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01.06.2013 | Original Paper

Synthesis and characterization of polyurethane/titanium dioxide nanocomposites obtained by in situ polymerization

verfasst von: Vinícius Demétrio da Silva, Leonardo M. dos Santos, Suelen M. Subda, Rosane Ligabue, Marcus Seferin, Carlos L. P. Carone, Sandra Einloft

Erschienen in: Polymer Bulletin | Ausgabe 6/2013

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Abstract

The development of new polymeric and polymeric based materials is fundamental to meet the market demands. This work aims the synthesis and characterization of polyurethane/titanium dioxide nanocomposite, using low cost commercial raw materials. Nanocomposites were synthesized by in situ polymerization reactions in which titanium dioxide were added in the following proportions, by weight, in relation to the mass obtained from the pure polymer: 0.5, 1.0, 2.0, 3.0, 5.0, 7.0, and 10.0 %. These reactions were based in poli (ε-caprolactone) and 1,6-diisocyanatohexane. The materials were characterized by infrared spectroscopy Fourier transform, scanning electron microscopy, differential scanning calorimetry analysis, thermogravimetric analysis, dynamic mechanical thermal analysis, and UV–Vis spectroscopy. Based on the obtained results it was concluded that the nanocomposites synthesized by in situ polymerization presented, in general, thermal properties (degradation temperature) and mechanical properties higher than the pure polymer.

Vorheriger Artikel Textural properties of poly(glycidyl methacrylate): acid-modified bentonite nanocomposites

Nächster Artikel Structure–rheology relationship in complex quaternized polysulfones/solvent/nonsolvent systems

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Malíková M, Rychlý J, Matisová-Rychlá L, Csomorová K, Janigová I, Wilde H-W (2010) Assessing the progress of degradation in polyurethanes by chemilum inescence. I. Unstabilised polyurethane films. Polym Degrad Stab 95:2367–2375. doi:10.1016/j.polymdegradstab.2010.08.016 CrossRef

Lu Y, Tighzert L, Berzin F, Rondot S (2005) Innovative plasticized starch films modified with waterborne polyurethane from renewable resources. Carbohydr Polym 61:174–182. doi:10.1016/j.carbpol.2005.04.013 CrossRef

Thomas PS, Thomas S, Bandyopadhyay S, Wurm A, Schick C (2008) Polystyrene/calcium phosphate nanocomposites: dynamic mechanical and differential scanning calorimetric studies. Compos Sci Technol 68:3220–3229. doi:10.1016/j.compscitech.2008.08.008 CrossRef

Ray SS, Yamada K, Okamoto M, Ueda K (2002) Polylactide-layered silicate nanocomposite: a novel biodegradable material. Nano Lett 2:1093–1096. doi:10.1021/nl0202152 CrossRef

Zia KM, Bhatti HN, Bhatti IA (2007) Methods for polyurethane and polyurethane composites, recycling and recovery: a review. React Funct Polym 67:675–692. doi:10.1016/j.reactfunctpolym.2007.05.004 CrossRef

Khalil M, Saeed S, Ahmad Z (2008) Mechanical and thermal properties of polyimide/silica hybrids with imide-modified silica network structures. J Appl Polym Sci 107:1257–1268. doi:10.1002/app.27149 CrossRef

Vladimirov V, Betchev C, Vassiliou A, Papageorgiou G, Bikiaris D (2006) Dynamic mechanical and morphological studies of isotactic polypropylene/fumed silica nanocomposites with enhanced gas barrier properties. Compos Sci Technol 66:2935–2944. doi:10.1016/j.compscitech.2006.02.010 CrossRef

Pavlidou S, Papaspyrides CD (2008) A review on polymer-layered silicate nanocomposites. Prog Polym Sci 33:1119–1198. doi:10.1016/j.progpolymsci.2008.07.008 CrossRef

Chen Y, Wang R, Zhou J, Fan H, Shi B (2011) Membrane formation temperature-dependent gas transport through thermo-sensitive polyurethane containing in situ-generated TiO₂ nanoparticles. Polymer 52:1856–1867. doi:10.1016/j.polymer.2011.02.021 CrossRef

10.

Esteves ACC, Barros-Timmons A, Trindade T (2004) Nanocompósitos de Matriz Polimérica: estratégias de Síntese de Materiais Híbridos. Quim Nova 27:798–806CrossRef

11.

