Skip to main content
Erschienen in: Journal of Materials Science 9/2014

01.05.2014

Density and viscosity of ternary Al–Cu–Si liquid alloys

verfasst von: Hidekazu Kobatake, Julianna Schmitz, Jürgen Brillo

Erschienen in: Journal of Materials Science | Ausgabe 9/2014

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Densities and viscosities of ternary Al–Cu–Si liquid alloys have been investigated over a wide temperature and composition range. Density was measured using electromagnetic levitation as a container-less technique, while viscosity was measured by means of a high-temperature oscillating cup viscometer. In this ternary system, binary interaction parameters as well as a third (ternary) interaction parameter need to be taken into account for the excess volume to describe the liquid densities. The temperature dependences of the viscosities are well described by the Arrhenius law. A maximum of the activation energy of viscous flow is found in that compositional range in which intermetallic phases exist in the solid state.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Caceres CH, Svensson IL, Taylor JA (2003) Strength–ductility behaviour of Al–Si–Cu–Mg casting alloys in T6 temper. Int J Cast Metals Res 15:531–543 Caceres CH, Svensson IL, Taylor JA (2003) Strength–ductility behaviour of Al–Si–Cu–Mg casting alloys in T6 temper. Int J Cast Metals Res 15:531–543
2.
Zurück zum Zitat Egry I, Giffard H, Schneider S (2005) The oscillating drop technique revisited. Meas Sci Technol 16:426–431CrossRef Egry I, Giffard H, Schneider S (2005) The oscillating drop technique revisited. Meas Sci Technol 16:426–431CrossRef
3.
Zurück zum Zitat Fukuyama H, Kobatake H, Takahashi K, Minato I, Tsukada T, Awaji S (2007) Development of modulated laser calorimetry using solid platinum sphere as a reference. Meas Sci Technol 18:2059–2066CrossRef Fukuyama H, Kobatake H, Takahashi K, Minato I, Tsukada T, Awaji S (2007) Development of modulated laser calorimetry using solid platinum sphere as a reference. Meas Sci Technol 18:2059–2066CrossRef
5.
Zurück zum Zitat Brillo J, Egry I, Westphal J (2008) Density and thermal expansion of liquid binary Al–Ag and Al–Cu alloys. Int J Mater Res 99:162–167CrossRef Brillo J, Egry I, Westphal J (2008) Density and thermal expansion of liquid binary Al–Ag and Al–Cu alloys. Int J Mater Res 99:162–167CrossRef
7.
Zurück zum Zitat Brillo J, Egry I (2011) Density of multicomponent melts measured by electromagnetic levitation. Jpn J Apple Phys 50:11RD02CrossRef Brillo J, Egry I (2011) Density of multicomponent melts measured by electromagnetic levitation. Jpn J Apple Phys 50:11RD02CrossRef
8.
Zurück zum Zitat Amore S, Horbach J, Egry I (2011) Is there a relation between excess volume and miscibility in binary liquid mixtures? J Chem Phys 134:1–044515CrossRef Amore S, Horbach J, Egry I (2011) Is there a relation between excess volume and miscibility in binary liquid mixtures? J Chem Phys 134:1–044515CrossRef
9.
Zurück zum Zitat Hirai M (1993) Estimation of viscosities of liquid alloys. Iron Steel Inst Jpn Int 33:251–258CrossRef Hirai M (1993) Estimation of viscosities of liquid alloys. Iron Steel Inst Jpn Int 33:251–258CrossRef
10.
Zurück zum Zitat Kaptay G (2003) Proceedings of microCAD 2003 International Conference, Section, Metallurgy, University of Miskolc, Hungary 23 Kaptay G (2003) Proceedings of microCAD 2003 International Conference, Section, Metallurgy, University of Miskolc, Hungary 23
11.
Zurück zum Zitat Glazov VM, Kol’tsov VB, Kurbatov VA (1986) Investigation of the temperature dependence of the electrical conductivity and thermoelectric power of silicon near its melting point in solid and liquid state. Sov Phys Semicond 20:1351–1353 Glazov VM, Kol’tsov VB, Kurbatov VA (1986) Investigation of the temperature dependence of the electrical conductivity and thermoelectric power of silicon near its melting point in solid and liquid state. Sov Phys Semicond 20:1351–1353
