Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Journal of Coatings Technology and Research
Published in: Journal of Coatings Technology and Research 4/2022

17-02-2022

Synthesis and application of nano-organosilicon coating through cyclonic plasma deposition on a polymeric separator for lithium-ion batteries

Authors: Li-Yu Wu, Fang-Yi Chung, Chun Huang

Published in: Journal of Coatings Technology and Research | Issue 4/2022

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

This study focuses on the vacuum-free deposition of nano-organosilicon coating through cyclonic plasma deposition on polymeric separators for application in lithium-ion batteries. Optical emission spectroscopy was used to determine various chemical plasma species and the association of the cyclonic plasma deposition of nano-organosilicon coating. The surface detections by ATR-FTIR and XPS revealed that the plasma power is the main reason affecting nano-organosilicon coating from organic to more inorganic features. The cyclonic-plasma-deposited nano-organosilicon coating was applied to the surface of a polymeric lithium-ion battery separator. The surface characteristics of the altered separator were analyzed through ATR-FTIR, TGA, EIS, and uptake test. The results indicated that the deposition of the nano-organosilicon coating on the separator surface improved the heat resistance and electrochemical performance of the polymeric separator. The synergistic effect of the cyclonic-plasma-coated separator was observed; that is, the electrolyte uptake of the cyclonic-plasma-coated separators was larger than that of a commercial separator.

Graphical abstract

This study focuses on the vacuum-free deposition of nano-organosilicon coating through cyclonic plasma deposition on polymeric separators for application in lithium-ion batteries. The surface characteristics of the altered separator were analyzed through ATR-FTIR, TGA, EIS, and uptake test. The results indicated that the deposition of the nano-organosilicon coating on the separator surface improved the heat resistance and electrochemical performance of the polymeric separator. The synergistic effect of the cyclonic-plasma-coated separator was observed; that is, the electrolyte uptake of the cyclonic-plasma-coated separators was larger than that of a commercial separator.
previous article Effect of coating pigment type on paper printability with water-based inks
next article Preparation and characterization of PVOH/kaolin and PVOH/talc coating dispersion by one-step process

