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Erschienen in: Journal of Materials Science 17/2017

30.05.2017 | Ceramics

Enhanced electrical energy storage properties in La-doped (Bi0.5Na0.5)0.93Ba0.07TiO3 lead-free ceramics by addition of La2O3 and La(NO3)3

verfasst von: Jiwen Xu, Xiaopeng Lu, Ling Yang, Changrong Zhou, Yangyang Zhao, Haibo Zhang, Xiaowen Zhang, Wei Qiu, Hua Wang

Erschienen in: Journal of Materials Science | Ausgabe 17/2017

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Abstract

Lead-free [(Bi0.5Na0.5)0.93Ba0.07]1−x La x TiO3 (BNBLT) ceramics for energy storage application were prepared by traditional solid-state reaction technique, and the La3+ ions doping content was varied at 0 ≤ x ≤ 0.04. The BNBLT ceramics showed single-phase perovskite structure without impurity phase. Compact and uniform microstructure with fine grain size was obtained. The remanent polarization and coercive field decreased with the increase in La3+ ions doping content, and the energy storage density increased drastically. The maximum energy storage density of the BNBLT ceramics at x = 0.04 was 1.09 J/cm3 by using La2O3 powders and can be further increased to 1.21 J/cm3 using La(NO3)3 powders, and meanwhile, the breakdown field strength increased obviously. Anti-ferroelectric-like behavior with a double pinched PE hysteresis loop was observed in La3+-doped BNBLT ceramics at room temperature, which is promising candidate for energy storage dielectric ceramic.

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Metadaten
Titel
Enhanced electrical energy storage properties in La-doped (Bi0.5Na0.5)0.93Ba0.07TiO3 lead-free ceramics by addition of La2O3 and La(NO3)3
verfasst von
Jiwen Xu
Xiaopeng Lu
Ling Yang
Changrong Zhou
Yangyang Zhao
Haibo Zhang
Xiaowen Zhang
Wei Qiu
Hua Wang
Publikationsdatum
30.05.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 17/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1209-0

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