nach oben

Journal of Materials Engineering and Performance

Erschienen in:

18.09.2015

Polypropylene Glycol-Silver Nanoparticle Composites: A Novel Anticorrosion Material for Aluminum in Acid Medium

verfasst von: Moses M. Solomon, Saviour A. Umoren, Aniekemeabasi U. Israel, Eno E. Ebenso

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 11/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Admixture of polypropylene glycol and 1 mM AgNO₃ together with natural honey as reducing and stabilizing agent was employed to prepare in situ polypropylene glycol/silver nanoparticle (PPG/AgNPs) composite. The prepared PPG/AgNPs composite was characterized by UV-Vis spectroscopy, FTIR, XRD, and EDS, while the morphology of the Ag nanoparticles in the composite was obtained by TEM. TEM results revealed that the Ag nanoparticles were spherical in shape. The anticorrosion property of PPG/AgNPs composite was examined by electrochemical, weight loss, SEM, EDS, and water contact angle measurements. Results obtained show that PPG/AgNPs are effective in retarding the dissolution of Al in an acid-induced corrosive environment. Inhibition efficiency increased with the increasing composite concentration but decreased with the increasing temperature. Potentiodynamic polarization results revealed that PPG/AgNPs functions as a mixed-type corrosion inhibitor. The adsorption of the composite onto Al surface was found to follow El-Awady et al. adsorption isotherm model. SEM, EDS, and water contact angle results confirmed the adsorption of PPG/AgNPs films onto Al surface.

Vorheriger Artikel Comparative Studies on Al-Based Composite Powder Reinforced with Nano Garnet and Multi-wall Carbon Nanotubes

Nächster Artikel Martensitic Transformation During Compressive Deformation of a Non-conventional Stainless Steel and Its Quantitative Assessment

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

T. Shanthi and S. Rajendran, Influence of Polyvinyl Alcohol on Corrosion Resistance of Mild Steel Simulated Concrete Pore Solution Prepared in Well Water, Chem. Sci. Trans., 2014, 3, p 187–192

A. Barak, P.J. Das, H. Vashisht, and S. Kumar, Synthesis, Characterization of Water Soluble PS-b-PEO-b-PS Tri-Block Copolymers and Its Corrosion Inhibition Behaviour on Mild Steel in Acidic Solution, Int. J. Sci. Res. Public., 2014, 4, p 2250–3153

C.B. Verma, M.A. Quraishi, and E.E. Ebenso, Electrochemical and Thermodynamic Investigation of Some Soluble Terpolymers as Effective Corrosion Inhibitors for Mild Steel in 1 M Hydrochloric Acid Solution, Int. J. Electrochem. Sci., 2013, 8, p 12894–12906

S. Rajendran, S.P. Sridevi, N. Anthony, A. John Amalraji, and M. Sundaravadivedi, Corrosion Behavior of Carbon Steel in Polyvinyl Alcohol, Anti-corros. Method Mater., 2005, 52, p 102–107CrossRef

S. Belkaid, K. Tebbji, A. Mansri, A. Chetouani, and B. Hammouti, Poly(4-Vinylpyridine-Hexadecyl Bromide) as Corrosion Inhibitor for Mild Steel in Acid Chloride Solution, Res. Chem. Intermed., 2012, 38, p 2309–2325CrossRef

U. León-Silva, M.E. Nicho, J.G. González-Rodríguez, J.G. Chacón-Nava, and V.M. Salinas-Bravo, Effect of Thermal Annealing of Poly(3-Octylthiophene) Films Covered Stainless Steel on Corrosion Properties, J. Solid State Electrochem., 2010, 14, p 1089–1100CrossRef

S.A. Umoren, M.M. Solomon, I.I. Udosoro, and A.P. Udoh, Synergistic and Antagonistic Effects Between Halide Ions and Carboxymethyl Cellulose for the Corrosion Inhibition of Mild Steel in Sulphuric Acid Solution, Cellulose, 2010, 17, p 635–648CrossRef

S.A. Umoren, Y. Li, and F.H. Wang, Synergistic Effect of Iodide Ion and Polyacrylic Acid on Corrosion Inhibition of Iron in H₂SO₄ Investigated by Electrochemical Techniques, Corros. Sci., 2010, 52, p 2422–2429CrossRef

M.M. Solomon, S.A. Umoren, I.I. Udosoro, and A.P. Udoh, Inhibitive and Adsorption Behaviour of Carboxymethyl Cellulose on Mild Steel Corrosion in Sulphuric Acid Solution, Corros. Sci., 2010, 52, p 1317–1325CrossRef

10.

S.A. Umoren, M.M. Solomon, A.U. Israel, U.M. Eduok, and A.E. Jonah, Comparative Study of the Corrosion Inhibition Efficacy of Polypropylene Glycol and Poly (Methacrylic Acid) for Mild Steel in Acid Solution, J. Dispers. Sci. Technol., 2015, 36, p 1721–1735CrossRef

11.

