nach oben

Erschienen in:

2011 | OriginalPaper | Buchkapitel

24. Colloidal Systems and Equilibrium in Such Systems

verfasst von : Vyacheslav G. Rumynin

Erschienen in: Subsurface Solute Transport Models and Case Histories

Verlag: Springer Netherlands

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

In this chapter, primary factors controlling the stability of colloidal systems and adsorption-related interactions of colloidal particles with dissolves chemical species are considered. Governing equations for sorption equilibrium and kinetics are formulated. A number of case study researches elsewhere illustrating the presence of colloids in groundwater at different locations and their role in the trace element (in particular radionuclides) binding and capture within this environment are examined. All this creates a basis for the further development (Chaps. 26 and 27) of colloid-facilitated transport models.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Vorheriges Kapitel Tomsk-7 and Krasnoyarsk-26 Sites for Deep-Well Injection Radioactive Waste Disposal, and Lake Karachai Site of Near-Surface Disposal of Radioactive Brine

Nächstes Kapitel Experimental Study of Radionuclide Interaction with Colloids with Respect to Tomsk-7 Deep-Well RW Disposal in a Geological Formation

Ahfir N-D, Wang HQ, Benamar A (2007) Transport and deposition of suspended particles in saturated porous media: hydrodynamic effect. Hydrogeol Journ 15:659–668CrossRef

Allen E, Henshaw J, Smith P (2001) A Review of particle agglomeration. Report number AEAT/R/PSEG/0398. AEA Technology Engineering Services, Inc., Sterling

Berctsch PM, Seaman JC (1999) Characterization of complex mineral assemblages: implications for contaminant transport and environmental remediation. Proc Natl Acad Sci USA 96:3350–3357CrossRef

Buddemeier RW, Hunt JR (1988) Transport of colloidal contaminants in groundwater: radionuclide migration at the Nevada Test Site. Appl Geochem 3:535–548CrossRef

Buffle J, Leppard GG (1995) Characterization of aquatic colloids and macromolecules. 1. Structure and behavior of colloidal material. Environ Sci Technol 29:2169–2175CrossRef

Bunzl K, Flessa H, Kracke W et al (1995) Association of fallout 239 + 240 Pu and 241 Am with soil components in successive layers of a grassland soil. Environ Sci Technol 29:2513–2518CrossRef

Cantrell KJ, Riley RG (2008) Subsurface behavior of plutonium and americium at Non-Hanford Sites and relevance to Hanford. Pacific Northwest National Laboratory, PNNL-17386

Choppin GR (1999) Utility of oxidation state analogs in the study of plutonium behavior. Radiochim Acta 85:89–95

Clark DL, Janecky DR, Lane LJ (2006) Science-based cleanup of rocky flats. Phys Today 59:34–40CrossRef

Contardi JS, Turner DR, Ahn TM (2001) Modeling colloid transport for performance assessment. J Contam Hydrol 47:323–333CrossRef

Crancon P, Pili E, Charlet L et al (2001) Uranium mobility in soil and groundwater following surface contamination: existence of rapid transport mechanism with still limited bulk migration. In: Abstracts of the 8th international conference on chemistry and migration behaviour of actinides and fission products in the geosphere, MIGRATION’01, Bregennz, p 119

Dai M, Kelly JM, Buesseler KO (2002) Sources and migration of plutonium in groundwater at the Savannah river site. Environ Sci Technol 36:3690–3699CrossRef

Dai M, Buesseler KO, Pike SM (2005) Plutonium in groundwater at the 100 K – Area of the U.S. DOE Hanford Site. J Contam Hydrol 76:167–189CrossRef

Degueldre C, Baeyens B, Goerlich W (1989) Colloids in water from a subsurface fracture in granitic rock, Grimsel test site, Switzerland. Geochim Cosmochim Acta 53:603–610CrossRef

Degueldre C, Grauer R, Laube A (1996a) Colloid properties in granitic groundwater systems. II: stability and transport study. Appl Geochem 11:697–710CrossRef

Degueldre C, Pfeiffer HR, Alexander W (1996b) Colloid properties in granitic groundwater systems. I: sampling and characterization. Appl Geochem 11:677–695CrossRef

Delos A, Duro L, Guimera J (2002) Reactive transports modeling of radionuclides along a single fracture in Grimsel (CRR Project). In: TrePro 2002: modeling of coupled transport reaction processes, workshop of the Forschungszentum Karlsrune, 20–21 March 2002, pp 9–13

Elimelech M (1992) Predicting collision efficiencies of colloidal particles in porous media. Water Res 26:1–8CrossRef

Fujita T, Sugiyama D, Swanton SW et al (2003) Observation and characterization of colloids derived from leached cement hydrates. J Contam Hydrol 61:3–16CrossRef

Geckeis H, Grambow B, Quinones J et al (1998) Formation and stability of coloids under simulated near field conditions. Radiochim Acta 82:123–128

Groffman A, Mejer A (1993) Colloid transport special study. Uranium mill tailings remedial action project. United States department of Energy. Uranium Mill Tailings Remedial Action Project, UMTRA-DOE/AL-400682.0000

