Application of Multivariate Statistical Methods and Water-Quality Index to Evaluation of Water Quality in the Kashkan River

The Kashkan River (KR), located in the west of Iran, is a major source of water supply for residential and agricultural areas as well as livestock. The objective of this study was to assess the spatial and long temporal variations of surface water quality of the KR based on measured chemical ions. The Canadian Council of Ministers of Environment Water Quality Index (CCME WQI) technique was utilized using measurements from 10 sampling stations during a period of 36 years (1974–2009). The measured data included cations (Na⁺, K⁺, Ca²⁺, Mg²⁺), anions (HCO₃ ⁻, Cl⁻, SO₄ ²⁻), pH, and electrical conductivity. Principal component analysis was performed to identify which of the parameters to be included in the CCME WQI calculations were actually correlated and which ones were responsible for most of the variance observed in the water-quality data. In addition, KR water quality was evaluated for its suitability for drinking and irrigation purposes using conventional methods. Last, trend detection in the WQI time series of the KR showed water-quality degradation at all sampling stations, whereas the Jelhool sub-basin more adversely affects the quality of KR water in the watershed. Nonetheless, on average, the water quality of the KR was rated as fair.