S.A. Umoren, I.B. Obot, and E.E. Ebenso, Corrosion Inhibition of Aluminium Using Exudates Gum from Pachylobus edulis in the Presence of Halide Ions in HCl, E-J. Chem., 2008, 5, p 355–364CrossRef

12.

S.A. Umoren and E.E. Ebenso, Studies of the Anti-corrosive Effect of Raphia hookeri Exudates Gum-Halide Mixture for Aluminium Corrosion in Acidic Medium, Pigm. Res. Technol., 2008, 37, p 173–182CrossRef

13.

K.M. Govindaraju, D. Gopi, and K. Anver, Basha, Synthesis, Characterization, and Electrochemical Evaluation of Anti-Corrosive Performance of Poly((N-Methacryloyloxymethyl) Benzotriazole-co-N-Vinylpyrrolidone) Coatings, J. Appl. Electrochem., 2013, 43, p 1043–1054CrossRef

14.

Y. Xu, B. Zhang, L. Zhao, and Y. Cui, Synthesis of Polyaspartic Acid/5-Aminoorotic Acid Graft Copolymer and Evaluation of Its Scale Inhibition And Corrosion Inhibition Performance, Desalination, 2013, 311, p 156–161CrossRef

15.

C. Jeyaprabha, S. Sathiyanarayanan, and G. Venkatachari, Influence of Halide Ions on the Adsorption of Diphenylamine on Iron in 0.5 M H₂SO₄ Solution, Electrochim. Acta, 2006, 51, p 4080–4088CrossRef

16.

M. Srimathi, R. Rajalakshmi, and S. Subhashini, Polyvinyl Alcohol–Sulphanilic Acid Water Soluble Composite as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Medium, Arab. J. Chem., 2014, 7, p 647–656CrossRef

17.

A.A.F. Sabirneeza and S. Subhashini, Novel Water-Soluble, Conducting Polymer Composite for Mild Steel Acid Corrosion Inhibition, J. Appl. Polym. Sci., 2013, 127, p 3084–3092CrossRef

18.

R. Karthikaiselvi and S. Subhashini, The Water Soluble Composite Poly(vinylpyrrolidone–methylaniline): A New Class of Corrosion Inhibitors of Mild Steel in Hydrochloric Acid Media, Arab. J. Chem., 2012, doi:10.1016/j.arabjc.2012.10.024

19.

B. Agarwal, L. Broutman, and K. Chandrashekhara, Analysis and Performance of Fiber Composites, 3rd ed., Wiley, New Jersey, 2006

20.

A.A.F. Sabirneeza, S. Subhashini, and R. Rajalakshmi, Water Soluble Conducting Polymer Composite of Polyvinyl Alcohol and Leucine: An Effective Acid Corrosion Inhibitor for Mild Steel, Mater. Corros., 2013, 64, p 74–82CrossRef

21.

H. Ashassi-Sorkhabi and M. Eshaghi, Electro-Synthesis of Nano-colloidal PANI/ND Composite for Enhancement of Corrosion-Protection Effect of PANI, Coatings, J. Mater. Eng. Perform., 2013, 22, p 3755–3761CrossRef

22.

A.M. Atta, H.A. Allohedan, G.A. El-Mahdy, and A.O. Ezzat, Application of Stabilized Silver Nanoparticles Thin Films as Corrosion Inhibitors for Carbon Steel Alloy in 1 M HCl, J. Nanomater., 2013, doi:10.1155/2013/580607

23.

A.M. Atta, G.A. El-Mahdy, H.A. Allohedan, and A.O. Ezzat, Synthesis and Application of Hybrid Polymer Composites Based on Silver Nanoparticles as Corrosion Protection for Line Pipe Steel, Molecules, 2014, 19, p 6246–6262CrossRef

24.

H. Haiza, A. Azizan, A.H. Mohidin, and D.S.C. Halin, Green Synthesis of Silver Nanoparticles Using Local Honey, Nano Hybrids, 2013, 4, p 87–98CrossRef

25.

ASTM G3-89, Standard Practice for Conventions Applicable to Electrochemical Measurements in Corrosion Testing, West Conshohocken, ASTM, 2010

26.

ASTM G31-72, Standard Practice for Laboratory Immersion Corrosion Testing of Metals, ASTM, West Conshohocken, 2004

27.

R.M. Silverstein, G.C. Bassler, and T.C. Morrill, Spectrometric Identification of Organic Compounds, 7th ed., Wiley, New York, 1981, p 95–98

28.

