nach oben

Journal of Materials Science

Erschienen in:

19.07.2019 | Electronic materials

Effect of neutralization of poly(acrylic acid) binder on the dispersion heterogeneity of Li-ion battery electrodes

verfasst von: Sang Hoon Sung, Do Hoon Kim, Sunhyung Kim, Min Hwan Jeong, Jaewook Nam, Kyung Hyun Ahn

Erschienen in: Journal of Materials Science | Ausgabe 20/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

A systematic study using a model negative electrode slurry with poly(acrylic acid) as a binder is conducted aiming at the control of both dispersion quality and rheology in the electrode manufacturing process. Rheological properties of the model slurries vary considerably with the neutralization degree α. Optical microscope and Turbiscan measurements show that the rheological change is accompanied by the change in particle aggregation tendency. Adsorption and zeta potential measurements reveal that α-dependent adsorption of poly(acrylic acid) is the key factor that controls the rheology of the slurries. The difference in α of the slurry results in a significant difference in the surface roughness and the carbon black particle distribution in the electrode. From this study, it is concluded that the adjustment of neutralization degree of poly(acrylic acid)-based binder critically affects the heterogeneity of the electrode, which can influence the performance as well as the rheological stability in the electrode manufacturing process.

Vorheriger Artikel Effect of the Fe3+ concentration on the upconversion luminescence in NaGdF4:Yb3+, Er3+ nanorods prepared by a hydrothermal method

Nächster Artikel Effect of proton irradiation on anatase TiO2 nanotube anodes for lithium-ion batteries

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Çetinel FA, Bauer W (2014) Processing of water-based LiNi_1/3Mn_1/3Co_1/3O₂ pastes for manufacturing lithium ion battery cathodes. Bull Mater Sci 37:1685–1690. https://doi.org/10.1007/s12034-014-0733-7 CrossRef

El Baradai O, Beneventi D, Alloin F et al (2016) Microfibrillated cellulose based ink for eco-sustainable screen printed flexible electrodes in lithium ion batteries. J Mater Sci Technol 32:566–572. https://doi.org/10.1016/j.jmst.2016.02.010 CrossRef

Lim S, Kim S, Ahn KH, Lee SJ (2015) The effect of binders on the rheological properties and the microstructure formation of lithium-ion battery anode slurries. J Power Sources 299:221–230. https://doi.org/10.1016/j.jpowsour.2015.09.009 CrossRef

Lim S, Kim S, Ahn KH, Lee SJ (2015) Stress development of Li-ion battery anode slurries during the drying process. Ind Eng Chem Res 54:6146–6155. https://doi.org/10.1021/acs.iecr.5b00878 CrossRef

Yim T, Choi SJ, Jo YN et al (2014) Effect of binder properties on electrochemical performance for silicon–graphite anode: method and application of binder screening. Electrochim Acta 136:112–120. https://doi.org/10.1016/j.electacta.2014.05.062 CrossRef

Lee J, Sung S, Kim Y et al (2017) A new paradigm of materials processing—heterogeneity control. Curr Opin Chem Eng 16:16–22. https://doi.org/10.1016/j.coche.2017.04.002 CrossRef

Li CC, Lin YS (2012) Interactions between organic additives and active powders in water-based lithium iron phosphate electrode slurries. J Power Sources 220:413–421. https://doi.org/10.1016/j.jpowsour.2012.07.125 CrossRef

Zhang Z, Zeng T, Lai Y et al (2014) A comparative study of different binders and their effects on electrochemical properties of LiMn₂O₄ cathode in lithium ion batteries. J Power Sources 247:1–8. https://doi.org/10.1016/j.jpowsour.2013.08.051 CrossRef

Li C-C, Lee J-T, Peng X-W (2006) Improvements of dispersion homogeneity and cell performance of aqueous-processed LiCoO₂ cathodes by using dispersant of PAA–NH₄. J Electrochem Soc 153:A809–A815. https://doi.org/10.1149/1.2177071 CrossRef

10.