12.
Zurück zum Zitat Higuchi K, Kimura K, Mizuno A, Watanabe M, Katayama Y, Kuribayashi K (2007) Density and structure of undercooled molten silicon using synchrotron radiation combined with an electromagnetic levitation technique. J Non-cryst Sol 353:2997–2999CrossRef Higuchi K, Kimura K, Mizuno A, Watanabe M, Katayama Y, Kuribayashi K (2007) Density and structure of undercooled molten silicon using synchrotron radiation combined with an electromagnetic levitation technique. J Non-cryst Sol 353:2997–2999CrossRef
13.
Zurück zum Zitat Faber TE (1972) Introduction to the theory of liquid metals. Cambridge University Press, Cambridge Faber TE (1972) Introduction to the theory of liquid metals. Cambridge University Press, Cambridge
14.
Zurück zum Zitat Plevachuk Y, Sklyarchuk V, Yakymovych A, Eckert S, Willers B, Eigenfeld K (2008) Density, viscosity, and electrical conductivity of hypoeutectic Al–Cu liquid alloys. Met Mater Trans A 39:3040–3045CrossRef Plevachuk Y, Sklyarchuk V, Yakymovych A, Eckert S, Willers B, Eigenfeld K (2008) Density, viscosity, and electrical conductivity of hypoeutectic Al–Cu liquid alloys. Met Mater Trans A 39:3040–3045CrossRef
15.
Zurück zum Zitat Konstantinova NY, Popel PS (2008) Kinematic viscosity of liquid Al–Cu alloys. J Phys 98:062022 Konstantinova NY, Popel PS (2008) Kinematic viscosity of liquid Al–Cu alloys. J Phys 98:062022
17.
Zurück zum Zitat Friedrichs HA, Ronkow LW, Zhou Y (1997) Measurement of viscosity, density and surface tension of metal melts. Steel Res 68:209–214 Friedrichs HA, Ronkow LW, Zhou Y (1997) Measurement of viscosity, density and surface tension of metal melts. Steel Res 68:209–214
18.
Zurück zum Zitat Kehr M, Schick M, Hoyer W, Egry I (2008) Viscosity of the binary system Al–Ni. High Temp High Press 37:361–369 Kehr M, Schick M, Hoyer W, Egry I (2008) Viscosity of the binary system Al–Ni. High Temp High Press 37:361–369
19.
Zurück zum Zitat Kozlov LY, Romanov LM, Petrov NN (1983) Izv vysch uch Zav, Chernaya Meyall 3:7–11 Kozlov LY, Romanov LM, Petrov NN (1983) Izv vysch uch Zav, Chernaya Meyall 3:7–11
20.
Zurück zum Zitat Brillo J, Egry I (2004) Density and excess volume of liquid copper, nickel, iron, and their binary alloys. Z Metallkd 95:691–697CrossRef Brillo J, Egry I (2004) Density and excess volume of liquid copper, nickel, iron, and their binary alloys. Z Metallkd 95:691–697CrossRef
21.
Zurück zum Zitat Brillo J, Egry I (2003) Density determination of liquid copper, nickel, and their alloys. Int J Thermophys 24:1155–1170CrossRef Brillo J, Egry I (2003) Density determination of liquid copper, nickel, and their alloys. Int J Thermophys 24:1155–1170CrossRef
22.
Zurück zum Zitat Vegard L (1921) Die Konstitution der Mischkristalle und die Raumfüllung der Atome. Z Phys 5:17–26CrossRef Vegard L (1921) Die Konstitution der Mischkristalle und die Raumfüllung der Atome. Z Phys 5:17–26CrossRef
23.
Zurück zum Zitat Krishnan S, Hansen GP, Hauge RH, Margrave JL (1990) Spectral emissivities and optical-properties of electromagnetically levitated liquid-metals as function of temperature and wavelength. High Temp Sci 29:17–52 Krishnan S, Hansen GP, Hauge RH, Margrave JL (1990) Spectral emissivities and optical-properties of electromagnetically levitated liquid-metals as function of temperature and wavelength. High Temp Sci 29:17–52
24.
Zurück zum Zitat Krishnan S, Yugawa K, Nordine PC (1997) Optical properties of liquid nickel and iron. Phys Rev B 55:8201–8206CrossRef Krishnan S, Yugawa K, Nordine PC (1997) Optical properties of liquid nickel and iron. Phys Rev B 55:8201–8206CrossRef
25.
Zurück zum Zitat He CY, Du Y, Chen HL, Xu H (2009) Experimental investigation and thermodynamic modeling of the AlCuSi system. CALPHAD 33:200–210CrossRef He CY, Du Y, Chen HL, Xu H (2009) Experimental investigation and thermodynamic modeling of the AlCuSi system. CALPHAD 33:200–210CrossRef
