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24-11-2017 | Original Paper

Carboxymethyl cellulose coated Fe₃O₄@SiO₂ core–shell magnetic nanoparticles for methylene blue removal: equilibrium, kinetic, and thermodynamic studies

Authors: Maryam Zirak, Aysan Abdollahiyan, Bagher Eftekhari-Sis, Mahnaz Saraei

Published in: Cellulose | Issue 1/2018

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Abstract

Fe₃O₄@SiO₂ core–shell magnetic nanoparticles (MNPs) were prepared by chemical coprecipitation of FeCl₃·6H₂O and FeCl₂·4H₂O in alkaline solution, followed by silylation using triethoxy silane, and then by treatment with 3-aminopropyltriethoxysilane. The corresponding MNPs were coated with carboxymethyl cellulose (CMC) by amide formation between carboxyl groups of CMC and amine functional groups of nanoparticles. The structure of MNPs was characterized by FT-IR, SEM, EDX, TEM, XRD, VSM and TGA analysis. CMC-coated Fe₃O₄@SiO₂ magnetic nanoparticles were used as an efficient adsorbent for the removal of methylene blue (MB, a cationic dye) from aqueous solutions. The impact of various factors such as adsorbent dosage, pH, initial concentration of MB, temperature and contact time were investigated. The kinetic, isotherms, and thermodynamic parameters of adsorption were also studied.

previous article Dual-responsive composite hydrogels based on TEMPO-oxidized cellulose nanofibril and poly(N-isopropylacrylamide) for model drug release

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Title: Carboxymethyl cellulose coated Fe3O4@SiO2 core–shell magnetic nanoparticles for methylene blue removal: equilibrium, kinetic, and thermodynamic studies
Authors: Maryam Zirak
Aysan Abdollahiyan
Bagher Eftekhari-Sis
Mahnaz Saraei
Publication date: 24-11-2017
Publisher: Springer Netherlands
Published in: Cellulose / Issue 1/2018
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-017-1590-5

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