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Erschienen in: Journal of Coatings Technology and Research 4/2022

17.02.2022

Synthesis and application of nano-organosilicon coating through cyclonic plasma deposition on a polymeric separator for lithium-ion batteries

verfasst von: Li-Yu Wu, Fang-Yi Chung, Chun Huang

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 4/2022

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Abstract

This study focuses on the vacuum-free deposition of nano-organosilicon coating through cyclonic plasma deposition on polymeric separators for application in lithium-ion batteries. Optical emission spectroscopy was used to determine various chemical plasma species and the association of the cyclonic plasma deposition of nano-organosilicon coating. The surface detections by ATR-FTIR and XPS revealed that the plasma power is the main reason affecting nano-organosilicon coating from organic to more inorganic features. The cyclonic-plasma-deposited nano-organosilicon coating was applied to the surface of a polymeric lithium-ion battery separator. The surface characteristics of the altered separator were analyzed through ATR-FTIR, TGA, EIS, and uptake test. The results indicated that the deposition of the nano-organosilicon coating on the separator surface improved the heat resistance and electrochemical performance of the polymeric separator. The synergistic effect of the cyclonic-plasma-coated separator was observed; that is, the electrolyte uptake of the cyclonic-plasma-coated separators was larger than that of a commercial separator.

Graphical abstract

This study focuses on the vacuum-free deposition of nano-organosilicon coating through cyclonic plasma deposition on polymeric separators for application in lithium-ion batteries. The surface characteristics of the altered separator were analyzed through ATR-FTIR, TGA, EIS, and uptake test. The results indicated that the deposition of the nano-organosilicon coating on the separator surface improved the heat resistance and electrochemical performance of the polymeric separator. The synergistic effect of the cyclonic-plasma-coated separator was observed; that is, the electrolyte uptake of the cyclonic-plasma-coated separators was larger than that of a commercial separator.

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Metadaten
Titel
Synthesis and application of nano-organosilicon coating through cyclonic plasma deposition on a polymeric separator for lithium-ion batteries
verfasst von
Li-Yu Wu
Fang-Yi Chung
Chun Huang
Publikationsdatum
17.02.2022
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 4/2022
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-021-00595-6

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