nach oben

Erschienen in:

25.10.2018 | Electronic materials

Electroconductive performance of polypyrrole/reduced graphene oxide/carbon nanotube composites synthesized via in situ oxidative polymerization

verfasst von: Xuan Tin Tran, Sung Soo Park, Sinae Song, Muhammad Salman Haider, Syed Muhammad Imran, Manwar Hussain, Hee Taik Kim

Erschienen in: Journal of Materials Science | Ausgabe 4/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

We report a novel approach to the fabrication of polypyrrole/reduced graphene oxide/carbon nanotube (PPy/rGO/CNT) composites. Firstly, the growth of carbon nanotube (CNT) and the partial reduction of graphene oxide occurred simultaneously within 10 s under ambient conditions using a microwave-assisted approach. Polypyrrole (PPy) was then integrated with reduced graphene oxide/carbon nanotube (rGO/CNT) hybrid materials through in situ oxidative polymerization of pyrrole in the presence of dodecylbenzenesulfonic acid, which acts as a stabilizing and doping agent. The morphological, structural, electrical, and thermal properties of PPy/rGO/CNT composites are discussed in detail, and a possible formation mechanism is proposed. The results indicate that introducing rGO/CNT into the PPy polymer can improve both the thermal and electrical properties of the polymer. Enhanced conductivity of 1214.16 S/m was observed in the sample with 5 wt% rGO/CNT loading with a pressing pressure of 10 MPa compared to that in individual PPy and PPy/GO samples pressed at the same pressing pressure. This study provides a simple approach to the preparation of PPy/rGO/CNT composites with tunable electrical properties for a variety of potential electronic applications.

Vorheriger Artikel Highly selective metal–organic framework-based sensor for protamine through photoinduced electron transfer

Nächster Artikel A facile room-temperature synthesis of three-dimensional coral-like Ag2S nanostructure with enhanced photocatalytic activity

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Hazarika A, Deka BK, Kim DY et al (2016) Microwave-induced hierarchical iron-carbon nanotubes nanostructures anchored on polypyrrole/graphene oxide-grafted woven Kevlar^® fiber. Compos Sci Technol 129:137–145. https://doi.org/10.1016/j.compscitech.2016.04.022 CrossRef

Liu Z, Zhang L, Poyraz S et al (2014) An ultrafast microwave approach towards multi-component and multi-dimensional nanomaterials. RSC Advances 4:9308–9313. https://doi.org/10.1039/c3ra47086e CrossRef

Wang B, Qiu J, Feng H, Sakai E (2015) Preparation of graphene oxide/polypyrrole/multi-walled carbon nanotube composite and its application in supercapacitors. Electrochim Acta 151:230–239. https://doi.org/10.1016/j.electacta.2014.10.153 CrossRef

Zhang LM, Sui XL, Zhao L et al (2017) Three-dimensional hybrid aerogels built from graphene and polypyrrole-derived nitrogen-doped carbon nanotubes as a high-efficiency Pt-based catalyst support. Carbon 121:518–526. https://doi.org/10.1016/j.carbon.2017.06.023 CrossRef

Zhang Ren, Wang Liu (2010) Graphene oxide-assisted dispersion of pristine multiwalled carbon nanotubes in aqueous media. J Phys Chem C 35:11435–11440. https://doi.org/10.1021/jp103745g CrossRef

Jyothirmayee Aravind SS, Eswaraiah V, Ramaprabhu S (2011) Facile synthesis of one-dimensional graphene wrapped carbon nanotube composites by chemical vapour deposition. J Mater Chem 21:15179–15182. https://doi.org/10.1039/c1jm12731d CrossRef

Dong X, Li B, Wei A et al (2011) One-step growth of graphene-carbon nanotube hybrid materials by chemical vapor deposition. Carbon 49:2944–2949. https://doi.org/10.1016/j.carbon.2011.03.009 CrossRef

Bajpai R, Wagner HD (2015) Fast growth of carbon nanotubes using a microwave oven. Carbon 82:327–336. https://doi.org/10.1016/j.carbon.2014.10.077 CrossRef

Liu Z, Wang J, Kushvaha V et al (2011) Poptube approach for ultrafast carbon nanotube growth. Chem Commun 47:9912–9914. https://doi.org/10.1039/c1cc13359d CrossRef

10.

Worsley MA, Pauzauskie PJ, Olson TY et al (2010) Synthesis of graphene aerogel with high electrical conductivity. J Am Chem Soc 132:14067–14069. https://doi.org/10.1021/ja1072299 CrossRef

11.

