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Erschienen in:
2002 | OriginalPaper | Buchkapitel
Catalysis by Polyampholytes
verfasst von : Sarkyt E. Kudaibergenov
Erschienen in: Polyampholytes
Verlag: Springer US
Enthalten in: Professional Book Archive
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The development of polymeric catalysts, which act likes enzymes is of great interest.1–6 Synthetic polyampholytes due to high content of functional groups and rich conformational liability are best candidate to design active and selective catalysts.7 Electrostatic interactions, hydrogen and coordination bonds, and hydrophobic entrapment can provide the selectivity of polyampholytes with respect to substrates. As compared with low molecular weight compounds, the reaction rate in the presence of polymeric catalysts is much higher, which is caused by a high local density of the functional groups in the bulk of the macromolecular coil.