nano-filled polymeric coatings. J Coat Technol Res 9:251–267CrossRef
Metadata
Title
Waterborne polyurethane/Fe3O4-synthetic talc composites: synthesis, characterization, and magnetic properties
Authors
Leonardo M. dos Santos
Rosane Ligabue
Angela Dumas
Christophe Le Roux
Pierre Micoud
Jean-François Meunier
François Martin
Marta Corvo
Pedro Almeida
Sandra Einloft
Publication date
19-07-2017
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 5/2018
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-017-2133-9

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