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2014 | OriginalPaper | Buchkapitel

1. Bibliographical Backgrounds

verfasst von : Marie-Hélène Larraufie

Erschienen in: Development of New Radical Cascades and Multi-Component Reactions

Verlag: Springer International Publishing

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Abstract

The cyanamide moiety consists of a nitrogen atom bearing a nitrile group. When the nitrogen atom is substituted with a carbonyl group, one speaks of N-acylcyanamide. Thanks to its original structure, it possesses unique properties as a building block in organic synthesis, as a ligand in organometallic applications or as an essential function in bioactive compounds. The synthesis and chemical transformations of mono- and disubstituted cyanamides have been reviewed in depth by Nekrasov in 2004, so only the recent literature will be covered in this section.

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Nächstes Kapitel Results: Developments of New Radical Cascades with N-Acylcyanamides
Fußnoten
1
Only a catalytic amount of AIBN is needed for this homolytic aromatic substitution involving aryl iodides. This result suggests that the mechanism pictured in Fig. 1.39 could be at work in that case.
 
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Metadaten
Titel
Bibliographical Backgrounds
verfasst von
Marie-Hélène Larraufie
Copyright-Jahr
2014
Buch
Development of New Radical Cascades and Multi-Component Reactions

Print ISBN: 978-3-319-01323-7

Electronic ISBN: 978-3-319-01324-4

Copyright-Jahr: 2014

DOI
https://doi.org/10.1007/978-3-319-01324-4_1

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