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Published in: Rare Metals 6/2021

07-01-2021 | Original Article

Enhanced formaldehyde sensitivity of two-dimensional mesoporous SnO2 by nitrogen-doped graphene quantum dots

Authors: Zhen-Lu Chen, Ding Wang, Xian-Ying Wang, Jun-He Yang

Published in: Rare Metals | Issue 6/2021

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Abstract

Formaldehyde (HCHO) is widely known as an indoor air pollutant, and the monitoring of the gas has significant importance. However, most HCHO sensing materials do not have low detection limits and operate at high temperatures. Herein, two-dimensional (2D) mesoporous ultrathin SnO2 modified with nitrogen-doped graphene quantum dots (N-GQDs) was synthesized. The N-GQDs/SnO2 nanocomposite demonstrated high efficiency for HCHO detection. With the addition of 1.00 wt% N-GQDs, the response (Ra/Rg) of SnO2 gas sensor increased from 120 to 361 at 60 °C for the detection of 10 × 10−6 HCHO. In addition, the corresponding detection limit was as low as 10 × 10−9. Moreover, the sensor exhibited excellent selectivity and stability for the detection of HCHO. The enhanced sensing performance was attributed to both the large specific surface area of SnO2 and electron regulation of N-GQDs. Therefore, this study presents a novel HCHO sensor, and it expands the research and application potential of GQDs nanocomposites.

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Appendix
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Literature
[1]
go back to reference Chung PR, Tzeng CT, Ke MT, Lee CY. Formaldehyde gas sensors: a review. Sensors. 2013;13(4):4468. Chung PR, Tzeng CT, Ke MT, Lee CY. Formaldehyde gas sensors: a review. Sensors. 2013;13(4):4468.
[2]
go back to reference Zheng YG, Wang J, Yao PJ. Formaldehyde sensing properties of electrospun NiO-doped SnO2 nanofibers. Sens Actuators B Chem. 2011;156(2):723. Zheng YG, Wang J, Yao PJ. Formaldehyde sensing properties of electrospun NiO-doped SnO2 nanofibers. Sens Actuators B Chem. 2011;156(2):723.
[3]
go back to reference Fang F, Bai L, Sun HY, Kuang Y, Sun XM, Shi T, Song DS, Guo P, Yang HP, Zhang ZF, Wang Y, Luo J, Zhu J. Hierarchically porous indium oxide nanolamellas with ten-parts-per-billion-level formaldehyde-sensing performance. Sens Actuators B Chem. 2015;206(9):714. Fang F, Bai L, Sun HY, Kuang Y, Sun XM, Shi T, Song DS, Guo P, Yang HP, Zhang ZF, Wang Y, Luo J, Zhu J. Hierarchically porous indium oxide nanolamellas with ten-parts-per-billion-level formaldehyde-sensing performance. Sens Actuators B Chem. 2015;206(9):714.
[4]
go back to reference Yoosefian M, Raissi H, Mola A. The hybrid of Pd and SWCNT (Pd loaded on SWCNT) as an efficient sensor for the formaldehyde molecule detection: a DFT study. Sens Actuators B Chem. 2015;212(2):55. Yoosefian M, Raissi H, Mola A. The hybrid of Pd and SWCNT (Pd loaded on SWCNT) as an efficient sensor for the formaldehyde molecule detection: a DFT study. Sens Actuators B Chem. 2015;212(2):55.
[5]
go back to reference Zhang Y, Zhang M, Cai ZQ, Chen MQ, Cheng FL. A novel electrochemical sensor for formaldehyde based on palladium nanowire arrays electrode in alkaline media. Electrochim Acta. 2012;68(2):172. Zhang Y, Zhang M, Cai ZQ, Chen MQ, Cheng FL. A novel electrochemical sensor for formaldehyde based on palladium nanowire arrays electrode in alkaline media. Electrochim Acta. 2012;68(2):172.