Nardecchia S, Carriazo D, Ferrer ML et al (2013) Three dimensional macroporous architectures and aerogels built of carbon nanotubes and/or graphene: synthesis and applications. Chem Soc Rev 42:794–830. https://doi.org/10.1039/c2cs35353a CrossRef

12.

Bi H, Yin K, Xie X et al (2012) Low temperature casting of graphene with high compressive strength. Adv Mater 24:5124–5129. https://doi.org/10.1002/adma.201201519 CrossRef

13.

Park H, Kim JW, Hong SY et al (2018) Microporous polypyrrole-coated graphene foam for high-performance multifunctional sensors and flexible supercapacitors. Adv Func Mater 18:1707017-1–1707017-11. https://doi.org/10.1002/adfm.201707013 CrossRef

14.

Idowu A, Boesl B, Agarwal A (2018) 3D graphene foam-reinforced polymer composites—A review. Carbon 135:52–71. https://doi.org/10.1016/j.carbon.2018.04.024 CrossRef

15.

Chen G, Liu Y, Liu F, Zhang X (2014) Fabrication of three-dimensional graphene foam with high electrical conductivity and large adsorption capability. Appl Surf Sci 311:808–815. https://doi.org/10.1016/j.apsusc.2014.05.171 CrossRef

16.

Woodward RT, Fam DWH, Anthony DB et al (2016) Hierarchically porous carbon foams from pickering high internal phase emulsions. Carbon 101:253–260. https://doi.org/10.1016/j.carbon.2016.02.002 CrossRef

17.

Silverstein MS (2014) PolyHIPEs: recent advances in emulsion-templated porous polymers. Prog Polym Sci 39:199–234. https://doi.org/10.1016/j.progpolymsci.2013.07.003 CrossRef

18.

Sun T, Zhang Z, Xiao J et al (2013) Facile and green synthesis of palladium nanoparticles-graphene-carbon nanotube material with high catalytic activity. Sci Rep 3:1–6. https://doi.org/10.1038/srep02527 CrossRef

19.

Bai Y, Du M, Chang J et al (2014) Supercapacitors with high capacitance based on reduced graphene oxide/carbon nanotubes/NiO composite electrodes. J Mater Chem A 2:3834–3840. https://doi.org/10.1039/C3TA15004F CrossRef

20.

Zhang Y, Wang Z, Ji Y et al (2015) Synthesis of Ag nanoparticle–carbon nanotube–reduced graphene oxide hybrids for highly sensitive non-enzymatic hydrogen peroxide detection. RSC Advances 5:39037–39041. https://doi.org/10.1039/C5RA04246A CrossRef

21.

Choi CH, Chung MW, Kwon HC et al (2014) Nitrogen-doped graphene/carbon nanotube self-assembly for efficient oxygen reduction reaction in acid media. Appl Catal B 144:760–766. https://doi.org/10.1016/j.apcatb.2013.08.021 CrossRef

22.

Sridhar V, Lee I, Chun HH, Park H (2015) Microwave synthesis of nitrogen-doped carbon nanotubes anchored on graphene substrates. Carbon 87:186–192. https://doi.org/10.1016/j.carbon.2015.01.063 CrossRef

23.

Li Z, Yang B, Su Y et al (2016) Ultrafast growth of carbon nanotubes on graphene for capacitive energy storage. Nanotechnology 27:1707017-1–1707017-10. https://doi.org/10.1088/0957-4484/27/2/025401 CrossRef

24.

Algadri NA, Hassan Z, Ibrahim K, Bououdina M (2017) Effect of ferrocene catalyst particle size on structural and morphological characteristics of carbon nanotubes grown by microwave oven. J Mater Sci 52:12772–12782. https://doi.org/10.1007/s10853-017-1381-2 CrossRef

25.

Yoon B-J, Hong EH, Jee SE et al (2005) Fabrication of flexible carbon nanotube field emitter arrays by direct microwave irradiation on organic polymer substrate. J Am Chem Soc 127:8234–8235. https://doi.org/10.1021/ja043823n CrossRef

26.

Hong EH, Lee K-H, Oh SH, Park C-G (2003) Synthesis of carbon nanotubes using microwave radiation. Adv Func Mater 13:961–966. https://doi.org/10.1002/adfm.200304396 CrossRef

27.

Zhang X, Liu Z (2012) Recent advances in microwave initiated synthesis of nanocarbon materials. Nanoscale 4:707–714. https://doi.org/10.1039/C2NR11603K CrossRef

28.