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
Manthiram, A, “An Outlook on Lithium Ion Battery Technology.” ACS Cent. Sci., 3 (10) 1063–1069 (2017)CrossRef
2.
Kim, JY, Lim, DY, “Surface-Modified Membrane as a Separator for Lithium-Ion Polymer Battery.” Energies, 3 (4) 866–885 (2010)CrossRef
3.
Manthiram, A, “A Reflection on Lithium-Ion Battery Cathode Chemistry.” Nat. Commun., 11 (1) 1550 (2020)CrossRef
4.
Schmitt, M, Scharfer, P, Schabel, W, “Slot Die Coating of Lithium-Ion Battery Electrodes: Investigations on Edge Effect Issues for Stripe and Pattern Coatings.” J. Coat. Technol. Res., 11 (1) 57–63 (2014)CrossRef
5.
Cznotka, E, Jeschke, S, Schmohl, S, Johansson, P, Wiemhofer, H-D, “3D Laser Scanning Confocal Microscopy of Siloxane-Based Comb and Double-Comb Polymers in PVDF-HFP Thin Films.” J. Coat. Technol. Res., 13 (4) 577–587 (2016)CrossRef
6.
Liang, CH, Juang, RS, Tsai, CY, Huang, C, “Tailoring Surface Properties of Polymeric Separators for Lithium-ion Batteries by 13.56 MHz Radio-frequency Plasma Glow Discharge.” Jpn. J. Appl. Phys., 52 (11) 11NM07 (2013)
7.
Yuan, J-J, Song, Y-Z, Zhang, Y, Qiu, Z-L, Sun, C-C, Yin, X, Zhu, L-P, Zhu, B-K, “Polyphenols Assisted Silica Coating on Polypropylene Separators with Improved Wettability and Heat-Resistance for Lithium-Ion Batteries.” J. Appl. Polym. Sci., 136 (13) 47277 (2019)CrossRef
8.
Zhang, SS, “A Review on the Separators of Liquid Electrolyte Li-Ion Batteries.” J. Power Sources, 164 (1) 351 (2007)CrossRef
9.
Jeong, H-S, Lee, S-Y, “Closely Packed SiO2 Nanoparticles/poly(vinylidene fluoride-hexafluoropropylene) Layers-coated Polyethylene Separators for Lithium-ion Batteries.” J. Power Sources, 196 (16) 6716 (2011)CrossRef
10.
Shi, C, Zhang, P, Chen, L, Yang, P, Zhao, J, “Effect of a Thin Ceramic-coating Layer on Thermal and Electrochemical Properties of Polyethylene Separator for Lithium-ion Batteries.” J. Power Sources, 270 547 (2014)CrossRef
11.
Lee, Y, Lee, H, Lee, T, Ryou, M-H, Lee, YM, “Synergistic Thermal Stabilization of Ceramic/Co-polyimide Coated Polypropylene Separators for Lithium-ion Batteries.” J. Power Sources, 294 537 (2015)CrossRef
12.
Yu, QS, Reddy, CM, Moffitt, CE, Wieliczka, DM, Johnson, R, Deffeyes, JE, Yasuda, HK, “Improved Corrosion Protection of Aluminum Alloys by System Approach Interface Engineering: Part 4 Spray Paint Primer-Coated Aluminum Alloys.” Corrosion, 57 (9) 802–814 (2001)CrossRef
13.
Vartiainen, J, Malm, T, “Surface Hydrophobization of CNF Films by Roll-to-Roll HMDSO Plasma Deposition.” J. Coat. Technol. Res., 13 (6) 1145–1149 (2016)CrossRef
14.
Liu, T, Hong, L, Hottel, T, Dong, X, Yu, Q, Chen, M, “Non-Thermal Plasma Enhanced Bonding of Resin Cement to Zirconia Ceramic.” Clin. Plasma Med., 4 (2) 50–55 (2016)CrossRef
15.
Choukourov, A, Pihosh, Y, Stelmashuk, V, Biederman, H, Slavinska, D, Kormunda, M, Zajickova, L, “Rf Sputtering of Composite SiOx/Plasma Polymer Films and Their Basic Properties.” Surf. Coat. Technol., 151 214–217 (2002)CrossRef
16.
Carpentier, J, Grundmeier, G, “Chemical Structure and Morphology of Thin Bilayer and Composite Organosilicon and Fluorocarbon Microwave Plasma Polymer Films.” Surf. Coat. Technol., 192 (2–3) 189–198 (2005)CrossRef
17.
Farhat, S, Gilliam, M, Rabago-Smith, M, Baran, C, Walter, N, Zand, A, “Polymer Coatings for Biomedical Applications Using Atmospheric Pressure Plasma.” Surf. Coat. Technol., 241 123–129 (2013)CrossRef