[6]
go back to reference Ding P, Xu DS, Dong N, Chen Y, Xu PC, Zheng D, Li XX. A high-sensitivity H2S gas sensor based on optimized ZnO-ZnS nano-heterojunction sensing material. Chin Chem Lett. 2020;31(8):2050. Ding P, Xu DS, Dong N, Chen Y, Xu PC, Zheng D, Li XX. A high-sensitivity H2S gas sensor based on optimized ZnO-ZnS nano-heterojunction sensing material. Chin Chem Lett. 2020;31(8):2050.
[7]
go back to reference Su C, Zhang L, Han YT, Ren C, Chen XW, Hu J, Zeng M, Hu NT, Su YJ, Zhou ZH, Yang Z. Controllable synthesis of crescent-shaped porous NiO nanoplates for conductometric ethanol gas sensors. Sens Actuators B Chem. 2019;296:126642. Su C, Zhang L, Han YT, Ren C, Chen XW, Hu J, Zeng M, Hu NT, Su YJ, Zhou ZH, Yang Z. Controllable synthesis of crescent-shaped porous NiO nanoplates for conductometric ethanol gas sensors. Sens Actuators B Chem. 2019;296:126642.
[8]
go back to reference Su C, Zhang L, Han YT, Chen XW, Wang ST, Zeng M, Hu NT, Su YJ, Zhou ZH, Wei H, Yang Z. Glucose-assisted synthesis of hierarchical flower-like Co3O4 nanostructures assembled by porous nanosheets for enhanced acetone sensing. Sens Actuators B Chem. 2019;288(3):699. Su C, Zhang L, Han YT, Chen XW, Wang ST, Zeng M, Hu NT, Su YJ, Zhou ZH, Wei H, Yang Z. Glucose-assisted synthesis of hierarchical flower-like Co3O4 nanostructures assembled by porous nanosheets for enhanced acetone sensing. Sens Actuators B Chem. 2019;288(3):699.
[9]
go back to reference Yuan ZY, Han EC, Meng FL, Zuo KY. Detection and identification of volatile organic compounds based on temperature-modulated ZnO sensors. IEEE Trans Instrum Meas. 2020;69(7):4533. Yuan ZY, Han EC, Meng FL, Zuo KY. Detection and identification of volatile organic compounds based on temperature-modulated ZnO sensors. IEEE Trans Instrum Meas. 2020;69(7):4533.
[10]
go back to reference Huang XY, Chi ZT, Liu J, Li DH, Sun XJ, Yan C, Wang YC, Li H, Wang XD, Xie WF. Enhanced gas sensing performance based on p-NiS/n-In2O3 heterojunction nanocomposites. Sens Actuators B Chem. 2020;304:127305. Huang XY, Chi ZT, Liu J, Li DH, Sun XJ, Yan C, Wang YC, Li H, Wang XD, Xie WF. Enhanced gas sensing performance based on p-NiS/n-In2O3 heterojunction nanocomposites. Sens Actuators B Chem. 2020;304:127305.
[11]
go back to reference Zhou TT, Zhang T, Zhang R, Lou Z, Deng JN, Wang LL. Hollow ZnSnO3 cubes with controllable shells enabling highly efficient chemical sensing detection of formaldehyde vapors. ACS Appl Mater Interfaces. 2017;9(16):14525. Zhou TT, Zhang T, Zhang R, Lou Z, Deng JN, Wang LL. Hollow ZnSnO3 cubes with controllable shells enabling highly efficient chemical sensing detection of formaldehyde vapors. ACS Appl Mater Interfaces. 2017;9(16):14525.
[12]
go back to reference Wang D, Tian L, Li HJ, Wan KC, Yu X, Wang P, Chen AY, Wang XY, Yang JH. Mesoporous ultrathin SnO2 nanosheets in situ modified by graphene oxide for extraordinary formaldehyde detection at low temperature. ACS Appl Mater Interfaces. 2019;11(13):12808. Wang D, Tian L, Li HJ, Wan KC, Yu X, Wang P, Chen AY, Wang XY, Yang JH. Mesoporous ultrathin SnO2 nanosheets in situ modified by graphene oxide for extraordinary formaldehyde detection at low temperature. ACS Appl Mater Interfaces. 2019;11(13):12808.
