Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 1/2020

06.08.2020 | Original Paper: Nano- and macroporous materials (aerogels, xerogels, cryogels, etc.)

Cu/SnO2 xerogels: a novel epoxide derived nanomaterial as formaldehyde gas sensor

verfasst von: Nagesh L. Myadam, Digambar Y. Nadargi, Jyoti D. Nadargi, Manohar G. Chaskar

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Traditionally, sol–gel processing of metal oxides using organometallic precursors is expensive, nonaqueous, and complicated when it comes to two-or-more dissimilar metal oxides. Herein, we report a versatile epoxide-assisted non-organometallic, aqueous, and inexpensive synthesis route of developing Cu/SnO2 xerogels and their use as efficient formaldehyde (FA) gas sensors. The route utilizes easy to handle salts as precursors (tin and copper chlorides, in the present case) and organic epoxide (propylene oxide) as a gelation agent, which led to highly porous web matrix of Cu/SnO2. The obtained Cu/SnO2 xerogels, with 0–2  mol% Cu doping, were analyzed using XRD, Fourier transform infrared, UV–Vis, FE-SEM, TEM/HRTEM, and EDAX. As-developed xerogels showed their versatility in physico-chemical as well as FA gas sensing properties. By proper Cu-doping level in SnO2 matrix, the reduction in sensor operating temperature (325–275 °C) and enhancement in the gas response (S = 50–96%) are chronicled. The effects of gas sensing are represented by an epoxy-assisted Cu/SnO2 sol–gel process and the subsequent morphological and structural properties.
Vorheriger Artikel The investigation of hydrogenation behavior of furfural over sol–gel prepared Cu/ZrO2 catalysts
Nächster Artikel In situ synthesis and characterization of sulfonic acid functionalized hierarchical silica monoliths