Porcher W, Lestriez B, Jouanneau S, Guyomard D (2010) Optimizing the surfactant for the aqueous processing of LiFePO₄ composite electrodes. J Power Sources 195:2835–2843. https://doi.org/10.1016/j.jpowsour.2009.11.088 CrossRef

11.

Lee J-H, Kim J-S, Kim YC et al (2008) Dispersion properties of aqueous-based LiFePO₄ pastes and their electrochemical performance for lithium batteries. Ultramicroscopy 108:1256–1259. https://doi.org/10.1016/j.ultramic.2008.04.027 CrossRef

12.

Cai ZP, Liang Y, Li WS et al (2009) Preparation and performances of LiFePO₄ cathode in aqueous solvent with polyacrylic acid as a binder. J Power Sources 189:547–551. https://doi.org/10.1016/j.jpowsour.2008.10.040 CrossRef

13.

Li J, Le D-B, Ferguson PP, Dahn JR (2010) Lithium polyacrylate as a binder for tin–cobalt–carbon negative electrodes in lithium-ion batteries. Electrochim Acta 55:2991–2995. https://doi.org/10.1016/j.electacta.2010.01.011 CrossRef

14.

Zhang Z, Bao W, Lu H et al (2012) Water-soluble polyacrylic acid as a binder for sulfur cathode in lithium–sulfur battery. ECS Electrochem Lett 1:A34–A37. https://doi.org/10.1149/2.009202eel CrossRef

15.

Magasinski A, Zdyrko B, Kovalenko I et al (2010) Toward efficient binders for Li-ion battery Si-based anodes: polyacrylic acid. ACS Appl Mater Interfaces 2:3004–3010. https://doi.org/10.1021/am100871y CrossRef

16.

Komaba S, Ozeki T, Yabuuchi N, Shimomura K (2011) Polyacrylate as functional binder for silicon and graphite composite electrode in lithium-ion batteries. Electrochemistry 79:6–9. https://doi.org/10.5796/electrochemistry.79.6 CrossRef

17.

Erk C, Brezesinski T, Sommer H et al (2013) Toward silicon anodes for next-generation lithium ion batteries: a comparative performance study of various polymer binders and silicon nanopowders. ACS Appl Mater Interfaces 5:7299–7307. https://doi.org/10.1021/am401642c CrossRef

18.

Mazouzi D, Karkar Z, Reale Hernandez C et al (2015) Critical roles of binders and formulation at multiscales of silicon-based composite electrodes. J Power Sources 280:533–549. https://doi.org/10.1016/j.jpowsour.2015.01.140 CrossRef

19.

Wei L, Chen C, Hou Z, Wei H (2016) Poly(acrylic acid sodium) grafted carboxymethyl cellulose as a high performance polymer binder for silicon anode in lithium ion batteries. Sci Rep 6:19583. https://doi.org/10.1038/srep19583 CrossRef

20.

Koo B, Kim H, Cho Y et al (2012) A highly cross-linked polymeric binder for high-performance silicon negative electrodes in lithium ion batteries. Angew Chem Int Ed 51:8762–8767. https://doi.org/10.1002/anie.201201568 CrossRef

21.

Han Z-J, Yabuuchi N, Hashimoto S et al (2013) Cross-linked poly(acrylic acid) with polycarbodiimide as advanced binder for Si/graphite composite negative electrodes in Li-ion batteries. ECS Electrochem Lett 2:A17–A20. https://doi.org/10.1149/2.005302eel CrossRef

22.

Aoki S, Han Z-J, Yamagiwa K et al (2015) Acrylic acid-based copolymers as functional binder for silicon/graphite composite electrode in lithium-ion batteries. J Electrochem Soc 162:A2245–A2249. https://doi.org/10.1149/2.0171512jes CrossRef

23.

