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Journal of Nanoparticle Research

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01.07.2019 | Research Paper

Chromium substituted iron oxide nanowires as affordable electrocatalysts for oxygen evolution reaction

verfasst von: Serra Kocabas, Asude Cetin, Ahmet M. Önal, Emren Nalbant Esenturk

Erschienen in: Journal of Nanoparticle Research | Ausgabe 7/2019

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Abstract

Earth-abundant metal oxides have become center of attention in the application of electrochemical energy conversion and storage. In this work, CrFeO₃ was synthesized as a new catalyst for oxygen evolution reaction (OER). The structural and chemical properties of CrFeO₃ were characterized by TEM, SEM, EDX, XRD, XPS, and BET analyses. The microscopy images reveal that CrFeO₃ have wire-like morphology, which was formed by assembly of ca. 14 nm nanocrystallites. Then, potential utility of the synthesized nanowires (NWs) as catalysts in OER has been investigated. The CrFeO₃ NW-modified fluorinated tin oxide (FTO) electrodes exhibited promising OER performance with an onset potential of 1.63 V vs RHE, overpotential of 737 mV at 10 mA cm⁻² current density, and Tafel slope of 57 mV dec⁻¹. Additionally, CrFeO₃ NWs are demonstrated to be very stable electrocatalyst during OER. The CrFeO₃ NWs present an overall electrocatalytic performance that is comparable to the one of RuO₂, and promise a great potential as an effective and affordable OER catalyst.

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Titel: Chromium substituted iron oxide nanowires as affordable electrocatalysts for oxygen evolution reaction
verfasst von: Serra Kocabas
Asude Cetin
Ahmet M. Önal
Emren Nalbant Esenturk
Publikationsdatum: 01.07.2019
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 7/2019
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-019-4591-5

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