[13]
go back to reference Wang D, Huang SM, Li HJ, Chen AY, Wang P, Yang J, Wang XY, Yang JH. Ultrathin WO3 nanosheets modified by g-C3N4 for highly efficient acetone vapor detection. Sens Actuators B Chem. 2019;282(11):961. Wang D, Huang SM, Li HJ, Chen AY, Wang P, Yang J, Wang XY, Yang JH. Ultrathin WO3 nanosheets modified by g-C3N4 for highly efficient acetone vapor detection. Sens Actuators B Chem. 2019;282(11):961.
[14]
go back to reference Meng D, Liu DY, Wang GS, Shen YB, San XG, Li M, Meng FL. Low-temperature formaldehyde gas sensors based on NiO-SnO2 heterojunction microflowers assembled by thin porous nanosheets. Sens Actuators B Chem. 2018;273(6):418. Meng D, Liu DY, Wang GS, Shen YB, San XG, Li M, Meng FL. Low-temperature formaldehyde gas sensors based on NiO-SnO2 heterojunction microflowers assembled by thin porous nanosheets. Sens Actuators B Chem. 2018;273(6):418.
[15]
go back to reference Han YT, Ma YJ, Liu Y, Xu SS, Chen XW, Zeng M, Hu NT, Su YJ, Zhou ZH, Yang Z. Construction of MoS2/SnO2 heterostructures for sensitive NO2 detection at room temperature. Appl Surf Sci. 2019;493(7):613. Han YT, Ma YJ, Liu Y, Xu SS, Chen XW, Zeng M, Hu NT, Su YJ, Zhou ZH, Yang Z. Construction of MoS2/SnO2 heterostructures for sensitive NO2 detection at room temperature. Appl Surf Sci. 2019;493(7):613.
[16]
go back to reference Bian H, Zhang XJ, Huang DX, Zhang N. Selective modification of two-dimensional MoS2 nanosheets by polymer grafting. Chin Chem Lett. 2019;30(2):311. Bian H, Zhang XJ, Huang DX, Zhang N. Selective modification of two-dimensional MoS2 nanosheets by polymer grafting. Chin Chem Lett. 2019;30(2):311.
[18]
go back to reference Wang D, Zhang ML, Chen ZL, Li HJ, Chen AY, Wang XY, Yang JH. Enhanced formaldehyde sensing properties of hollow SnO2 nanofibers by graphene oxide. Sens Actuators B Chem. 2017;250(4):533. Wang D, Zhang ML, Chen ZL, Li HJ, Chen AY, Wang XY, Yang JH. Enhanced formaldehyde sensing properties of hollow SnO2 nanofibers by graphene oxide. Sens Actuators B Chem. 2017;250(4):533.
[19]
go back to reference Zhang YM, Zhao JH, Sun HL, Zhu ZQ, Zhang J, Liu QJ. B, N, S, Cl doped graphene quantum dots and their effects on gas-sensing properties of Ag-LaFeO3. Sens Actuators B Chem. 2018;266(3):364. Zhang YM, Zhao JH, Sun HL, Zhu ZQ, Zhang J, Liu QJ. B, N, S, Cl doped graphene quantum dots and their effects on gas-sensing properties of Ag-LaFeO3. Sens Actuators B Chem. 2018;266(3):364.
[20]
go back to reference Rong XR, Chen DL, Qu GP, Li T, Zhang R, Sun J. Effects of graphene on the microstructures of SnO2@rGO nanocomposites and their formaldehyde-sensing performance. Sens Actuators B Chem. 2018;269(4):223. Rong XR, Chen DL, Qu GP, Li T, Zhang R, Sun J. Effects of graphene on the microstructures of SnO2@rGO nanocomposites and their formaldehyde-sensing performance. Sens Actuators B Chem. 2018;269(4):223.
[21]
go back to reference Teng ZW, Wang BT, Hu YY, Xu DQ. Light-responsive nanocomposites combining graphene oxide with POSS based on host-guest chemistry. Chin Chem Lett. 2019;30(3):717. Teng ZW, Wang BT, Hu YY, Xu DQ. Light-responsive nanocomposites combining graphene oxide with POSS based on host-guest chemistry. Chin Chem Lett. 2019;30(3):717.
