nach oben

Erschienen in:

2020 | OriginalPaper | Buchkapitel

Adsorption of Phosphates on Modified Eggshells - Batch and Fixed-Bed Column Process

verfasst von : Dawid Skrzypczak, Katarzyna Mikula, Daria Kocek, Grzegorz Izydorczyk, Rafał Taf, Anna Witek-Krowiak

Erschienen in: Practical Aspects of Chemical Engineering

Verlag: Springer International Publishing

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

The aim of this study was to develop a method for removing phosphate from an aqueous solution using iron (III) chloride-modified eggshells. The physicochemical properties of the modified biomass (FTIR, pH_PZC) were examined. The sorption capacity of the modified sorbents was tested. The kinetic rate constant was determined using the general model and equals 1.82 10⁻¹⁰ min⁻¹. The maximum sorption capacity of modified eggshells was determined using the Langmuir model (Q_max = 42.3 mg g⁻¹). Kinetic experiments were also carried out in a fixed-bed column. To establish the adsorption parameters in the bed column, the Thomas, Yoon-Nelson, and MDR models were used to describe the experimental data. The maximum sorption capacity in the column was 58.4 mg g⁻¹. Based on the result, modified eggshells could be used in the future as an effective sorbent for removing phosphate ions from aqueous solutions.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Vorheriges Kapitel Risk Assessment in Process Industries Using Fuzzy Logic Approach

Nächstes Kapitel Experimental Analysis of the Deposition of Aerosol Droplets in the Upper Airways of Human

Chen, J., Yan, L.G., Yu, H.Q., Li, S., Qin, L.L., Liu, G.Q., Li, Y.F., Du, B.: Efficient removal of phosphate by facile prepared magnetic diatomite and illite clay from aqueous solution. Chem. Eng. J. 287, 162–172 (2016). https://doi.org/10.1016/j.cej.2015.11.028CrossRef

Rocha, P.D., Franca, A.S., Oliveira, L.S.: Batch and column studies of phenol adsorption by an activated carbon based on acid treatment of corn cobs. Int. J. Eng. Technol. 7, 459–464 (2015). https://doi.org/10.7763/ijet.2015.v7.837CrossRef

Dai, J., Yang, H., Yan, H., Shangguan, Y., Zheng, Q., Cheng, R.: Phosphate adsorption from aqueous solutions by disused adsorbents: Chitosan hydrogel beads after the removal of copper (II). Chem. Eng. J. 166, 970–977 (2011). https://doi.org/10.1016/j.cej.2010.11.085CrossRef

Dubey, A., Mishra, A.: A novel plant-based biosorbent for removal of copper (II) from aqueous solutions: biosorption of copper (II) by dried plant biomass. J. Renew. Mater. 5, 54–61 (2016). https://doi.org/10.7569/jrm.2016.634127CrossRef

Freundlich, H.: Über die Adsorption in Lösungen. Zeitschrift für Phys Chemie 57(1), 385–480 (1907). https://doi.org/10.1515/zpch-1907-5723CrossRef

Guo, Z., Li, J., Guo, Z., Guo, Q., Zhu, B.: Phosphorus removal from aqueous solution in parent and aluminum-modified eggshells: thermodynamics and kinetics, adsorption mechanism, and diffusion process. Environ. Sci. Pollut. Res. 24, 14525–14536 (2017). https://doi.org/10.1007/s11356-017-9072-8CrossRef

Hoon, C.H.: The Removal Methods of Phosphorus/Phosphate and Nitrogen/Nitrate from Water and Wastewater. 83 (2012)

Huang, W., Chen, J., He, F., Tang, J., Li, D., Zhu, Y., Zhang, Y.: Effective phosphate adsorption by Zr/Al-pillared montmorillonite: Insight into equilibrium, kinetics and thermodynamics. Appl. Clay Sci. 104, 252–260 (2015). https://doi.org/10.1016/j.clay.2014.12.002CrossRef

Kasama, T., Watanabe, Y., Yamada, H., Murakami, T.: Sorption of phosphates on Al-pillared smectites and mica at acidic to neutral pH. Appl. Clay Sci. 25, 167–177 (2004). https://doi.org/10.1016/j.clay.2003.09.005CrossRef

Lagergren, S.: Zur theorie der sogenannten adsorption gelöster stoffe. K. Sv. Vet. Akad. Handl. 24, 1–39 (1898)

Li, R., Wang, J.J., Zhou, B., Awasthi, M.K., Ali, A., Zhang, Z., Gaston, L.A., Lahori, A.H., Mahar, A.: Enhancing phosphate adsorption by Mg/Al layered double hydroxide functionalized biochar with different Mg/Al ratios. Sci. Total Environ. 559, 121–129 (2016). https://doi.org/10.1016/j.scitotenv.2016.03.151CrossRefPubMed

