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Topics in Catalysis
Erschienen in: Topics in Catalysis 13-14/2016

06.06.2016 | Original Paper

α-d-Glucopyranose Adsorption on a Pd30 Cluster Supported on Boron Nitride Nanotube

verfasst von: Antonio Prestianni, Remedios Cortese, Francesco Ferrante, Roberto Schimmenti, Dario Duca, Sophie Hermans, Dmitry Yu. Murzin

Erschienen in: Topics in Catalysis | Ausgabe 13-14/2016

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Abstract

Boron nitride nanotube (BNNT) as an innovative support for carbohydrate transformation processes was evaluated, using density functional theory. The α-d-glucopyranose adsorption on a Pd30 cluster, supported on BNNT, was used to check both the local activity of topologically different metallic sites and the effects of the proximity of the BNNT surface to the same metallic sites. Detailed geometrical and electronic analyses performed on Pd30/BNNT and α-d-glucopyranose/Pd30/BNNT systems were discussed. It was observed that the deposition of the Pd30 cluster onto the BNNT support gives rise to an electronic rearrangement, determining a charge transfer from the support to the adsorbed metal cluster. The charge transfer, as shown by the analysis of molecular electrostatic potential, seems to generate electron-rich and electron-poor zones in the Pd30 cluster. The α-d-glucopyranose species, regardless the interaction geometry experienced, acts as an electron donor and preferentially adsorbs close to the electron-poor metal/support interface.
Vorheriger Artikel Catalytic Hydrogenation of d-Xylose Over Ru Decorated Carbon Foam Catalyst in a SpinChem® Rotating Bed Reactor
Nächster Artikel Pd-Nanoparticles Confined Within Hollow Polymeric Framework as Effective Catalysts for the Synthesis of Fine Chemicals

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Metadaten
Titel
α-d-Glucopyranose Adsorption on a Pd30 Cluster Supported on Boron Nitride Nanotube
verfasst von
Antonio Prestianni
Remedios Cortese
Francesco Ferrante
Roberto Schimmenti
Dario Duca
Sophie Hermans
Dmitry Yu. Murzin
Publikationsdatum
06.06.2016
Verlag
Springer US
Erschienen in
Topics in Catalysis / Ausgabe 13-14/2016
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-016-0638-3

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