[22]
go back to reference Liu W, Zhou XY, Xu L, Zhu SD, Yang S, Chen XF, Dong B, Bai X, Lu GY, Song HW. Graphene quantum dot-functionalized three-dimensional ordered mesoporous ZnO for acetone detection toward diagnosis of diabetes. Nanoscale. 2019;11(24):11496. Liu W, Zhou XY, Xu L, Zhu SD, Yang S, Chen XF, Dong B, Bai X, Lu GY, Song HW. Graphene quantum dot-functionalized three-dimensional ordered mesoporous ZnO for acetone detection toward diagnosis of diabetes. Nanoscale. 2019;11(24):11496.
[23]
go back to reference Zhang YM, Rong Q, Zhao JH, Zhang J, Zhu ZQ, Liu QJ. Boron-doped graphene quantum dot/Ag–LaFeO3 p–p heterojunctions for sensitive and selective benzene detection. J Mater Chem A. 2018;6(26):12647. Zhang YM, Rong Q, Zhao JH, Zhang J, Zhu ZQ, Liu QJ. Boron-doped graphene quantum dot/Ag–LaFeO3 p–p heterojunctions for sensitive and selective benzene detection. J Mater Chem A. 2018;6(26):12647.
[24]
go back to reference Li HJ, Sun X, Xue FF, Ou NQ, Sun BW, Qian DJ, Chen M, Wang D, Yang JH, Wang XY. Redox induced fluorescence on–off switching based on nitrogen enriched graphene quantum dots for formaldehyde detection and bioimaging. ACS Sustain Chem Eng. 2018;6(2):1708. Li HJ, Sun X, Xue FF, Ou NQ, Sun BW, Qian DJ, Chen M, Wang D, Yang JH, Wang XY. Redox induced fluorescence on–off switching based on nitrogen enriched graphene quantum dots for formaldehyde detection and bioimaging. ACS Sustain Chem Eng. 2018;6(2):1708.
[25]
go back to reference Safarpour M, Khataee A, Vatanpour V. Effect of reduced graphene oxide/TiO2 nanocomposite with different molar ratios on the performance of PVDF ultrafiltration membranes. Sep Purif Technol. 2015;140(11):32. Safarpour M, Khataee A, Vatanpour V. Effect of reduced graphene oxide/TiO2 nanocomposite with different molar ratios on the performance of PVDF ultrafiltration membranes. Sep Purif Technol. 2015;140(11):32.
[26]
go back to reference Wang D, Wan KC, Zhang ML, Li HJ, Wang P, Wang XY, Yang JH. Constructing hierarchical SnO2 nanofiber/nanosheets for efficient formaldehyde detection. Sens Actuators B Chem. 2019;283(11):714. Wang D, Wan KC, Zhang ML, Li HJ, Wang P, Wang XY, Yang JH. Constructing hierarchical SnO2 nanofiber/nanosheets for efficient formaldehyde detection. Sens Actuators B Chem. 2019;283(11):714.
[27]
go back to reference Wang L, Wang YL, Xu T, Liao HB, Yao CJ, Liu Y, Li Z, Chen ZW, Pan DY, Sun LT, Wu MH. Gram-scale synthesis of single-crystalline graphene quantum dots with superior optical properties. Nat Commun. 2014;5:5357. Wang L, Wang YL, Xu T, Liao HB, Yao CJ, Liu Y, Li Z, Chen ZW, Pan DY, Sun LT, Wu MH. Gram-scale synthesis of single-crystalline graphene quantum dots with superior optical properties. Nat Commun. 2014;5:5357.
[28]
go back to reference Qu D, Zheng M, Du P, Zhou Y, Zhang LG, Li D, Tan HQ, Zhao Z, Xie ZG, Sun ZC. Highly luminescent S, N co-doped graphene quantum dots with broad visible absorption bands for visible light photocatalysts. Nanoscale. 2013;5(24):12272. Qu D, Zheng M, Du P, Zhou Y, Zhang LG, Li D, Tan HQ, Zhao Z, Xie ZG, Sun ZC. Highly luminescent S, N co-doped graphene quantum dots with broad visible absorption bands for visible light photocatalysts. Nanoscale. 2013;5(24):12272.