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Zhang D, Sun L, Gang X, Yan C (2006) Size-controllable one-dimensinal SnO2 nanocrystals: synthesis, growth mechanism, and gas sensing property. Phys Chem Chem Phys 8:4874–4880
2.
Jimenez I, Arbiol J, Dezanneau G, Cornet A, Morante J (2003) Crystalline structure, defects and gas sensor response to NO2 and H2S of tungsten trioxide nanopowders. Sens Actuators B 93:475–485
3.
Baruwati B, Kumar D, Manorama S (2006) Hydrothermal synthesis of highly crystalline ZnO nanoparticles: a competitive sensor for LPG and EtOH. Sens Actuators B 119:676–682
4.
Koebel M, Nadargi D, Cadena G, Romanyuk Y (2012) Transparent, conducting ATO thin films by epoxide-initiated sol−gel chemistry: a highly versatile route to mixed-metal oxide films. ACS Appl Mater 4:2464–2473
5.
Benad A, Jürries F, Vetter B, Klemmed B, Hübner R, Leyens C, Eychmüller A (2018) Mechanical properties of metal oxide aerogels. Chem Mater 30(1):145–152
6.
Nadargi D, Kelly C, Wehrs J, Philippe L (2014) Epoxide assisted metal oxide replication (EAMOR): a new technique for metal oxide patterning. RSC Adv 4:36494–36497
7.
Gash A, Satcher Jr. J, Simpson R (2003) Strong akaganeite aerogel monoliths using epoxides: synthesis and characterization. Chem Mater 15:3268–3275
8.
Gash A, Tillotson T, Satcher Jr. J, Hrubesh L, Simpson R (2001) New sol–gel synthetic route to transition and main-group metal oxide aerogels using inorganic salt precursors. J Non-Cryst Solids 285:22–28
9.
Bunkoed O, Davis F, Kanatharana P, Thavarungkul P, Higson SPJ (2010) Sol-gel based sensor for selective formaldehyde determination. Anal Chim Acta 659:251–257
10.
Zhang Y, Zhang M, Cai ZQ, Chen MQ, Cheng FL (2012) A novel electrochemical sensor for formaldehyde based on palladium nanowire arrays electrode in alkaline media. Electrochim Acta 68:172–177
11.
Chen T, Liu QJ, Zhou ZL, Wang YD (2008) A high sensitivity gas sensor forformaldehyde based on CdO and In2O3doped nanocrystalline SnO2. Nanotechnology 19:095506
12.
Sun W, Sun GQ, Qin B, Xin Q (2007) A fuel-cell-type sensor for detection of formaldehyde in aqueous solution. Sens Actuator B 128:193–198
13.
Nielsen G, Wolkoff P (2010) Cancer effects of formaldehyde: a proposal for an indoor air guideline value. Arch Toxicol 84:423–446
14.
Lee C, Chiang CM, Wang YH, Ma RH (2007) A self-heating gas sensor with integrated NiO thin-film for formaldehyde detection. Sens Actuator B 122:503–510
15.
Wang X, Ding B, Sun M, Yu JY, Sun G (2010) Nanofibrous polyethylene imine membranes as sensitive coatings for quartz crystal microbalance-based formaldehyde sensors. Sens Actuator B 144:11–17
16.
Ritchie I, Lehnen R (1987) Formaldehyde-related health complaints ofresidents living in mobile and conventional homes. Am J Health 77:323–328
17.
Jiang X, Li C, Chi Y, Yan J (2010) TG-FTIR study on urea-formaldehyde resin residue during pyrolysis and combustion. J Hazard Mater 173:205–210
18.
Xu K, Zeng D, Tian S, Zhang S, Xie C (2014) Hierarchical porous SnO2 micro-rods topologically transferred from tin oxalate for fast response sensors to trace formaldehyde. Sens Actuators B 190:585–592
19.
Nageswari A, Krishna Reddy K, Mukkanti K (2012) Low-level quantitation of formaldehyde in drug substance by HPLC-UV. Chromatographia 75:275–280
20.
Li Y, Chen N, Deng D, Xing X, Xiao X, Wang Y (2017) Formaldehyde detection: SnO2 microspheres for formaldehyde gassensor with high sensitivity, fast response/recovery and good selectivity. Sens Actuators B 238:264–273
21.
Korpan Y, Soldatkin O, Sosovska O, Klepach H, Csoregi E, Vocanson F, Jaffrezic-Renault N, Gonchar M (2010) Formaldehyde-sensitive conductometric sensors based on commercial and recombinant formaldehyde dehydrogenase. Microchim Acta 170:337–344
22.
Li N, Fan Y, Shi Y, Xiang Q, Wang X, Xu J (2019) A low temperature formaldehyde gas sensor based on hierarchical SnO/SnO2 nano-flowers assembled from ultrathin nanosheets: synthesis, sensing performance and mechanism. Sens Actuators B 294:106–115
23.
Du H, Wang J, Su M, Yao P, Zheng Y, Yu N (2012) Formaldehyde gas sensor based on SnO2/In2O3hetero-nanofibers by a modified double jetselectrospinning process. Sens Actuator B 166:746–752
24.
Srinives S, Sarkar T, Mulchandani A (2014) Primary amine-functionalized polyaniline nano thin film sensor for detecting formaldehyde. Sens Actuator B B194:255–259
25.
Berry F, Maddock A (1977) A Tin-119 Mössbauer investigation of the thermal decomposition of Tin (IV) hydroxides. Radiochim Acta 24:32
26.
Giri P, Bhattacharyya S, Singh D, Kesavamoorthy R, Panigrahi B, Nair K (2007) Correlation between microstructure and optical properties of ZnO nanoparticles synthesized by ball milling. J Appl Phys 102:093515
27.
Karthik T, Olvera M, Maldonado A, Pozos H (2016) CO gas sensing properties of pure and Cu-incorporated SnO2 nanoparticles: a study of Cu-induced modifications. Sensors 16:1283
28.
Fang L, Zu X, Li Z, Zhu S, Liu C, Zhou W (2008) Synthesis and characteristics of Fe3+-doped SnO2 nanoparticles via sol–gel-calcination or sol–gel-hydrothermal route. J Alloy Compd 454:261–267
29.
Shannon RD (1976) Revised effective ionic radii and systematic studies of interatomie distances in halides and chaleogenides. Acta Cryst A32:751
30.
Niu X, Zhong H, Wang X, Jiang K (2006) Sensing properties of rare earth oxide doped In2O3 by a sol–gel method. Sens Actuator B 115:434–438
31.
Mohanapriya P, Segawa H, Watanabe K, Samitsu S, Natarajan TS, VictorJaya N, Ohashi N (2013) Enhanced ethanol-gas sensing performance of Ce-doped SnO2 hollow nanofibers prepared by electrospinning. Sens Actuators B 188:872–878