Hu B, Shkrob IA, Zhang S et al (2018) The existence of optimal molecular weight for poly(acrylic acid) binders in silicon/graphite composite anode for lithium-ion batteries. J Power Sources 378:671–676. https://doi.org/10.1016/j.jpowsour.2017.12.068 CrossRef

24.

Li C-C, Lee J-T, Lo C-Y, Wu M-S (2005) Effects of PAA–NH₄ addition on the dispersion property of aqueous LiCoO₂ slurries and the cell performance of As-prepared LiCoO₂ cathodes. Electrochem Solid-State Lett 8:A509–A512. https://doi.org/10.1149/1.2012287 CrossRef

25.

Han Z-J, Yabuuchi N, Shimomura K et al (2012) High-capacity Si–graphite composite electrodes with a self-formed porous structure by a partially neutralized polyacrylate for Li-ion batteries. Energy Environ Sci 5:9014–9020. https://doi.org/10.1039/C2EE22292B CrossRef

26.

Han Z-J, Yamagiwa K, Yabuuchi N et al (2015) Electrochemical lithiation performance and characterization of silicon–graphite composites with lithium, sodium, potassium, and ammonium polyacrylate binders. Phys Chem Chem Phys 17:3783–3795. https://doi.org/10.1039/C4CP04939J CrossRef

27.

Grunlan JC, Liu L, Kim YS (2006) Tunable single-walled carbon nanotube microstructure in the liquid and solid states using poly(acrylic acid). Nano Lett 6:911–915. https://doi.org/10.1021/nl052486t CrossRef

28.

Saint-Aubin K, Poulin P, Saadaoui H et al (2009) Dispersion and film-forming properties of poly(acrylic acid)-stabilized carbon nanotubes. Langmuir 25:13206–13211. https://doi.org/10.1021/la9018822 CrossRef

29.

Hu B, Jiang S, Shkrob IA et al (2019) Understanding of pre-lithiation of poly(acrylic acid) binder: striking the balances between the cycling performance and slurry stability for silicon–graphite composite electrodes in Li-ion batteries. J Power Sources 416:125–131. https://doi.org/10.1016/j.jpowsour.2019.01.068 CrossRef

30.

Kay PJ, Treloar FE (1974) The intrinsic viscosity of poly(acrylic acid) at different ionic strengths: random coil and rigid rod behaviour. Die Makromolekulare Chemie 175:3207–3223. https://doi.org/10.1002/macp.1974.021751114 CrossRef

31.

Staikos G, Bokias G (1993) The intrinsic viscosity of poly(acrylic acid) and partially neutralized poly(acrylic acid) by isoionic dilution. Polym Int 31:385–389. https://doi.org/10.1002/pi.4990310412 CrossRef

32.

Adamczyk Z, Bratek A, Jachimska B et al (2006) Structure of poly(acrylic acid) in electrolyte solutions determined from simulations and viscosity measurements. J Phys Chem B 110:22426–22435. https://doi.org/10.1021/jp063981w CrossRef

33.

Alves BR, Cooper WD (1981) Colloid stabilisation by polyelectrolytes. Dispersions of carbon black in aqueous poly(acrylic acid) solution. J Chem Soc, Faraday Trans 1(77):889–896. https://doi.org/10.1039/F19817700889 CrossRef

34.

Wiśniewska M, Nosal-Wiercińska A, Ostolska I et al (2017) Nanostructure of poly(acrylic acid) adsorption layer on the surface of activated carbon obtained from residue after supercritical extraction of hops. Nanoscale Res Lett 12:2. https://doi.org/10.1186/s11671-016-1772-3 CrossRef

35.

Grunlan JC, Liu L, Regev O (2008) Weak polyelectrolyte control of carbon nanotube dispersion in water. J Colloid Interface Sci 317:346–349. https://doi.org/10.1016/j.jcis.2007.08.057 CrossRef

36.