Grolimund D, Borkovec M (2001a) Release of system-borne colloidal particles natural porous media: phenomena and modeling. In: Abstracts of the 8th international conference on chemistry and migration behaviour of actinides and fission products in the geosphere, MIGRATION’01, Bregennz, p 120

Grolimund D, Borkovec M (2001b) Release and transport of colloidal particles in natural porous media: 1 Modeling. Water Resour Res 37:559–570CrossRef

Hakem NL, Allen PG, Sylwester ER (1999) Sorption and diffusion studies of Pu (III) and Pu (IV)–EDTA onto and through Hanford soil. Preprint UCRL-JC-135799

Harmand B, Sardin M (1994) Transient transport of colloids in weakly clayey sand. In: Dracos T, Stauffer F (eds) Transport and reactive processes in aquifers. Balkema, Rotterdam, pp 149–154

Ibaraki M, Sudicky EA (1995) Colloid-facilitated contaminant transport in discretely fractured porous media. Water Resour Res 31:2945–2960CrossRef

Ivanov IA (2004) Uranium and transuranium elements migration in groundwater at Lake Karachai site. Ph.D. thesis, Ozersk (In Russian)

Ivanov IA, Postovalova GA, Drozhko EG (2005) Uranium and transuranium elements migration in groundwater in the vicinity of the Lake Karachai, a surface reservoir for radioactive waste disposal. Probl Radiat Saf 1:23–34 (In Russian)

James SC, Chrysikopoulos CV (1999) Transport of polydisperse colloid suspensions in a single fracture. Water Resour Res 35:707–718CrossRef

Kersting AB, Efurd DW, Finnegan DL et al (1999) Migration of plutonium in ground water at the Nevada test site. Nature 397:56–59CrossRef

Kim JI (1986) Chemical behavior of transuranic elements in natural aquatic system. In: Freeman A, Keller C (eds) Handbook on the physics and chemistry of the actinides. Elsevier, New York, pp 413–454

Kim JI (1990) Actinide colloid generation in groundwater. Final report for the CEC project MIRAGE II. RCM 01190. Institut für Radiochemie der Technischen Universität München

Kim JI, Delakowitz B, Zeh P et al (1994) A column experiment for the study of colloidal radionuclide migration in Gorleben aquifer systems. Radiochim Acta 66(67):165–171

Kosakowsky G (2004) Anomalous transport of colloids and solutes in a shear zone. J Cotamin Hydrol 72:23–46CrossRef

Kretzschmar R, Barmettler K, Grolimund D et al (1997) Experimental determination of colloid deposition rates and collision efficiencies in natural porous media. Water Resour Res 33:1129–1137CrossRef

Kretzschmar R, Borkovec M, Grolimud D (1999) Mobile subsurface colloids and their role in contaminant transport. Adv Agron 66:121–194CrossRef

Krey PW (1976) Remote plutonium contamination from Rocky flats. Health Phys 30:209–214CrossRef

Ledin A, Karlsson S, Duker A et al (1994) Measurements in situ of concentration and size distribution of colloidal matter in deep groundwater by photon correlation spectroscopy. Water Resour Res 28:1539–1545CrossRef

Lehto J, Kelokaski P, Vaaramaa K et al (1999) Soluble and particle-bound 210Po and 210Pb in groundwaters. Radiochim Acta 85:149–155

Litaor MI (1995) Spatial analysis of plutonium-239, 240 and americium-241 in soil around Rocky Flats, CO. J Environ Qual 24:506–516CrossRef

Lu N, Triay IR, Cotter CR et al (1998a) Reversibility of sorption of plutonium-239 onto colloids of hematite, goethite, smectite and silica: a milestone final report of YMP. Technical Report LA-UR-98-3057. Los Alamos National Laboratory, Los Alamos

Lu N, Cotter CR, Kitten HD et al (1998b) Reversibility of sorption of plutonium-239 onto hematite and goethite colloids. Radiochim Acta 83:167–182

Lührmann L, Noseck U, Tix C (1998) Model on contaminant transport in porous media in the presence of colloids applied to actinide migration in column experiments. Water Resour Res 34:421–426CrossRef

McCarthy JF, Degueldre C (1993) Sampling and characterizing of colloids and particles in groundwater for studying their role in contaminant transport. In: Buffle J, Van Leeuwen HP (eds) Environmental particles. Lewis Publishers, Boca Raton/Ann Archor/London/Tokyo, pp 247–315

McCarthy JF, McKay LD (2004) Colloid transport in the subsurface: past, present and future challenges. Vadoze Zone J 3:326–337

McDowell-Boyer LM, Hunt JR, Sitar N (1986) Particle transport through porous media. Water Resour Res 22:1901–1921CrossRef

Meier H, Zimmerhackl E, Zietler G (2003) Modeling of collod-associated radionuclide transport in porous groundwater aquifer at the Gorleben site, Germany. Geochem J 37:325–350CrossRef

Missana T, Mingarro M, Garcia-Gutiérrez M (2001) CRR Project: sorption kinetics of Cs, U, Tc and Se onto granite and fault gouge materials and effects due to the presence of bentonite colloids. In: Abstracts of the 8th international conference on chemistry and migration behaviour of actinides and fission products in the geosphere, MIGRATION’01, Bregennz, p 145

