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Journal of Materials Science

Erschienen in:

22.02.2019 | Polymers

A simple and rapid Fourier transform infrared method for the determination of the degree of acetyl substitution of cellulose nanocrystals

verfasst von: Wenwen Li, Guixin Cai, Pudun Zhang

Erschienen in: Journal of Materials Science | Ausgabe 10/2019

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Abstract

The application of cellulose nanocrystal (CNC) is limited by the rich hydroxyl groups on its surface. It can be promoted by acetylation. The degree of acetyl substitution of CNC is a key index to evaluate its performance. In this paper, a series of acetylated CNC with different degrees of substitution (DS) were prepared by acetylation with acetic anhydride and were analyzed by means of Fourier transform infrared spectroscopy (FTIR). The absorbance ratio (A_R) of the band at ~ 1745 cm⁻¹ to the one at 1164 cm⁻¹ was applied to determine the DS. An excellent linear relationship with a correlation coefficient \( R^{2} \ge 0.994 \) between A_R and the referenced DS from ¹H NMR was established. The regression equations, both based on band area ratio and band height ratio, can be directly applied to any FTIR instruments. The proposed method is simple, rapid and universal and can also be applied to determine the DS of any other cellulose derivatives.

Vorheriger Artikel Sodium alginate solutions: correlation between rheological properties and spinnability

Nächster Artikel Retraction Note to: MD simulations on the melting and compression of C, SiC and Si nanotubes

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Titel: A simple and rapid Fourier transform infrared method for the determination of the degree of acetyl substitution of cellulose nanocrystals
verfasst von: Wenwen Li
Guixin Cai
Pudun Zhang
Publikationsdatum: 22.02.2019
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 10/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-019-03471-2

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