Biggs S, Healy TW (1994) Electrosteric stabilisation of colloidal zirconia with low-molecular-weight polyacrylic acid. An atomic force microscopy study. J Chem Soc Faraday Trans 90:3415–3421. https://doi.org/10.1039/FT9949003415 CrossRef

37.

Szilagyi I, Trefalt G, Tiraferri A et al (2014) Polyelectrolyte adsorption, interparticle forces, and colloidal aggregation. Soft Matter 10:2479–2502. https://doi.org/10.1039/C3SM52132J CrossRef

38.

Tsukida N, Muranaka H, Ide M et al (1997) Effect of neutralization of poly(acrylic acid) on the structure of water examined by Raman spectroscopy. J Phys Chem B 101:6676–6679. https://doi.org/10.1021/jp971210+ CrossRef

39.

Donnet J-B (1993) Carbon black: science and technology, 2nd edn. CRC Press, New York

40.

Bhosale PS, Berg JC (2012) The dynamics of polymer bridge formation and disruption and its effect on the bulk rheology of suspensions. Langmuir 28:16807–16811CrossRef

41.

Sung SH, Kim S, Hendricks J et al (2018) Orthogonal superposition rheometry of colloidal gels: time-shear rate superposition. Soft Matter. https://doi.org/10.1039/C8SM01512K

42.

Kim S, Sung J, Ahn K, Lee S (2009) Drying of the silica/PVA suspension: effect of suspension microstructure. Langmuir 25:6155–6161. https://doi.org/10.1021/la804112b CrossRef

43.

Kim S, Sung JH, Hur K et al (2010) The effect of adsorption kinetics on film formation of silica/PVA suspension. J Colloid Interface Sci 344:308–314. https://doi.org/10.1016/j.jcis.2009.12.046 CrossRef

44.

Mohanty D, Hockaday E, Li J et al (2016) Effect of electrode manufacturing defects on electrochemical performance of lithium-ion batteries: cognizance of the battery failure sources. J Power Sources 312:70–79. https://doi.org/10.1016/j.jpowsour.2016.02.007 CrossRef

45.

Ludwig B, Zheng Z, Shou W et al (2016) Solvent-free manufacturing of electrodes for lithium-ion batteries. Sci Rep 6:23150. https://doi.org/10.1038/srep23150 CrossRef

46.

Bauer W, Nötzel D, Wenzel V, Nirschl H (2015) Influence of dry mixing and distribution of conductive additives in cathodes for lithium ion batteries. J Power Sources 288:359–367. https://doi.org/10.1016/j.jpowsour.2015.04.081 CrossRef

47.

Morelly SL, Alvarez NJ, Tang MH (2018) Short-range contacts govern the performance of industry-relevant battery cathodes. J Power Sources 387:49–56. https://doi.org/10.1016/j.jpowsour.2018.03.039 CrossRef

Titel: Effect of neutralization of poly(acrylic acid) binder on the dispersion heterogeneity of Li-ion battery electrodes
verfasst von: Sang Hoon Sung
Do Hoon Kim
Sunhyung Kim
Min Hwan Jeong
Jaewook Nam
Kyung Hyun Ahn
Publikationsdatum: 19.07.2019
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 20/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-019-03846-5

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 20/2019

Effect of the Fe3+ concentration on the upconversion luminescence in NaGdF4:Yb3+, Er3+ nanorods prepared by a hydrothermal method

Biomineralization synthesis of HBc-CuS nanoparticles for near-infrared light-guided photothermal therapy

Effect of proton irradiation on anatase TiO2 nanotube anodes for lithium-ion batteries

4,4′-Fluoresceinoxy bisphthalonitrile (FPN)-incorporated polycaprolactone electrospun membranes: a portable sensor strip for detection of Fe3+ ions

Application of hydrogen for rare-earth gadolinium purification and thermodynamic simulation of system

Flame retardant nanocomposites based on 2D layered nanomaterials: a review

Premium Partner

Marktübersichten