I.H. Chowdhury, S. Ghosh, M. Roy, and M.K. Naskar, Green Synthesis of Water-Dispersible Silver Nanoparticles At Room Temperature Using Green Carambola (Star Fruit) Extract, J. Sol-Gel Sci. Technol., 2015, 73, p 199–207CrossRef

29.

V. Gopinath, D. Mubara Ali, S. Priyadarshini, N.M. Priyadharsshini, N. Thajuddin, and P. Velusamy, Biosynthesis of Silver Nanoparticles from Tribulus terrestris and Its Antimicrobial Activity: A Novel Biological Approach, Colloids Surf. B, 2012, 96, p 69–74CrossRef

30.

Z. Khan, S.A. Al-Thabaiti, A.Y. Obaid, and A.O. Al-Youbi, Preparation and Characterization of Silver Nanoparticles by Chemical Reduction Method, Colloids Surf. B, 2011, 82, p 513–517CrossRef

31.

S. Coseri, A. Spatareanu, L. Sacarescu, C. Rimbu, D. Suteu, S. Spirk, and V. Harabagiu, Green Synthesis of the Silver Nanoparticles Mediated by Pullulan and 6-Carboxypullulan, Carbohydr. Polym, 2015, 116, p 9–17CrossRef

32.

N. Bhattarai, S. Khanal, P.R. Pudasaini, S. Pahl, and D. Romero-Urbina, Citrate Stabilized Silver Nanoparticles: Study of Crystallography and Surface Properties, Int. J. Nanotechnol. Mol. Comput., 2011, 3, p 15–28CrossRef

33.

E.E. Oguzie, Y. Li, and F.H. Wang, Effect of Ascorbic Acid on Mild Steel Dissolution in Sulphuric Acid Solution Investigated by Electrochemical Polarization and Surface Probe Techniques, J. Appl. Electrochem., 2007, 37, p 1183–1190CrossRef

34.

X. Li and X. Xie, Adsorption and Inhibition Effect of Two Aminopyrimidine Derivatives on Steel Surface in H₂SO₄ Solution, J. Taiwan Inst. Chem. Eng., 2014, 45, p 3033–3045CrossRef

35.

A.K. Singh and M.A. Quraishi, Effect of Cefazolin on the Corrosion of Mild Steel in HCl Solution, Corros. Sci., 2010, 52, p 152–160CrossRef

36.

M. Lagrenée, B. Mernari, M. Bouanis, M. Traisnel, and F. Bentiss, Study of the Mechanism and Inhibiting Efficiency of 3,5-Bis(4-Metylthiophenyl)-4h-1,2,4-Triazole on Mild Steel Corrosion in Acidic Media, Corros. Sci., 2002, 44, p 573–588CrossRef

37.

N. Labjar, M. Lebrini, F. Bentiss, N.E. Chihib, S. El Hajjaji, and C. Jama, Corrosion Inhibition of Carbon Steel and Antibacterial Properties of Aminotris-(Methylnephosnic) Acid, Mater. Chem. Phys., 2010, 119, p 330–336CrossRef

38.

M. Yadav, S. Kumar, and L. Gope, Experimental and Theoretical Study on Amino Acid Derivatives as Eco-Friendly Corrosion Inhibitor on Mild Steel in Hydrochloric Acid Solution, J. Adhes. Sci. Technol., 2014, 28, p 1072–1089CrossRef

39.

M. Lebrini, M. Lagrenée, H. Vezin, M. Traisnel, and F. Bentiss, Experimental and Theoretical Study for Corrosion Inhibition of Mild Steel in Normal Hydrochloric Acid Solution by Some New Macrocyclic Polyether Compounds, Corros. Sci., 2007, 49, p 2254–2269CrossRef

40.

H. Zhang, D. Wang, X. Jin, T. Yang, and X. Shen, Preparation of Bi-modified Amphoteric Oligochitosan Derivatives and Electrochemical Evaluation on Anticorrosion Performances, J. Appl. Polym. Sci., 2015, 132, p 41714

41.

X. Li, S. Deng, and H. Fu, synergistic Inhibition Effect of Red Tetrazolium and Uracil on the Corrosion of Cold Rolled Steel in H₃PO₄ Solution: Weight Loss, Electrochemical, and AFM Approaches, Mater. Chem. Phys., 2009, 115, p 815–824CrossRef

42.

X. He, Y. Jiang, C. Li, W. Wang, B. Hou, and L. Wu, Inhibition Properties and Adsorption Behavior of Imidazole and 2-Phenyl-2-Imidazoline on AA5052 in 1.0 M HCl Solution, Corros. Sci., 2014, 83, p 124–136CrossRef

43.

R. Karthikaiselvi, S. Subhashini, and R. Rajalakshmi, Poly (Vinyl Alcohol–Aniline) Water Soluble Composite as Corrosion Inhibitor for Mild Steel in 1 M HCl, Arab. J. Chem., 2012, 5, p 517–522CrossRef

44.

