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2019 | OriginalPaper | Buchkapitel

14. Borate Glasses

verfasst von : Steve Feller

Erschienen in: Springer Handbook of Glass

Verlag: Springer International Publishing

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Abstract

Borate glasses are both scientifically interesting and surprisingly practical. As additives to silicate-based glasses they can be exceedingly useful. This chapter focusses mainly on the mathematical relationships between structure and property. Atomic structure at both the short and intermediate-range levels was determined by various spectroscopies including nuclear magnetic resonance, neutron scattering, and vibrational spectroscopy. Properties examined include density, molar volume, packing fraction, the glass transition temperature, and stiffness. In many studies, these are model glasses that are relatively easy to make across wide-compositional limits at relatively low temperatures, but they do suffer from hygroscopicity, which leads to degradation of borate glasses in the atmosphere.

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14.38
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14.39
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14.40
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14.45
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14.46
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14.47
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14.48
Zurück zum Zitat S. Feller: Glass forming limits: A simple model based on short and intermediate range structural groups. In: Mater. Sci. Technol. Conf., Salt Lake City (2016) S. Feller: Glass forming limits: A simple model based on short and intermediate range structural groups. In: Mater. Sci. Technol. Conf., Salt Lake City (2016)
14.49
Zurück zum Zitat E.I. Kamitsos, M.A. Karakassides, A.P. Patsis: Spectroscopic: Study of carbonate retention in high-basicity borate glasses, J. Non-Cryst. Solids 111(2/3), 252–262 (1989)CrossRef E.I. Kamitsos, M.A. Karakassides, A.P. Patsis: Spectroscopic: Study of carbonate retention in high-basicity borate glasses, J. Non-Cryst. Solids 111(2/3), 252–262 (1989)CrossRef
14.50
Zurück zum Zitat T. Mullenbach, M. Franke, A. Ramm, A. Betzen, S. Kapoor, N. Lower, T. Munhollon, M. Berman, M. Affatigato, S.A. Feller: Structural determination of alkaline-earth borosilicate glasses through density modelling, Inelastic neutron scattering studies of superstructural units in borate glasses and crystalline phases, Phys. Chem. Glasses 50(2), 89–94 (2009) T. Mullenbach, M. Franke, A. Ramm, A. Betzen, S. Kapoor, N. Lower, T. Munhollon, M. Berman, M. Affatigato, S.A. Feller: Structural determination of alkaline-earth borosilicate glasses through density modelling, Inelastic neutron scattering studies of superstructural units in borate glasses and crystalline phases, Phys. Chem. Glasses 50(2), 89–94 (2009)
Metadaten
Titel
Borate Glasses
verfasst von
Steve Feller
Copyright-Jahr
2019
Verlag
Springer International Publishing
DOI
https://doi.org/10.1007/978-3-319-93728-1_14

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