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Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 3/2017

21.03.2017 | Original Paper: Sol-gel and hybrid materials with surface modification for applications

A simple strategy for the synthesis of Zn-IL-SBA-15 by sol–gel and the application in desulfurization

verfasst von: Zhiqing Zhang, Fang Wang, Huihui Nie, Ting Zhou, Guodong Zhang, Xiufeng Wang, Mei Cui, Yunze Li

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2017

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Abstract

SBA-15 functionalized with both zinc ions and ionic liquids was simply synthesized by sol–gel method. The characterization results of Fourier transform infrared spectroscopy, X-ray diffraction, elemental analysis, scanning electron microscopy, energy dispersive spectrometer, atomic absorption spectroscopy, and Brunauer–Emmett–Teller indicated that Zn2+ and imidazolium ionic liquid had been successfully immobilized on SBA-15, imidazolium as cation and [ZnCl3]- /[Zn2Cl5]- as complex anion. The immobilized Zn2+ and ionic liquid did not destroy the typical two-dimensional hexagonal mesoscopic structure of SBA-15 in this experimental research scope. But with the mass of Zn2+ and IL increasing, the mesoscopic order reduced, the pore diameter, pore volume and specific surface area decreased, whereas the wall thickness increased. The adsorption desulfurization experiments showed that the loaded Zn2+ and imidazolium ionic liquid improved the S-removal efficiency of SBA-15 especially for high aromatic sulfur compound.

Graphical Abstract

https://static-content.springer.com/image/art%3A10.1007%2Fs10971-017-4351-x/MediaObjects/10971_2017_4351_Figa_HTML.gif
Vorheriger Artikel Robust superhydrophobic candle soot and silica composite sponges for efficient oil/water separation in corrosive and hot water
Nächster Artikel Application of chalcone-based dithiocarbamate derivative incorporated sol–gel for the removal of Hg (II) ion from water

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Metadaten
Titel
A simple strategy for the synthesis of Zn-IL-SBA-15 by sol–gel and the application in desulfurization
verfasst von
Zhiqing Zhang
Fang Wang
Huihui Nie
Ting Zhou
Guodong Zhang
Xiufeng Wang
Mei Cui
Yunze Li
Publikationsdatum
21.03.2017
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 3/2017
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-017-4351-x

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