Nie H, Cui M, Russell TP (2013) A route to rapid carbon nanotube growth. Chem Commun 49:5159. https://doi.org/10.1039/c3cc41746h CrossRef

29.

Bibi S, Ullah H, Ahmad SM et al (2015) Molecular and electronic structure elucidation of polypyrrole gas sensors. J Phys Chem C 119:15994–16003. https://doi.org/10.1021/acs.jpcc.5b03242 CrossRef

30.

Li Y, Ye D, Liu W et al (2017) A three-dimensional core-shell nanostructured composite of polypyrrole wrapped MnO₂/reduced graphene oxide/carbon nanotube for high performance lithium ion batteries. J Colloid Interface Sci 493:241–248. https://doi.org/10.1016/j.jcis.2017.01.008 CrossRef

31.

Peng YJ, Wu TH, Hsu CT et al (2014) Electrochemical characteristics of the reduced graphene oxide/carbon nanotube/polypyrrole composites for aqueous asymmetric supercapacitors. J Power Sources 272:970–978. https://doi.org/10.1016/j.jpowsour.2014.09.022 CrossRef

32.

Ding B, Lu X, Yuan C et al (2012) One-step electrochemical composite polymerization of polypyrrole integrated with functionalized graphene/carbon nanotubes nanostructured composite film for electrochemical capacitors. Electrochim Acta 62:132–139. https://doi.org/10.1016/j.electacta.2011.12.011 CrossRef

33.

Zhou H, Zhai HJ (2016) A highly flexible solid-state supercapacitor based on the carbon nanotube doped graphene oxide/polypyrrole composites with superior electrochemical performances. Organic Electronics: physics, materials, applications 37:197–207. https://doi.org/10.1016/j.orgel.2016.06.036 CrossRef

34.

Yan M, Vetter CA, Gelling VJ (2013) Corrosion inhibition performance of polypyrrole Al flake composite coatings for Al alloys. Corros Sci 70:37–45. https://doi.org/10.1016/j.corsci.2012.12.019 CrossRef

35.

Hojjat Ansari M, Basiri Parsa J, Arjomandi J (2017) Application of conducting polyaniline, o-anisidine, o-phenetidine and o-chloroaniline in removal of nitrate from water via electrically switching ion exchange: modeling and optimization using a response surface methodology. Sep Purif Technol 179:104–117. https://doi.org/10.1016/j.seppur.2017.02.002 CrossRef

36.

Bora C, Dolui SK (2012) Fabrication of polypyrrole/graphene oxide nanocomposites by liquid/liquid interfacial polymerization and evaluation of their optical, electrical and electrochemical properties. Polymer (UK) 53:923–932. https://doi.org/10.1016/j.polymer.2011.12.054 CrossRef

37.

Khamlich S, Barzegar F, Nuru ZY et al (2014) Polypyrrole/graphene nanocomposite: high conductivity and low percolation threshold. Synth Met 198:101–106. https://doi.org/10.1016/j.synthmet.2014.10.004 CrossRef

38.

Manivel P, Kanagaraj S, Balamurugan A, et al (2014) Rheological behavior—Electrical and thermal properties of polypyrrole/graphene oxide nanocomposites. J Appl Polym Sci. https://doi.org/10.1002/app.40642 CrossRef

39.

Omastová M, Trchova M, Kovarova J, Stejskal J (2003) Synthesis and structural study of polypyrrole prepared in the presence of surfactants. Synth Met 138:447–455. https://doi.org/10.1016/S0379-6779(02)00498-8 CrossRef

40.

Tabačiarová J, Mičušík M, Fedorko P, Omastová M (2015) Study of polypyrrole aging by XPS, FTIR and conductivity measurements. Polym Degrad Stab 120:392–401. https://doi.org/10.1016/j.polymdegradstab.2015.07.021 CrossRef

41.

Lu X, Zhang F, Dou H et al (2012) Preparation and electrochemical capacitance of hierarchical graphene/polypyrrole/carbon nanotube ternary composites. Electrochim Acta 69:160–166. https://doi.org/10.1016/j.electacta.2012.02.107 CrossRef

42.

Lu X, Dou H, Yuan C et al (2012) Polypyrrole/carbon nanotube nanocomposite enhanced the electrochemical capacitance of flexible graphene film for supercapacitors. J Power Sour 197:319–324. https://doi.org/10.1016/j.jpowsour.2011.08.112 CrossRef

43.

Zhou H, Zhai H-J, Zhi X (2018) Enhanced electrochemical performances of polypyrrole/carboxyl graphene/carbon nanotubes ternary composite for supercapacitors. Electrochim Acta 290:1–11. https://doi.org/10.1016/j.electacta.2018.09.039 CrossRef

44.

Wu TM, Chang HL, Lin YW (2009) Synthesis and characterization of conductive polypyrrole/multi-walled carbon nanotubes composites with improved solubility and conductivity. Compos Sci Technol 69:639–644. https://doi.org/10.1016/j.compscitech.2008.12.010 CrossRef

45.

Bose S, Kuila T, Uddin ME et al (2010) In-situ synthesis and characterization of electrically conductive polypyrrole/graphene nanocomposites. Polymer 51:5921–5928. https://doi.org/10.1016/j.polymer.2010.10.014 CrossRef

46.

Stejskal J, Omastová M, Fedorova S et al (2003) Polyaniline and polypyrrole prepared in the presence of surfactants: a comparative conductivity study. Polymer 44:1353–1358. https://doi.org/10.1016/S0032-3861(02)00906-0 CrossRef

47.

Rawal I, Kaur A (2014) Effect of anionic surfactant concentration on the variable range hopping conduction in polypyrrole nanoparticles. J Appl Phys https://doi.org/10.1063/1.4863179 CrossRef

48.

Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339. https://doi.org/10.1021/ja01539a017 CrossRef

49.

Li Z, Yao Y, Lin Z et al (2010) Ultrafast, dry microwave synthesis of graphene sheets. J Mater Chem 20:4781. https://doi.org/10.1039/c0jm00168f CrossRef

50.

Suarez-Martinez I, Grobert N, Ewels CP (2012) Nomenclature of sp ² carbon nanoforms. Carbon 50:741–747. https://doi.org/10.1016/j.carbon.2011.11.002 CrossRef

51.

Hsu FH, Wu TM (2012) In situ synthesis and characterization of conductive polypyrrole/graphene composites with improved solubility and conductivity. Synth Met 162:682–687. https://doi.org/10.1016/j.synthmet.2012.02.025 CrossRef

52.

Ivanova MV, Lamprecht C, Jimena Loureiro M et al (2012) Pharmaceutical characterization of solid and dispersed carbon nanotubes as nanoexcipients. Int J Nanomed 7:403–415. https://doi.org/10.2147/IJN.S27442 CrossRef

53.

Sharma P, Bhalla V, Dravid V et al (2012) Enhancing electrochemical detection on graphene oxide-CNT nanostructured electrodes using magneto-nanobioprobes. Scientific Reports 2:1–7. https://doi.org/10.1038/srep00877 CrossRef

54.

Wang X, Yang C, Li H, Liu P (2013) Synthesis and electrochemical performance of well-defined flake-shaped sulfonated graphene/polypyrrole composites via facile in situ doping polymerization. Electrochim Acta 111:729–737. https://doi.org/10.1016/j.electacta.2013.08.145 CrossRef

55.

Naikoo RA, Tomar R (2018) Fabrication of a novel zeolite-X/reduced graphene oxide/polypyrrole nanocomposite and its role in sensitive detection of CO. Mater Chem Phys 211:225–233. https://doi.org/10.1016/j.matchemphys.2018.02.021 CrossRef

56.

Wang R, Wang Y, Xu C et al (2013) Facile one-step hydrazine-assisted solvothermal synthesis of nitrogen-doped reduced graphene oxide: reduction effect and mechanisms. RSC Adv 3:1194–1200. https://doi.org/10.1039/c2ra21825a CrossRef

57.

Sanches EA, Alves SF, Soares JC, et al (2015) Nanostructured polypyrrole powder: a structural and morphological characterization. J Nanomater. https://doi.org/10.1155/2015/129678 CrossRef

58.

Asghari E, Ashassi-Sorkhabi H, Charmi GR et al (2016) A facile electrochemical strategy for synthesis of 3D nanodimensional polypyrrole structures using self-assembled layers of pyrrole monomers. Prog Org Coat 101:130–141. https://doi.org/10.1016/j.porgcoat.2016.07.015 CrossRef

59.

Machida S, Miyata S, Techagumpuch A (1989) Chemical synthesis of highly electrically conductive polypyrrole. Synth Met 31:311–318. https://doi.org/10.1016/0379-6779(89)90798-4 CrossRef

60.

Lu X, Dou H, Yang S et al (2011) Fabrication and electrochemical capacitance of hierarchical graphene/polyaniline/carbon nanotube ternary composite film. Electrochim Acta 56:9224–9232. https://doi.org/10.1016/j.electacta.2011.07.142 CrossRef

61.