18.
Gilliam, M, Farhat, S, Zand, A, Stubbs, B, Magyar, M, Garner, G, “Atmospheric Plasma Surface Modification of PMMA and PP Micro-Particles.” Plasma Processes Polym., 11 (11) 1037–1043 (2014)CrossRef
19.
Nattinen, K, Nikkola, J, Minkkinen, H, Heikkila, P, Lavonen, J, Tuominen, M, “Reel-to-Reel Inline Atmospheric Plasma Deposition of Hydrophobic Coatings.” J. Coat. Technol. Res., 8 (2) 237–245 (2011)CrossRef
20.
Huang, C, Wu, SY, Liu, YC, Chang, Tsai, CY, "Static Water Contact Angle Analysis of Cyclonic Atmospheric Pressure Plasma-activated Polycarbonate." Jpn. J. Appl. Phys., 50 (1) 01AH05-1-5 (2011)
21.
Niu, G, Li, Y, Tang, J, Wang, X, Duan, Y, “Optical and Electrical Analysis of Multi-Electrode Cylindrical Dielectric Barrier Discharge (DBD) Plasma Reactor.” Vacuum, 157 465–474 (2018)CrossRef
22.
Ma, WC, Lin, CH, Huang, C, "Deposition of Fluorine-containing Thin Film by Atmospheric Pressure Plasma Jet and Film Surface Structural Transition." Plasma Processes Polym., 12 (4) 362 (2015)
23.
Li, HL, Huang, C, “Spectroscopic Diagnostics of Enhanced Magnetron and Mesh Separation Effects in Cyclonic Atmospheric Pressure Plasma Surface Modification of Polyethylene Terephthalate.” Plasma Chem. Plasma Process., 37 (6) 1587–1605 (2017)CrossRef
24.
Chen, T-H, Chung, F-Y, Jiang, W-F, Huang, C, “A Study of Plasma Power Effects on Surface Activation of Polystyrene.” Vacuum, 186 110069 (2021)
25.
Lin, JH, Tsai, CY, Liu, WT, Syu, YK, Huang, C, “Large-area Organosilicon Film Deposition Using Cyclonic Atmospheric Pressure Glow Discharge.” Jpn. J. Appl. Phys., 52 (5) 05EA01-05EB06 (2013)
26.
Guruvenket, S, Andrie, S, Simon, M, Johnson, KW, Sailer, RA, “Atmospheric-Pressure Plasma-Enhanced Chemical Vapor Deposition of a-SiCN: H Films: Role of Precursors on the Film Growth and Properties.” ACS Appl. Mater. Interfaces, 4 (10) 5293–5299 (2012)CrossRef
27.
Blaszczyk-Lezak, I, Wrobel, AM, Aoki, T, Nakanishi, Y, Kucinska, I, Tracz, A, “Remote Nitrogen Microwave Plasma Chemical Vapor Deposition from a Tetramethyldisilazane Precursor. 1. Growth Mechanism, Structure, and Surface Morphology of Silicon Carbonitride Films.” Thin Solid Films, 497 (1–2) 24–34 (2006)CrossRef
28.
Nowling, GR, Yajima, M, Babayan, SE, Moravej, M, Yang, X, Hoffman, W, Hicks, RF, “Chamberless Plasma Deposition of Glass Coatings on Plastic.” Plasma Sources Sci. Technol., 14 (3) 477–484 (2005)CrossRef
29.
Ladwig, A, Babayan, S, Smith, M, Hester, M, Highland, W, Koch, R, Hicks, RF, “Atmospheric Plasma Deposition of Glass Coatings on Aluminum.” Surf. Coat. Technol., 201 (14) 6460–6464 (2007)CrossRef
30.
Borris, J, Thomas, M, Klages, C-P, Faupel, F, Zaporojtchenko, V, “Investigations into Composition and Structure of DBD-Deposited Amino Group Containing Polymer Layers.” Plasma Processes Polym., 4 S482–S486 (2007)CrossRef
31.
Weichart, J, Mtiller, J, “Preparation and Characterization of Glassy Plasma Polymer Membranes.” Colloid Polym. Sci., 85 111–117 (1991)
32.
Morent, R, Geyer, ND, Vlierberghe, SV, Beaurain, A, Dubruel, P, Payen, E, “Influence of Operating Parameters on Plasma Polymerization of Acrylic Acid in a Mesh-to-Plate Dielectric Barrier Discharge.” Prog. Org. Coat., 70 (4) 336–341 (2011)CrossRef
33.