[29]
go back to reference Liu Y, Jiao Y, Zhang ZL, Qu FY, Umar A, Wu X. Hierarchical SnO2 nanostructures made of intermingled ultrathin nanosheets for environmental remediation, smart gas sensor, and supercapacitor applications. ACS Appl Mater Interfaces. 2014;6(3):2174. Liu Y, Jiao Y, Zhang ZL, Qu FY, Umar A, Wu X. Hierarchical SnO2 nanostructures made of intermingled ultrathin nanosheets for environmental remediation, smart gas sensor, and supercapacitor applications. ACS Appl Mater Interfaces. 2014;6(3):2174.
[30]
go back to reference Dieguez A, Romano-Rodrıguez A, Vila A, Morante JR. The complete Raman spectrum of nanometric SnO2 particles. J Appl Phys. 2001;90(3):1550. Dieguez A, Romano-Rodrıguez A, Vila A, Morante JR. The complete Raman spectrum of nanometric SnO2 particles. J Appl Phys. 2001;90(3):1550.
[31]
go back to reference Sun X, Li HJ, Ou NQ, Lyu B, Gui BJ, Tian SW, Qian DJ, Wang XY, Yang JH. Visible-light driven TiO2 photocatalyst coated with graphene quantum dots of tunable nitrogen doping. Molecules. 2019;24(2):344. Sun X, Li HJ, Ou NQ, Lyu B, Gui BJ, Tian SW, Qian DJ, Wang XY, Yang JH. Visible-light driven TiO2 photocatalyst coated with graphene quantum dots of tunable nitrogen doping. Molecules. 2019;24(2):344.
[32]
go back to reference Gu CP, Cui YW, Wang LY, Sheng EH, Shim JJ, Huang JR. Synthesis of the porous NiO/SnO2 microspheres and microcubes and their enhanced formaldehyde gas sensing performance. Sens Actuators B Chem. 2017;241(10):298. Gu CP, Cui YW, Wang LY, Sheng EH, Shim JJ, Huang JR. Synthesis of the porous NiO/SnO2 microspheres and microcubes and their enhanced formaldehyde gas sensing performance. Sens Actuators B Chem. 2017;241(10):298.
[33]
go back to reference Wan KC, Wang D, Wang F, Li HJ, Xu JC, Wang XY, Yang JH. Hierarchical In2O3@SnO2 core-shell nanofiber for high efficiency formaldehyde detection. ACS Appl Mater Interfaces. 2019;11(48):45214. Wan KC, Wang D, Wang F, Li HJ, Xu JC, Wang XY, Yang JH. Hierarchical In2O3@SnO2 core-shell nanofiber for high efficiency formaldehyde detection. ACS Appl Mater Interfaces. 2019;11(48):45214.
[34]
go back to reference Hu J, Wang T, Wang YJ, Huang D, He GL, Han YT, Hu NT, Su YJ, Zhou ZH, Zhang YF, Yang Z. Enhanced formaldehyde detection based on Ni doping of SnO2 nanoparticles by one-step synthesis. Sens Actuators B Chem. 2018;263(2):120. Hu J, Wang T, Wang YJ, Huang D, He GL, Han YT, Hu NT, Su YJ, Zhou ZH, Zhang YF, Yang Z. Enhanced formaldehyde detection based on Ni doping of SnO2 nanoparticles by one-step synthesis. Sens Actuators B Chem. 2018;263(2):120.
[35]
go back to reference Li GJ, Cheng ZX, Xiang Q, Yan LM, Wang XH, Xu JQ. Bimetal PdAu decorated SnO2 nanosheets based gas sensor with temperature-dependent dual selectivity for detecting formaldehyde and acetone. Sens Actuators B Chem. 2019;283(9):590. Li GJ, Cheng ZX, Xiang Q, Yan LM, Wang XH, Xu JQ. Bimetal PdAu decorated SnO2 nanosheets based gas sensor with temperature-dependent dual selectivity for detecting formaldehyde and acetone. Sens Actuators B Chem. 2019;283(9):590.