32.
Cheng J, Wang B, Zhao M, Liu F, Zhang X (2014) Nickel-doped tin oxidehollow nanofibers prepared by electrospinning for acetone sensing. Sens Actuators B 190:78–85
33.
Wang Z, Liu L (2009) Synthesis and ethanol sensing properties of Fe-doped SnO2 nanofibers. Mater Lett 63:917–919
34.
Myadam N, Nadargi D, Gurav Nadargi J, Shaikh F, Suryavanshi S, Chaskar M (2020) A facile approach of developing Al/SnO2 xerogels via epoxide assisted gelation: a highly versatile route for formaldehyde gas sensors. Inorg Chem Commun 116:107901–107909
35.
Xie C, Xiao L, Hu M (2010) Fabrication and formaldehyde gas-sensing property of ZnO–MnO2 coplanar gas sensor arrays. Sens Actuator B 145:457–463
36.
Nadargi D, Dateer R, Tamboli M, Mulla I, Suryavanshi S (2019) A greener approach towards the development of graphene–Ag loaded ZnO nanocomposites for acetone sensing applications. RSC Adv 9:33602–33606
37.
Wang K, Zhao TY, Lian G, Yu QQ, Luan CH, Wang QL, Cui DL (2013) Room temperature CO sensor fabricated from Pt-loaded SnO2 porous nanosolid. Sens Actuators B 184:33–39
38.
Zeng W, Liu T, Wang Z, Tsukimoto S, Saito M, Ikuhara Y (2009) Selective detection of formaldehyde gas using a Cd-doped TiO2-SnO2 sensor. Sensors 9(11):9029–9038
39.
Tian S, Ding X, Zeng D, Wu J, Zhang S, Xie C (2013) A low temperature gas sensor based on Pd-functionalized mesoporous SnO2 fibers for detecting trace formaldehyde. RSC Adv 3:11823
40.
Chung F, Wu R, Cheng F (2014) Fabrication of a Au@SnO2 core–shell structure for gaseous formaldehyde sensing at room temperature. Sens Actuators B 190:1–7
41.
Ren H, Zhao W, Wang L, Ryu SO, Gu C (2015) Preparation of porous flower-like SnO2 micro/nano structures and their enhanced gas sensing property. J Alloy Compd 653:611–618
42.
Xiang X, Zhu D, Wang D (2016) Enhanced formaldehyde gas sensing properties of La-doped SnO2 nanoparticles prepared by ball-milling solid chemical reaction method. J Mater Sci Mater Electron 27(7):7425–7432
43.
Yang J, Wang S, Dong R, Zhang L, Zhu Z, Gao X (2016) One-pot synthesis of SnO2 hollow microspheres and their formaldehyde sensor application. Mater Lett 184:9–12
44.
Chen S, Qiao Y, Huang J, Yao H, Zhang Y, Li Y et al. (2016) One-pot synthesis of mesoporous spherical SnO2@graphene for high-sensitivity formaldehyde gas sensors. RSC Adv 6:25198–25202
45.
Ma X, Shen J, Hu D et al. (2017) Preparation of three-dimensional Ce-doped Sn3O4 hierarchical microsphere and its application on formaldehyde gas sensor. J Alloy Compd 726:1092–1100
46.
Zhou T, Zhang T, Zhang R et al. (2017) Hollow ZnSnO3 cubes with controllable shells enabling highly efficient chemical sensing detection of formaldehyde vapors. ACS Appl Mater Interfaces 9(16):14525–14533
47.
Wei Q, Song P, Li Z, Yang Z, Wang Q (2017) Hierarchical peony-like Sb-doped SnO2 nanostructures: synthesis, characterization and HCHO sensing properties. Mater Lett 191:173–177
48.
Gu C, Guan W, Liu X, Gao L, Wang L, Shim J-J, Huang J (2017) Controlled synthesis of porous Ni-doped SnO2 microstructures and their enhanced gas sensing properties. J Alloy Compd 692:855–864
49.
Wang D, Zhang M, Chen Z, Li H, Chen A, Wang X et al. (2017) Enhanced formaldehyde sensing properties of hollow SnO2 nanofibers by graphene oxide. Sens Actuators B 250:533–542
50.
Gu C, Cui Y, Wang L, Sheng E, Shim J-J, Huang J (2017) Synthesis of the porous NiO/SnO2 microspheres and microcubes and their enhanced formaldehyde gas sensing performance. Sens Actuators B 241:298–307
51.
Yu H, Yu H, Li J, Tian Y, Li Z (2018) Environmentally friendly recycling of SnO2/Sn3O4 from tin anode slime for application in formaldehyde sensing material by Ag/Ag2O modification. J Alloy Compd 765:624–634
52.
Tie Y, Ma S, Yang G et al. (2019) Improved formaldehyde sensor of Zn2SnO4/SnO2 microcubes by compositional evolution and Y2O3 decoration. Ceram Int 45(5):5384–5391
53.
Zhu K, Ma S, Tie Y et al. (2019) Highly sensitive formaldehyde gas sensors based on Y-doped SnO2 hierarchical flower-shaped nanostructures. J Alloy Compd 792:938–944
54.
Wang L, Li Y, Yue W, Gao S, Zhang C, Chen Z (2019) High-performance formaldehyde gas sensor based on Cu-doped Sn3O4 hierarchical nanoflowers. IEEE (c) 20:1558–1748
Metadaten
Titel
Cu/SnO2 xerogels: a novel epoxide derived nanomaterial as formaldehyde gas sensor
verfasst von
Nagesh L. Myadam
Digambar Y. Nadargi
Jyoti D. Nadargi
Manohar G. Chaskar
Publikationsdatum
06.08.2020
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 1/2020
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-020-05377-x

Weitere Artikel der Ausgabe 1/2020

Journal of Sol-Gel Science and Technology 1/2020 Zur Ausgabe

Correction

Correction to: Transparent conductive organic-inorganic hybrid composites based on Ag nanowires

Original Paper: Sol-gel and hybrid materials for biological and health (medical) applications

In vitro bioactivity and osteoblast cell viability studies of hydroxyapatite-incorporated silica aerogel

Original Paper: Sol–gel and hybrid materials for catalytic, photoelectrochemical and sensor applications

Characteristics and photocatalytic activity of highly c-axis-oriented ZnO thin films

Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Cost-effective SnS heterojunction solar cells synthesized by spray pyrolysis

Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Study on SBA-15 as an effective sorbent for dye butyl rhodamine B

Original Paper: Sol–gel and hybrid materials for biological and health (medical) applications

A mesostructured hybrid CTA–silica carrier for curcumin delivery

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise