nach oben

Topics in Catalysis

Erschienen in:

12.02.2020 | Original Paper

Ethanol Conversion to Short-Chain Olefins Over ZSM-5 Zeolite Catalysts Enhanced with P, Fe, and Ni

verfasst von: Ricardo H. Gil-Horán, Juan C. Chavarría-Hernández, Patricia Quintana-Owen, Aída Gutiérrez-Alejandre

Erschienen in: Topics in Catalysis | Ausgabe 5-6/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

The ethanol dehydration and subsequent ethylene oligomerization to short-chain olefins using catalysts based on ZSM-5 zeolite was studied in detail. P, Fe, and Ni were added by incipient wetness impregnation on zeolites with two SiO₂/Al₂O₃ molar ratios (50 and 80). The catalysts were characterized by N₂ adsorption–desorption, XRD, SEM–EDX, FTIR spectroscopy of adsorbed pyridine, and XPS techniques, while the catalytic activity was evaluated using an isothermal fixed-bed reactor. The impregnation of P, Fe, and Ni significantly improved the formation of the desired C₃₊ olefins (olefins having three or more C atoms). Particularly, the zeolite with SiO₂/Al₂O₃ molar ratio = 50 and impregnated with P, exhibited the highest selectivity (C₃₊ olefins > 45 wt% at TOS = 5 h) in comparison with the rest of the evaluated catalysts. On the contrary, catalysts with SiO₂/Al₂O₃ molar ratio = 80 showed lower selectivity to C₃₊ olefins, producing more side products (i.e. paraffins, aromatics and diethyl-ether).

Vorheriger Artikel VII International Congress & XVI Mexican Congress on Catalysis: CMC 2019 “Catalysis: Effective Synergy for the Processing Industry”

Nächster Artikel Selective Vanillin Hydrodeoxygenation on Synthetic Takovite Derived NiAlOx Mixed Oxide

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Lu J, Liu Y (2011) J Nat Gas Chem 20(2):162–166. https://doi.org/10.1016/S1003-9953(10)60163-6CrossRef

Inaba M, Murata K, Saito M, Takahara I (2007) Green Chem 9(6):638–646. https://doi.org/10.1039/B614157ACrossRef

Galadima A, Muraza O (2015) J Ind Eng Chem 31:1–14. https://doi.org/10.1016/j.jiec.2015.07.015CrossRef

Cherubini F (2010) Ener Convers Manage 51(7):1412–1421. https://doi.org/10.1016/j.enconman.2010.01.015CrossRef

Li X, Kant A, He Y, Thakkar HV, Atanga MA, Rezaei F, Ludlow DK, Rownaghi AA (2016) Catal Today 276:62–77. https://doi.org/10.1016/j.cattod.2016.01.038CrossRef

Renewable Fuels Association (2018) World fuel ethanol production. https://ethanolrfa.org/statistics/annual-ethanol-production/. Accessed 20 June 2019

Sousa ZSB, Veloso CO, Henriques CA, Teixeira da Silva V (2016) J Mol Catal a-Chem 422:266–274. https://doi.org/10.1016/j.molcata.2016.03.005CrossRef

Kondo JN, Ito K, Yoda E, Wakabayashi F, Domen K (2005) J Phys Chem B 109(21):10969–10972. https://doi.org/10.1021/jp050721qCrossRefPubMed

Zhang X, Wang R, Yang X, Zhang F (2008) Micropor Mesopor Mat 116(1–3):210–215. https://doi.org/10.1016/j.micromeso.2008.04.004CrossRef

10.

Nash CP, Ramanathan A, Ruddy DA, Behl M, Gjersing E, Griffin M, Zhu H, Subramaniam B, Schaidle JA, Hensley JE (2016) Appl Catal A-Gen 510:110–124. https://doi.org/10.1016/j.apcata.2015.11.019CrossRef

11.

Madeira FF, Gnep NS, Magnoux P, Maury S, Cadran N (2009) Appl Catal A-Gen 367(1–2):39–46. https://doi.org/10.1016/j.apcata.2009.07.033CrossRef

12.

Zhang D, Wang R, Yang X (2008) Catal Lett 124(3):384–391. https://doi.org/10.1007/s10562-008-9481-xCrossRef

13.

Lu J, Liu Y, Li N (2011) J Nat Gas Chem 20(4):423–427. https://doi.org/10.1016/S1003-9953(10)60193-4CrossRef

14.

Goto D, Harada Y, Furumoto Y, Takahashi A, Fujitani T, Oumi Y, Sadakane M, Sano T (2010) Appl Catal A-Gen 383(1–2):89–95. https://doi.org/10.1016/j.apcata.2010.05.032CrossRef

15.