Grill, A, Neumayer, DA, “Structure of Low Dielectric Constant to Extreme Low Dielectric Constant SiCOH Films: Fourier Transform Infrared Spectroscopy Characterization.” J. Appl. Phys., 94 (10) 6697–6707 (2003)CrossRef
34.
Kim, CY, Kim, SH, Kim, HS, Navamathavan, R, Choi, CK, “Formation Mechanism and Structural Characteristics of Low-Dielectric-Constant SiOCH films Deposited by Using Plasma-Enhanced Chemical-Vapor Deposition with DMDMS and O2 Precursors.” J. Korean Phys. Soc., 50 (4) 1119–1124 (2007)CrossRef
35.
Huang, C, Lin, HH, Li, C, “Atmospheric Pressure Plasma Polymerization of Super-Hydrophobic Nano-Films Using Hexamethyldisilazane Monomer.” Plasma Chem. Plasma Process, 35 (6) 1015–1028 (2015)CrossRef
36.
Wu, LY, Kuo, YL, Chang, KH, Chen, TH, Cheng, CY, Liu, YS, Huang, C, “Effects of Cyclonic Plasma Deposited Organosilicon Nano-coating on 316 Stainless Steel and Its Surface Characterization.” Surf. Interface Anal., 51 (10) 993–1000 (2019)CrossRef
37.
Kim, Y-H, Hwang, MS, Kim, HJ, Kim, JY, Lee, Y, “Infrared Spectroscopy Study of Low-Dielectric-Constant Fluorine-Incorporated and Carbon-Incorporated Silicon Oxide Films.” J. Appl. Phys., 90 (7) 3367–3370 (2001)CrossRef
38.
Pai, PG, Chao, SS, Takagi, Y, Lucovsky, G, “Infrared Spectroscopic Study of SiOx Films Produced by Plasma Enhanced Chemical Vapor Deposition.” J. Vac. Sci. Technol., A, 4 (3) 689–694 (1986)
39.
Lucovsky, G, Manitini, MJ, Srivastava, JK, Irene, EA, “Low‐Temperature Growth of Silicon Dioxide Films: A Study of Chemical Bonding by Ellipsometry and Infrared Spectroscopy.” J. Vac. Sci. Technol., B, 5 (2) 530–537 (1987)
40.
Yang, SH, Liu, CH, Hsu, WT, Chen, H, “Preparation of Super-Hydrophobic Films Using Pulsed Hexafluorobenzene Plasma.” Surf. Coat. Technol., 203 (10–11) 1379–1383 (2009)CrossRef
41.
Huang, C, Lin, C-C, Tsai, C-Y, Juang, R-S, “Tailoring Surface Properties of Polymeric Separators for Lithium-Ion Batteries by Cyclonic Atmospheric-Pressure Plasma.” Plasma Processes Polym., 10 (5) 407–415 (2013)CrossRef
42.
Tseng, YC, Li, HL, Huang, C, “Atmospheric-pressure Plasma Activation and Surface Characterization on Polyethylene Membrane Separator.” Jpn. J. Appl. Phys., 56 (1) 01AF03 (2017)
Metadata
Title
Synthesis and application of nano-organosilicon coating through cyclonic plasma deposition on a polymeric separator for lithium-ion batteries
Authors
Li-Yu Wu
Fang-Yi Chung
Chun Huang
Publication date
17-02-2022
Publisher
Springer US
Published in
Journal of Coatings Technology and Research / Issue 4/2022
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-021-00595-6

Other articles of this Issue 4/2022

Journal of Coatings Technology and Research 4/2022 Go to the issue

OriginalPaper

Validation of adhesion characterization methods for antistick coatings applied in cooking systems

OriginalPaper

Preparation and characterization of PVOH/kaolin and PVOH/talc coating dispersion by one-step process

OriginalPaper

Improving anticorrosion performance of epoxy coating by hybrids of rGO and g-C3N4 nanosheets

OriginalPaper

The nano building blocks approach for modification of surface properties of nanocomposite inorganic–organic films

OriginalPaper

Study on the ultraviolet absorbing properties of cotton fabric finished with boron and nitrogen co-doped carbon dots

OriginalPaper

Pigmented silicone/epoxy novel blends for preparation of stratified nontoxic foul release coatings

Premium Partners

    Image Credits