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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 2/2016

01.02.2016 | Original Paper

Efficient preparation of high concentration cellulose solution with complex DMSO/ILs solvent

verfasst von: Xinda Li, Yue Zhang, Jingwen Tang, Ai Lan, Yanping Yang, Magdi Gibril, Muhuo Yu

Erschienen in: Journal of Polymer Research | Ausgabe 2/2016

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Abstract

The development of a low-cost and efficient solvent for cellulose has been a longstanding challenge in the field of cellulose chemistry. In this paper, we further studied a highly effective cellulose solvent composed of a large amount of dimethyl sulfoxide (DMSO) and a small amount of 1-ethyl-3-methylimidazolium acetate ([C2mim][CH3COO]). The fact that DMSO/[C2mim][CH3COO] can dissolve cellulose more efficiently than pure [C2mim][CH3COO] was fully confirmed with a combination of polarized light microscope and turbidimetric measurements. 1H-NMR spectrographs and conductivity results indicated that an increased concentration of free [CH3COO]− was the main reason for this enhanced dissolution ability. Rheology results revealed that cellulose-DMSO/ionic liquids (ILs) solution had lower zero shear viscosity, structural viscosity index, and viscous flow activation energy, which would contribute to its outstanding spinning property compared to other cellulose solutions. These advantages combined with the low cost of this proposed complex cellulose solvent make it promising to promote its industrial applications.
Vorheriger Artikel Regularly grafted polymer brush with degradable PCL backbone by ring-opening polymerization and “click” reaction: synthesis and self-assembly
Nächster Artikel Phase separation behavior and fluorescence properties of poly(N-isopropylacrylamide) with chalcone side groups in mixed solvents

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Metadaten
Titel
Efficient preparation of high concentration cellulose solution with complex DMSO/ILs solvent
verfasst von
Xinda Li
Yue Zhang
Jingwen Tang
Ai Lan
Yanping Yang
Magdi Gibril
Muhuo Yu
Publikationsdatum
01.02.2016
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 2/2016
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-016-0922-8

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