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Journal of Materials Science
Erschienen in: Journal of Materials Science 2/2019

12.09.2018 | Chemical routes to materials

Difluoroborate-based conjugated organic polymer: a high-performance heterogeneous photocatalyst for oxidative coupling reactions

verfasst von: Wanting Liu, Shujie Wu, Qing Su, Bixuan Guo, Pengyao Ju, Guanghua Li, Qiaolin Wu

Erschienen in: Journal of Materials Science | Ausgabe 2/2019

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Abstract

A photoactive difluoroborate-based conjugated organic polymer (B-COP) with A3B2-type donor–acceptor arrays in the polymer framework was synthesized by direct polycondensation and exhibited amorphous structure, high thermal and photophysical stability. The B-COP was shown to be a highly efficient heterogeneous photocatalyst for a wide range of photocatalytic transformations, including the oxidative coupling of primary amine and cross-dehydrogenative coupling reactions between tetrahydroisoquinolines and nucleophiles such as nitromethane, nitroethane, acetone and phenylethyl ketone.
Vorheriger Artikel Preparation of recycled graphite/expanded polystyrene by a facile solvent dissolution method
Nächster Artikel Size and shape effect on the photocatalytic efficiency of TiO2 brookite

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Metadaten
Titel
Difluoroborate-based conjugated organic polymer: a high-performance heterogeneous photocatalyst for oxidative coupling reactions
verfasst von
Wanting Liu
Shujie Wu
Qing Su
Bixuan Guo
Pengyao Ju
Guanghua Li
Qiaolin Wu
Publikationsdatum
12.09.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 2/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2893-0

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