26.
Zurück zum Zitat Brillo J, Egry I, Ho I (2006) Density and thermal expansion of liquid Ag–Cu and Ag–Au alloys. Int J Thermophys 27:494–506CrossRef Brillo J, Egry I, Ho I (2006) Density and thermal expansion of liquid Ag–Cu and Ag–Au alloys. Int J Thermophys 27:494–506CrossRef
27.
Zurück zum Zitat Kehr M, Hoyer W, Egry I, Hallstedt B (2007) A new high-temperature oscillating cup viscometer. Int J Thermophys 28:1017–1025CrossRef Kehr M, Hoyer W, Egry I, Hallstedt B (2007) A new high-temperature oscillating cup viscometer. Int J Thermophys 28:1017–1025CrossRef
28.
Zurück zum Zitat Ferris D, Quested PN (2002) NPL Report CMMT(A):306 Ferris D, Quested PN (2002) NPL Report CMMT(A):306
29.
Zurück zum Zitat Roscoe R (1958) Viscosity determination by the oscillating vessel method. I: theoretical considerations. Proc Phys Soc 72:576–584CrossRef Roscoe R (1958) Viscosity determination by the oscillating vessel method. I: theoretical considerations. Proc Phys Soc 72:576–584CrossRef
30.
Zurück zum Zitat Brillo J, Brooks R, Egry I, Quested PN (2008) Density and viscosity of liquid ternary Al–Cu–Ag alloys. High Temp High Press 37:371–381 Brillo J, Brooks R, Egry I, Quested PN (2008) Density and viscosity of liquid ternary Al–Cu–Ag alloys. High Temp High Press 37:371–381
31.
Zurück zum Zitat Brillo J, Egry I, Matsushita T (2006) Density and excess volumes of liquid copper, cobalt, iron and their binary and ternary alloys. Int Mater Res 97:1526–1532CrossRef Brillo J, Egry I, Matsushita T (2006) Density and excess volumes of liquid copper, cobalt, iron and their binary and ternary alloys. Int Mater Res 97:1526–1532CrossRef
33.
Zurück zum Zitat Brillo J, Egry I, Matsushita T (2006) Density and surface tension of liquid ternary Ni–Cu–Fe alloys. Int J Thermophys 27:1778–1791CrossRef Brillo J, Egry I, Matsushita T (2006) Density and surface tension of liquid ternary Ni–Cu–Fe alloys. Int J Thermophys 27:1778–1791CrossRef
34.
Zurück zum Zitat Schick M, Brillo J, Egry I (2009) Thermophysical properties of liquid Co–Cu–Ni alloys. Int J Cast Met Res 22:82–85CrossRef Schick M, Brillo J, Egry I (2009) Thermophysical properties of liquid Co–Cu–Ni alloys. Int J Cast Met Res 22:82–85CrossRef
35.
Zurück zum Zitat Brillo J, Brooks R, Egry I, Quested PN (2007) Viscosity measurement of liquid ternary Cu–Ni–Fe alloys by an oscillating cup viscometer and comparison with models. Int Mater Res 98:457–462CrossRef Brillo J, Brooks R, Egry I, Quested PN (2007) Viscosity measurement of liquid ternary Cu–Ni–Fe alloys by an oscillating cup viscometer and comparison with models. Int Mater Res 98:457–462CrossRef
36.
Zurück zum Zitat Iida T, Guthrie R (1993) The physical properties of liquid metals. Clarendon Press, Oxford Iida T, Guthrie R (1993) The physical properties of liquid metals. Clarendon Press, Oxford
37.
Zurück zum Zitat Sato Y, Kameda Y, Nagasawa T, Sakamoto T, Moriguchi S, Yamamura T, Waseda Y (2003) Viscosity of molten silicon and the factors affecting measurement. J Cryst Growth 249:404–415CrossRef Sato Y, Kameda Y, Nagasawa T, Sakamoto T, Moriguchi S, Yamamura T, Waseda Y (2003) Viscosity of molten silicon and the factors affecting measurement. J Cryst Growth 249:404–415CrossRef
38.
Zurück zum Zitat Walsdorfer H, Arpshofen I, Predel B (1988) Viscosity and electrical-resistance of liquid In–Sn and In–Bi alloys. Z Metallkd 79:503–512 Walsdorfer H, Arpshofen I, Predel B (1988) Viscosity and electrical-resistance of liquid In–Sn and In–Bi alloys. Z Metallkd 79:503–512
Metadaten
Titel
Density and viscosity of ternary Al–Cu–Si liquid alloys
verfasst von
Hidekazu Kobatake
Julianna Schmitz
Jürgen Brillo
Publikationsdatum
01.05.2014
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 9/2014
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-014-8072-z

Weitere Artikel der Ausgabe 9/2014

Journal of Materials Science 9/2014 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.