[36]
go back to reference Zhu KM, Ma SY. Preparations of Bi-doped SnO2 hierarchical flower-shaped nanostructures with highly sensitive HCHO sensing properties. Mater Lett. 2019;236(10):491. Zhu KM, Ma SY. Preparations of Bi-doped SnO2 hierarchical flower-shaped nanostructures with highly sensitive HCHO sensing properties. Mater Lett. 2019;236(10):491.
[37]
go back to reference Wei Q, Song P, Li ZQ, Yang ZX, Wang Q. Hierarchical peony-like Sb-doped SnO2 nanostructures: synthesis, characterization and HCHO sensing properties. Mater Lett. 2016;191(15):173. Wei Q, Song P, Li ZQ, Yang ZX, Wang Q. Hierarchical peony-like Sb-doped SnO2 nanostructures: synthesis, characterization and HCHO sensing properties. Mater Lett. 2016;191(15):173.
[38]
go back to reference Shu SM, Wang MX, Yang W, Liu ST. Synthesis of surface layered hierarchical octahedral-like structured Zn2SnO4/SnO2 with excellent sensing properties toward HCHO. Sens Actuators B Chem. 2017;243(12):1171. Shu SM, Wang MX, Yang W, Liu ST. Synthesis of surface layered hierarchical octahedral-like structured Zn2SnO4/SnO2 with excellent sensing properties toward HCHO. Sens Actuators B Chem. 2017;243(12):1171.
[40]
go back to reference Zhou TT, Liu XP, Zhang R, Wang LL, Zhang T. Constructing hierarchical heterostructured Mn3O4/Zn2SnO4 materials for efficient gas sensing reaction. Adv Mater Interfaces. 2018;5(11):1800115. Zhou TT, Liu XP, Zhang R, Wang LL, Zhang T. Constructing hierarchical heterostructured Mn3O4/Zn2SnO4 materials for efficient gas sensing reaction. Adv Mater Interfaces. 2018;5(11):1800115.
[41]
go back to reference Zou YH, Chen S, Sun J, Liu JQ, Che YK, Liu XH, Zhang J, Yang DJ. Highly efficient gas sensor using a hollow SnO2 microfiber for triethylamine detection. ACS Sens. 2017;2(7):897. Zou YH, Chen S, Sun J, Liu JQ, Che YK, Liu XH, Zhang J, Yang DJ. Highly efficient gas sensor using a hollow SnO2 microfiber for triethylamine detection. ACS Sens. 2017;2(7):897.
[42]
go back to reference Li Y, Zhao Y, Cheng HH, Hu Y, Shi GQ, Dai LM, Qu LT. Nitrogen-doped graphene quantum dots with oxygen-rich functional groups. J Am Chem Soc. 2012;134(1):15. Li Y, Zhao Y, Cheng HH, Hu Y, Shi GQ, Dai LM, Qu LT. Nitrogen-doped graphene quantum dots with oxygen-rich functional groups. J Am Chem Soc. 2012;134(1):15.
[43]
go back to reference Wang LL, Chen S, Li W, Wang K, Lou Z, Shen GZ. Grain-boundary-induced drastic sensing performance enhancement of polycrystalline-microwire printed gas sensors. Adv Mater. 2018;31(4):1804583. Wang LL, Chen S, Li W, Wang K, Lou Z, Shen GZ. Grain-boundary-induced drastic sensing performance enhancement of polycrystalline-microwire printed gas sensors. Adv Mater. 2018;31(4):1804583.
Metadata
Title
Enhanced formaldehyde sensitivity of two-dimensional mesoporous SnO2 by nitrogen-doped graphene quantum dots
Authors
Zhen-Lu Chen
Ding Wang
Xian-Ying Wang
Jun-He Yang
Publication date
07-01-2021
Publisher
Nonferrous Metals Society of China
Published in
Rare Metals / Issue 6/2021
Print ISSN: 1001-0521
Electronic ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-020-01636-6

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