Yang K, Yang Q, Li G, Sun Y, Feng D (2006) Morphology and mechanical properties of polypropylene/calcium carbonate nanocomposites. Mater Lett 60:805–809. doi:10.1016/j.matlet.2005.10.020 CrossRef

12.

Oriakhi CO (2000) Polymer nanocomposition approach to advanced materials. J Chem Educ 77:1138–1146. doi:10.1021/ed077p1138 CrossRef

13.

Gao X, Zhou B, Guo Y, Zhu Y, Chen X, Zheng Y, Gao W, Ma X, Wang Z (2010) Synthesis and characterization of well-dispersed polyurethane/CaCO₃ nanocomposites. Colloids Surf A 371:1–7. doi:10.1016/j.colsurfa.2010.08.036 CrossRef

14.

Reyes-Coronado D, Rodríguez-Gattorno G, Espinosa-Pesqueira ME, Cab C, Coss R, Oskam G (2008) Phase-pure TiO₂ nanoparticles: anatase, brookite and rutile. Nanotechnology 19:10. doi:10.1088/0957-4484/19/14/145605 CrossRef

15.

Bavykin DV, Friedrich JM, Walsh FC (2006) Protonated titanates and TiO₂ nanostructured materials: synthesis, properties, and applications. Adv Mater 18:2807–2824. doi:10.1002/adma.200502696 CrossRef

16.

Reijnders L (2009) The release of TiO₂ and SiO₂ nanoparticles from nanocomposites. Polym Degrad Stab 94:873–876. doi:10.1016/j.polymdegradstab.2009.02.005 CrossRef

17.

Imai Y, Terahara A, Hakuta Y, Matsui K, Hayashi H, Ueno N (2009) Transparent poly(bisphenol A carbonate)-based nanocomposites with high refractive index nanoparticles. Eur Polym J 45:630–638. doi:10.1016/j.eurpolymj.2008.12.031 CrossRef

18.

Mahmoudian MR, Basirun WJ, Alias Y (2011) Synthesis of polypyrrole/Ni-doped TiO₂ nanocomposites (NCs) as a protective pigment in organic coating. Prog Org Coat 71:56–64. doi:10.1016/j.porgcoat.2010.12.010 CrossRef

19.

Xian G, Walter R, Haupert F (2006) Friction and wear of epoxy/TiO₂ nanocomposites: influence of additional short carbon fibers, aramid and PTFE particles. Compos Sci Technol 66:3199–3209. doi:10.1016/j.compscitech.2005.02.022 CrossRef

20.

Mihailovic D, Saponjic Z, Radoicic M, Radetic T, Jovancic P, Nedeljkovic J, Radetic M (2010) Functionalization of polyester fabrics with alginates and TiO₂ nanoparticles. Carbohydr Polym 79:526–532. doi:10.1016/j.carbpol.2009.08.036 CrossRef

21.

Jiang X, Tian X, Gu J, Huang D, Yang Y (2011) Cotton fabric coated with nano TiO₂-acrylate copolymer for photocatalytic self-cleaning by in situ suspension polymerization. Appl Surf Sci 257:8451–8456CrossRef

22.

Patra N, Salerno M, Malerba M, Cozzoli PD, Athanassiou A (2011) Improvement of thermal stability of poly(methyl methacrylate) by incorporation of colloidal TiO₂ nanorods. Polym Degrad Stab 96:1377–1381. doi:10.1016/j.polymdegradstab.2011.03.020 CrossRef

23.

Shi Y, Mu L, Feng X, Lu X (2011) The tribological behavior of nanometer and micrometer TiO₂ particle-filled polytetrafluoroethylene/polyimide. Mater Des 32:964–970. doi:10.1016/j.matdes.2010.07.013 CrossRef

24.

Liaw W-C, Chen K-P (2007) Preparation and characterization of poly(imide siloxane) (PIS)/titania(TiO₂) hybrid nanocomposites by sol–gel processes. Eur Polym J 43:2265–2278. doi:10.1016/j.eurpolymj.2007.01.015 CrossRef

25.

Song M, Pan C, Li J, Zhang R, Wang X, Gu Z (2008) Blends of TiO₂ nanoparticles and poly(N-isopropylacrylamide)-co-polystyrene nanofibers as a means to promote the biorecognition of an anticancer drug. Talanta 75:1035–1040. doi:10.1016/j.talanta.2008.01.005 CrossRef

26.