P.K. Khanna, N. Singh, S. Charan, V.V.V.S. Subbarao, R. Gokhale, and U.P. Mulik, Synthesis and Characterization of Ag/PVA Nanocomposite by Chemical Reduction Method, Mater. Chem. Phys., 2005, 93, p 117–121CrossRef

45.

M.A. Amin, Q. Mohsen, and O.A. Hazzazi, Synergistic Effect of I-Ions on the Corrosion Inhibition of Al in 1.0 M Phosphoric Acid Solutions by Purine, Mater. Chem. Phys., 2009, 114, p 908–914CrossRef

46.

S.S. Abd El Rehim, M.A.M. Ibrahim, and K.F. Khaled, Amino Antipyrine as an Inhibitor of Mild Steel Corrosion in HCl Solution, Mater. Chem. Phys., 2001, 70, p 268–276CrossRef

47.

P. Roy, A. Pal, and D. Sukul, Origin of the Synergistic Effect Between Polysaccharide and Thiourea Towards Adsorption and Corrosion Inhibition for Mild Steel in Sulphuric Acid, RSC Adv., 2014, 4, p 10607–10613CrossRef

48.

S.A. Umoren, Inhibition of Aluminium and Mild Steel Corrosion in Acidic Medium Using Gum Arabic, Cellulose, 2008, 15, p 751–761CrossRef

49.

M.M. Solomon and S.A. Umoren, Performance Evaluation of Poly (Methacrylic Acid) as Corrosion Inhibitor in the Presence of Iodide Ions for Mild Steel in H₂SO₄ Solution, J. Adhes. Sci. Technol., 2015, 29, p 1060–1080CrossRef

50.

K. Ramya, R. Mohan, K.K. Anupama, and A. Joseph, Electrochemical and Theoretical Studies on the Synergistic Interaction and Corrosion Inhibition of Alkyl Benzimidazoles and Thiosemicarbazide Pair on Mild Steel in Hydrochloric Acid, Mater. Chem. Phys., 2015, 149–150, p 632–647CrossRef

51.

D. Thirumoolan, V.A. Katkar, G. Gunasekaran, T. Kanai, and K.A. Basha, Hyperbranched Poly(cyanurateamine): A New Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Medium, Prog. Organ. Coat., 2014, 77, p 1253–1263CrossRef

52.

H. Ashassi-Sorkhabi, B. Shaabani, and D. Seifzadeh, Corrosion Inhibition of Some Schiff Base Compounds in Hydrochloric Acid, Appl. Surf. Sci., 2005, 239, p 154–164CrossRef

53.

R. Solmaz, G. Kardas, B. Yazıcı, and M. Erbil, Adsorption and Corrosion Inhibitive Properties of 2-Amino-5-Mercapto-1,3,4-Thiadiazole on Mild Steel in Hydrochloric Acid Media, Colloids Surf. A, 2008, 312, p 7–17CrossRef

54.

J.I. Bhat and V.D.P. Alva, A Study of Aluminium Corrosion Inhibition in Acid Medium by an Antiemitic Drug, Trans. Ind. Inst. Met., 2011, 64, p 377–384CrossRef

55.

F.S. de Souza, C. Giacomelli, R.S. Gonçalves, and A. Spinelli, Adsorption Behavior of Caffeine as a Green Corrosion Inhibitor for Copper, Mater. Sci. Eng. C, 2012, 32, p 2436–2444CrossRef

Titel: Polypropylene Glycol-Silver Nanoparticle Composites: A Novel Anticorrosion Material for Aluminum in Acid Medium
verfasst von: Moses M. Solomon
Saviour A. Umoren
Aniekemeabasi U. Israel
Eno E. Ebenso
Publikationsdatum: 18.09.2015
Verlag: Springer US
Erschienen in: Journal of Materials Engineering and Performance / Ausgabe 11/2015
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI: https://doi.org/10.1007/s11665-015-1716-6

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 11/2015

Effect of Preheat Treatment on the Texture Evolution During Cold Rolling of AA 3003 Aluminum Alloy

Characterization of GNP-Containing Al2O3 Nanocomposites Fabricated via High Frequency-Induction Heat Sintering Route

Comparative Studies on Al-Based Composite Powder Reinforced with Nano Garnet and Multi-wall Carbon Nanotubes

Effect of 0.2 and 0.5% Ti on the microstructure and mechanical properties of 13Cr supermartensitic stainless steel

Effect of Ultrasonic Vibration on Compression Behavior and Microstructural Characteristics of Commercially Pure Aluminum

Effect of Surplus Phase on the Microstructure and Mechanical Properties in Al-Cu-Mg-Ag Alloys with High Cu/Mg Ratio

Premium Partner

Marktübersichten