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Erschienen in:
1989 | OriginalPaper | Buchkapitel
Diolefin Iron Complexes — Useful and Versatile Tools in Organic Synthesis
verfasst von : A. Salzer
Erschienen in: Organometallics in Organic Synthesis 2
Verlag: Springer Berlin Heidelberg
Enthalten in: Professional Book Archive
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This review aims to present our current work, which focuses on the preparation and use of Wittig reagents via allyl-Fe(CO)4 and dienyl-Fe(CO)3 complexes. We have applied these reagents, among others, to the highly stereoselective synthesis of naturally occurring triolefins. In a related topic, the reactivity of functionalized tricarbonyl(diene)iron complexes will be discussed with regard to their use in selective C-C coupling reactions.