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Journal of Materials Engineering and Performance

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18-09-2015

Polypropylene Glycol-Silver Nanoparticle Composites: A Novel Anticorrosion Material for Aluminum in Acid Medium

Authors: Moses M. Solomon, Saviour A. Umoren, Aniekemeabasi U. Israel, Eno E. Ebenso

Published in: Journal of Materials Engineering and Performance | Issue 11/2015

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Abstract

Admixture of polypropylene glycol and 1 mM AgNO₃ together with natural honey as reducing and stabilizing agent was employed to prepare in situ polypropylene glycol/silver nanoparticle (PPG/AgNPs) composite. The prepared PPG/AgNPs composite was characterized by UV-Vis spectroscopy, FTIR, XRD, and EDS, while the morphology of the Ag nanoparticles in the composite was obtained by TEM. TEM results revealed that the Ag nanoparticles were spherical in shape. The anticorrosion property of PPG/AgNPs composite was examined by electrochemical, weight loss, SEM, EDS, and water contact angle measurements. Results obtained show that PPG/AgNPs are effective in retarding the dissolution of Al in an acid-induced corrosive environment. Inhibition efficiency increased with the increasing composite concentration but decreased with the increasing temperature. Potentiodynamic polarization results revealed that PPG/AgNPs functions as a mixed-type corrosion inhibitor. The adsorption of the composite onto Al surface was found to follow El-Awady et al. adsorption isotherm model. SEM, EDS, and water contact angle results confirmed the adsorption of PPG/AgNPs films onto Al surface.

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Title: Polypropylene Glycol-Silver Nanoparticle Composites: A Novel Anticorrosion Material for Aluminum in Acid Medium
Authors: Moses M. Solomon
Saviour A. Umoren
Aniekemeabasi U. Israel
Eno E. Ebenso
Publication date: 18-09-2015
Publisher: Springer US
Published in: Journal of Materials Engineering and Performance / Issue 11/2015
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI: https://doi.org/10.1007/s11665-015-1716-6

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