Moridis GJ, Hu Q, WuY-S (2001) Preliminary 3-D site-scale studies of radioactive colloid transport in the unsaturated zone at Yucca Mountain, Nevada. LNBL Report LBNL-45876

Nagra Bulletin (2002) Vol. 34

Novikov AP, Pavlotskaya FI, Goryachenkova TA et al (1998) Radionuclide content in groundwater and rocks from observation wells around Lake Karachai. Radiochemestry 40(5):484–490

Novikov AP, Kalmykov SN, Utsunomiya S et al (2006) Colloid transport of Plutonium in the far-field of the Mayak production association, Russia. Science 314:638–641CrossRef

Painter S, Cvetkovic V, Pickett D et al (2002) Significance of kinetics for sorption on inorganic colloids: modeling and data interpretation issues. Environ Sci Technol 36:5369–5375CrossRef

Penrose WR, Polzer WL, Essington EH (1990) Mobility of plutonium and americium through a shallow aquifer in a semiarid region. Environ Sci Technol 24:228–234CrossRef

Reimus PW, Ware SD, Lu N et al (2001) Laboratory experiments to assess the potential for colloid-facilitated plutonium transport in fractured rock. Abstracts of the AGU 2001 Fall Meeting. H41Y-02 0855h

Runde W (2000) The chemical interactions of actinides in environment. Los Alamos Sci 26:392–411

Saiers JE, Hornberger GM (1996) The role of colloidal kaolinite in the transport of cesium through laboratory sand columns. Water Resour Res 32:33–41CrossRef

Saiers JE, Hornberger GM (1999) The influence of ionic strength on the facilitated transport of cesium by kaolonite colloids. Water Resour Res 35:1713–1727CrossRef

Schäfer T, Bauer A, Hofmann T et al (2000) Reaction front related colloid/particle transport downstream of contaminant plume. In: Rosbjerg et al (eds) Groundwater Research. Balkema, Rotterdam

Schäfer T, Artinger R, Bauer A et al (2001) Iron oxide-hydroxide colloid facilitated americium migration in Gorleben groundwater. In: Abstracts of the 8th international conference on chemistry and migration behaviour of actinides and fission products in the geosphere, MIGRATION’01, Bregennz, p 118

Schäfer T, Artinger R, Dardenne K et al (2002) Effect of colloidal iron hydroxide transformation on actinide mobility in Gorleben groundwater. In: TrePro 2002: modeling of coupled transport reaction processes. Workshop of the Forschungszentum Karlsrune, 20–21 March 2002, pp 84–88

Tanaka T, Mukai M, Maeda T et al (2003) Migration mechanisms of 237 Np and 241Am through loess media. J Radioanal Nucl Chem 256:205–211CrossRef

Torok J, Buckley LP, Woods BL (1990) The separation of radionuclide migration by solution and particle transport in soil. J Contam Hydrol 6:185–203CrossRef

UZ Colloid Transport Model (2000) Report ANL-NBS-HS-000028, 2000, p 51, Internet resources http://www.ymp.gov/documents/amr/u0070/u0070.pdf

Van de Weerd H (2000) Transport of reactive carriers and contaminants in groundwater systems (a dynamic competitive happening). Doctoral thesis, Wageningen University, Wageningen

Van de Weerd H, Leijnse A (1997) Assessment of the effect of kinetics on colloid facilitated radionuclide transport in porous media. J Contam Hydrol 26:245–256CrossRef

Van de Weerd H, Leijnse A, van Riemsdijk WH (1998) Transport of reactive colloids and contaminants in groundwater: effect of nonlinear kinetic interactions. J Contam Hydrol 32:313–331CrossRef

Vilks P, Baik M-H (2001) Laboratory migration experiments with radionuclides and natural colloids in a granite fracture. J Contam Hydrol 47:197–210CrossRef

Vilks P, Cramer JJ, Bachinski DB (1993) Studies of colloids and suspended particles, Cigar lake uranium deposit, Saskatchewan, Canada. Appl Geochem 8:605–616CrossRef

Vilks P, Caron F, Haas M (1998) Potential for the formation and migration of colloidal material from a near-surface waste disposal site. Appl Geochem 13:31–42CrossRef

Zänker H, Richter W, Brendler V et al (2000) Colloid-borne uranium and other heavy metals in the water of a mine drainage gallery. Radiochim Acta 88:619–624CrossRef

Zhao P, Steward SA (1997) Literature review of intrinsic actinide colloids related to spent fuel waste package release rates. Lawrence Livermore National Laboratory. UCRL-ID-126039

Titel: Colloidal Systems and Equilibrium in Such Systems
verfasst von: Vyacheslav G. Rumynin
Verlag: Springer Netherlands
Buch: Subsurface Solute Transport Models and Case Histories
Print ISBN: 978-94-007-1305-5

Electronic ISBN: 978-94-007-1306-2

Copyright-Jahr: 2011
DOI: https://doi.org/10.1007/978-94-007-1306-2_24