Luo, X., Wang, X., Bao, S., Liu, X., Zhang, W., Fang, T.: Adsorption of phosphate in water using one-step synthesized zirconium-loaded reduced graphene oxide. Sci. Rep. 6, 1–13 (2016). https://doi.org/10.1038/srep39108CrossRef

Martín-Lara, M.A., Blázquez, G., Ronda, A., Pérez, A., Calero, M.: Development and characterization of biosorbents to remove heavy metals from aqueous solutions by chemical treatment of olive stone. Ind. Eng. Chem. Res. 52, 10809–10819 (2013). https://doi.org/10.1021/ie401246cCrossRef

Nguyen, T.A.H., Ngo, H.H., Guo, W.S., Zhou, J.L., Wang, J., Liang, H., Li, G.: Phosphorus elimination from aqueous solution using “zirconium loaded okara” as a biosorbent. Bioresour. Technol. 170, 30–37 (2014). https://doi.org/10.1016/j.biortech.2014.07.069CrossRefPubMed

Park, D., Yun, Y.S., Park, J.M.: The past, present, and future trends of biosorption. Biotechnol. Bioprocess Eng. 15, 86–102 (2010). https://doi.org/10.1007/s12257-009-0199-4CrossRef

Pastoriza-Santos, I., Liz-Marzán, L.M.: Formation and stabilization of silver nanoparticles through reduction by N, N -Dimethylformamide. Langmuir 15, 948–951 (1999). https://doi.org/10.1021/la980984uCrossRef

Przywara, L.: Warunki i możliwości usuwania fosforanów i fosforu ogólnego ze ścieków przemysłowych (2014)

Riazi, M., Keshtkar, A.R., Moosavian, M.A.: Biosorption of Th (IV) in a fixed-bed column by Ca-pretreated Cystoseira indica. J. Environ. Chem. Eng. 4, 1890–1898 (2016). https://doi.org/10.1016/j.jece.2016.03.017CrossRef

Tian, S., Jiang, P., Ning, P., Su, Y.: Enhanced adsorption removal of phosphate from water by mixed lanthanum/aluminum pillared montmorillonite. Chem. Eng. J. 151, 141–148 (2009). https://doi.org/10.1016/j.cej.2009.02.006CrossRef

Wang, Z., Shen, D., Shen, F., Li, T.: Phosphate adsorption on lanthanum loaded biochar. Chemosphere 150, 1–7 (2016). https://doi.org/10.1016/j.chemosphere.2016.02.004CrossRefPubMed

Wänke, H., Brückner, J., Dreibus, G., Rieder, R., Ryabchikov, I.: Chemical composition of rocks and soils at the pathfinder site. Space Sci. Rev. 96, 317–330 (2001). https://doi.org/10.1023/A:1011961725645CrossRef

Woumfo, E.D., Siéwé, J.M., Njopwouo, D.: A fixed-bed column for phosphate removal from aqueous solutions using an andosol-bagasse mixture. J. Environ. Manage. 151, 450–460 (2015). https://doi.org/10.1016/j.jenvman.2014.11.029CrossRefPubMed

Yan, L.G., Xu, Y.Y., Yu, H.Q., Xin, X.D., Wei, Q., Du, B.: Adsorption of phosphate from aqueous solution by hydroxy-aluminum, hydroxy-iron and hydroxy-iron-aluminum pillared bentonites. J. Hazard. Mater. 179, 244–250 (2010). https://doi.org/10.1016/j.jhazmat.2010.02.086CrossRefPubMed

Ye, Y., Ngo, H.H., Guo, W., Liu, Y., Li, J., Liu, Y., Zhang, X., Jia, H.: Insight into chemical phosphate recovery from municipal wastewater. Sci. Total Environ. 576, 159–171 (2017). https://doi.org/10.1016/j.scitotenv.2016.10.078CrossRefPubMed

Yuan, X., Xia, W., An, J., Yin, J., Zhou, X., Yang, W.: Kinetic and thermodynamic studies on the phosphate adsorption removal by dol mineral. J. Chem. 2015, 8 (2015). https://doi.org/10.1155/2015/853105CrossRef

Titel: Adsorption of Phosphates on Modified Eggshells - Batch and Fixed-Bed Column Process
verfasst von: Dawid Skrzypczak
Katarzyna Mikula
Daria Kocek
Grzegorz Izydorczyk
Rafał Taf
Anna Witek-Krowiak
Verlag: Springer International Publishing
Buch: Practical Aspects of Chemical Engineering
Print ISBN: 978-3-030-39866-8

Electronic ISBN: 978-3-030-39867-5

Copyright-Jahr: 2020
DOI: https://doi.org/10.1007/978-3-030-39867-5_43