Zhang L, Liu P, Su Z (2006) Preparation of PANI-TiO₂ nanocomposites and their solid-phase photocatalytic degradation. Polym Degrad Stab 91:2213–2219CrossRef

27.

Sabzi M, Mirabedini SM, Zohuriaan-Mehr J, Atai M (2009) Surface modification of TiO₂ nano-particles with silane coupling agent and investigation of its effect on the properties of polyurethane composite coating. Prog Org Coat 65:222–228. doi:10.1016/j.porgcoat.2008

28.

Che X-C, Jin Y-Z, Lee Y-S (2010) Preparation of nano-TiO₂/polyurethane emulsions via in situ RAFT polymerization. Prog Org Coat 69:534–538. doi:10.1016/j.porgcoat.2010.09.013 CrossRef

29.

Chen J, Zhou Y, Nan Q, Ye X, Sun Y, Zhang F, Wang Z (2007) Preparation and properties of optically active polyurethane/TiO₂ nanocomposites derived from optically pure 1,1′-binaphthyl. Eur Polym J 43:4151–4159. doi:10.1016/j.eurpolymj.2007.07.006 CrossRef

30.

Kasanen J, Suvanto M, Pakkanen TT (2011) UV stability of polyurethane binding agent on multilayer photocatalytic TiO₂ coating. Polym Test 30:381–389. doi:10.1016/j.polymertesting.2011.02.006 CrossRef

31.

Mirabedini SM, Sabzi M, Zoguriaan-Mehr J, Atai M, Behzadnasab M (2011) Weathering performance of the polyurethane nanocomposite coatings containing silane treated TiO₂ nanoparticles. Appl Surf Sci 257:4196–4203. doi:10.1016/j.apsusc.2010.12.020 CrossRef

32.

Chen J, Zhou Y, Nan Q, Sun Y, Ye X, Wang Z (2007) Synthesis, characterization and infrared emissivity study of polyurethane/TiO₂ nanocomposites. Appl Surf Sci 253:9154–9158. doi:10.1016/j.apsusc.2007.05.046

33.

Zheng J, Ozisik R, Siegel RW (2005) Disruption of self-assembly and altered mechanical behavior in polyurethane/zinc oxides nanocomposites. Polymer 46:10873–10882. doi:10.1016/j.polymer.2005.08.082 CrossRef

34.

Polizos G, Tuncer E, Agapov AL, Stevens D, Sokolov AP, Kidder MK, Jacobs JD, Koerner H, Vaia RA, More KL, Sauers I (2012) Effect of polymer–nanoparticle interactions on the glass transition dynamics and the conductivity mechanism in polyurethane titanium dioxide nanocomposites. Polymer 53:595–603. doi:10.1016/j.polymer.2011.11.050 CrossRef

35.

Paiva JMF, Mayer S, Rezende MC, Cândido GM (2006) Avaliação da temperatura de transição vítrea de compósitos poliméricos reparados de uso aeronáutico. Polímeros 16:79–87

36.

Zhang SW, Liu R, Jiang JQ, Yang C, Chen M, Liu XY (2011) Facile synthesis of waterborne UV-curable polyurethane/silica nanocomposites and morphology, physical properties of its nanostructured films. Prog Org Coat 70:1–8. doi:10.1016/j.porgcoat.2010.09.005 CrossRef

37.

Ma X-Y, Zang W-D (2009) Effects of flower-like ZnO nanowhiskers on the mechanical, thermal and antibacterial properties of waterborne polyurethane. Polym Degrad Stab 94:1103–1109. doi:10.1016/j.polymdegradstab.2009.03.024 CrossRef

38.

Mishra AK, Mishra RS, Narayan R, Raju KVSN (2010) Effect of nano ZnO on the phase mixing of polyurethane hybrid dispersions. Prog Org Coat 67:405–413. doi:10.1016/j.porgcoat.2009.12.008 CrossRef

Titel: Synthesis and characterization of polyurethane/titanium dioxide nanocomposites obtained by in situ polymerization
verfasst von: Vinícius Demétrio da Silva
Leonardo M. dos Santos
Suelen M. Subda
Rosane Ligabue
Marcus Seferin
Carlos L. P. Carone
Sandra Einloft
Publikationsdatum: 01.06.2013
Verlag: Springer-Verlag
Erschienen in: Polymer Bulletin / Ausgabe 6/2013
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-013-0927-y

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