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Published in: Journal of Materials Science: Materials in Electronics 9/2021

18-04-2021

X-ray photoelectron, FTIR, and Mössbauer spectroscopy studied the effect of Fe2O3/CuO substitution on structural and electrical properties of lithium borosilicate glasses

Authors: Asmaa Ratep, Ismail Kashif

Published in: Journal of Materials Science: Materials in Electronics | Issue 9/2021

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Abstract

Effect of substitution of CuO with Fe2O3 on the iron oxidation state and electrical conductivity of some lithium borosilicate glass samples studied using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron (XPS), and Mössbauer spectroscopy (MS). Infrared results show that the homogeneity of the glass increases with the iron concentration increases. X-ray electron spectroscopy measurements showed that the ratios of Fe+2/Fe+3 depend on CuO. The results also indicated that the iron ions in the glass samples under study contain Fe2O3 more than 7.5% in the ferrous state. By studying the electrical conductivity, it was found that the conduction of samples depends on the oxidation state of copper and the mixed transition metal effect.

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Metadata
Title
X-ray photoelectron, FTIR, and Mössbauer spectroscopy studied the effect of Fe2O3/CuO substitution on structural and electrical properties of lithium borosilicate glasses
Authors
Asmaa Ratep
Ismail Kashif
Publication date
18-04-2021
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 9/2021
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-021-05865-y

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