Zhang D, Zhang X, Chen Y et al (2011) Enhanced capacitance and rate capability of graphene/polypyrrole composite as electrode material for supercapacitors. J Power Sour 196:5990–5996. https://doi.org/10.1016/j.jpowsour.2011.02.090 CrossRef

62.

Tian B, Zerbi G (1990) Lattice dynamics and vibrational spectra of polypyrrole. J Chem Phys 92:3886–3891. https://doi.org/10.1063/1.457794 CrossRef

63.

Tian B, Zerbi G (1990) Lattice dynamics and vibrational spectra of pristine and doped polypyrrole: effective conjugation coordinate. J Chem Phys 92:3892–3898. https://doi.org/10.1063/1.457795 CrossRef

64.

Zhong J, Gao S, Xue G, Wang B (2015) Study on enhancement mechanism of conductivity induced by graphene oxide for Polypyrrole nanocomposites. Macromolecules 48:1592–1597. https://doi.org/10.1021/ma502449k CrossRef

65.

Lei J, Cai Z, Martin CR (1992) Effect of reagent concentrations used to synthesize polypyrrole on the chemical characteristics and optical and electronic properties of the resulting polymer. Synthetic Metals 46:53–69. https://doi.org/10.1016/0379-6779(92)90318-D CrossRef

66.

Gao YS, Xu JK, Lu LM et al (2014) Overoxidized polypyrrole/graphene nanocomposite with good electrochemical performance as novel electrode material for the detection of adenine and guanine. Biosens Bioelectron 62:261–267. https://doi.org/10.1016/j.bios.2014.06.044 CrossRef

67.

Muller D, Rambo CR, Porto LM et al (2013) Structure and properties of polypyrrole/bacterial cellulose nanocomposites. Carbohyd Polym 94:655–662. https://doi.org/10.1016/j.carbpol.2013.01.041 CrossRef

68.

Truong VT (1992) Thermal degradation of polypyrrole: effect of temperature and film thickness. Synth Met 52:33–44. https://doi.org/10.1016/0379-6779(92)90017-D CrossRef

69.

Sahoo S, Karthikeyan G, Nayak GC, Das CK (2011) Electrochemical characterization of in situ polypyrrole coated graphene nanocomposites. Synth Met 161:1713–1719. https://doi.org/10.1016/j.synthmet.2011.06.011 CrossRef

70.

Zang L, Qiu J, Yang C, Sakai E (2016) Preparation and application of conducting polymer/Ag/clay composite nanoparticles formed by in situ UV-induced dispersion polymerization. Sci Rep 6:20470. https://doi.org/10.1038/srep20470 CrossRef

71.

Joo J, Lee JK, Lee SY et al (2000) Physical characterization of electrochemically and chemically synthesized polypyrroles. Macromolecules 33:5131–5136. https://doi.org/10.1021/ma991418o CrossRef

72.

Imran SM, Salman A, Shao GN et al (2016) Study of the electroconductive properties of conductive polymers-graphene/graphene oxide nanocomposites synthesized via in situ emulsion polymerization. Polym Polym Compos 16:101–113. https://doi.org/10.1002/pc.24179 CrossRef

73.

D. Fichou, G. Horowitz (2000) Molecular and polymer semiconductors, conductors, and superconductors: overview. Polymer. https://doi.org/10.1016/B0-08-043152-6/01000-7 CrossRef

Titel: Electroconductive performance of polypyrrole/reduced graphene oxide/carbon nanotube composites synthesized via in situ oxidative polymerization
verfasst von: Xuan Tin Tran
Sung Soo Park
Sinae Song
Muhammad Salman Haider
Syed Muhammad Imran
Manwar Hussain
Hee Taik Kim
Publikationsdatum: 25.10.2018
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 4/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-018-3043-4

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 4/2019

Mussel-inspired cotton fabric with pH-responsive superwettability for bidirectional oil–water separation

In situ synthesis of energetic metal–organic frameworks [Cd5(Mtta)9]n film exhibiting excellent ignition capability

Dynamic crack propagation behaviors of calcium carbonate: aragonite

Effect of biomass on reaction performance of sintering fuel

Investigation on the melting and crystallization behaviors, mechanical properties and morphologies of polypropylene/sericite composites

LaF3: Pr3+ hollow hexagon nanostructures via green and eco-friendly synthesis and their photoluminescence properties

Premium Partner

Marktübersichten