Takahashi A, Xia W, Nakamura I, Shimada H, Fujitani T (2012) Appl Catal A-Gen 423 (Supplement C):162–167. https://doi.org/10.1016/j.apcata.2012.02.029CrossRef

16.

Song Z, Takahashi A, Mimura N, Fujitani T (2009) Catal Lett 131(3):364–369. https://doi.org/10.1007/s10562-009-0071-3CrossRef

17.

Song Z, Takahashi A, Nakamura I, Fujitani T (2010) Appl Catal A-Gen 384(1–2):201–205. https://doi.org/10.1016/j.apcata.2010.06.035CrossRef

18.

Inaba M, Murata K, Takahara I (2009) React Kinet Catal Lett 97(1):19–26. https://doi.org/10.1007/s11144-009-0002-8CrossRef

19.

Inaba M, Murata K, Takahara I, Inoue K (2011) J Chem Technol Biotechnol 86(1):95–104. https://doi.org/10.1002/jctb.2519CrossRef

20.

Inaba M, Murata K, Takahara I, Inoue K (2012) Adv Mater Sci Eng 2012:7. https://doi.org/10.1155/2012/293485CrossRef

21.

Gayubo AG, Alonso A, Valle B, Aguayo AT, Bilbao J (2010) Appl Catal B-Environ 97(1–2):299–306. https://doi.org/10.1016/j.apcatb.2010.04.021CrossRef

22.

Furumoto Y, Harada Y, Tsunoji N, Takahashi A, Fujitani T, Ide Y, Sadakane M, Sano T (2011) Appl Catal A-Gen 399(1):262–267. https://doi.org/10.1016/j.apcata.2011.04.009CrossRef

23.

Ouyang J, Kong F, Su G, Hu Y, Song Q (2009) Catal Lett 132(1):64–74. https://doi.org/10.1007/s10562-009-0047-3CrossRef

24.

Tretyakov VF, Makarfi YI, Tretyakov KV, Frantsuzova NA, Talyshinskii RM (2010) Catal ind 2(4):402–420. https://doi.org/10.1134/s2070050410040161CrossRef

25.

Makarfi YI, Yakimova MS, Lermontov AS, Erofeev VI, Koval LM, Tretiyakov VF (2009) Chem Eng J 154(1–3):396–400. https://doi.org/10.1016/j.cej.2009.06.001CrossRef

26.

Gayubo AG, Alonso A, Valle B, Aguayo AT, Olazar M, Bilbao J (2010) Fuel 89(11):3365–3372. https://doi.org/10.1016/j.fuel.2010.03.002CrossRef

27.

Phung TK, Radikapratama R, Garbarino G, Lagazzo A, Riani P, Busca G (2015) Fuel Process Technol 137:290–297. https://doi.org/10.1016/j.fuproc.2015.03.012CrossRef

28.

Van der Borght K, Galvita VV, Marin GB (2015) Appl Catal A-Gen 492:117–126. https://doi.org/10.1016/j.apcata.2014.12.020CrossRef

29.

Leofanti G, Padovan M, Tozzola G, Venturelli B (1998) Catal Today 41(1):207–219. https://doi.org/10.1016/S0920-5861(98)00050-9CrossRef

30.

McCue AJ, Mutch GA, McNab AI, Campbell S, Anderson JA (2016) Catal Today 259:19–26. https://doi.org/10.1016/j.cattod.2015.03.039CrossRef

31.

Pieta IS, Ishaq M, Wells RPK, Anderson JA (2010) Appl Catal A-Gen 390(1):127–134. https://doi.org/10.1016/j.apcata.2010.10.001CrossRef

32.

Emeis CA (1993) J Catal 141(2):347–354. https://doi.org/10.1006/jcat.1993.1145CrossRef

33.

Barzetti T, Selli E, Moscotti D, Forni L (1996) J Chem Soc. Faraday Trans 92(8):1401–1407. https://doi.org/10.1039/FT9969201401CrossRef

34.

Li X, Han D, Wang H, Liu G, Wang B, Li Z, Wu J (2015) Fuel 144:9–14. https://doi.org/10.1016/j.fuel.2014.12.005CrossRef

35.

Haw JF (2002) Phys Chem Chem Phys 4(22):5431–5441. https://doi.org/10.1039/B206483ACrossRef

36.

Singh R, Dutta PK (2003) MFI: a case study of zeolite synthesis. In: Auerbach SM, Carrado KA, Dutta PK (eds) Handbook of zeolite science and technology. Marcel Dekker, Inc., New York. https://doi.org/10.1201/9780203911167

37.

Rasouli M, Atashi H, Mohebbi-Kalhori D, Yaghobi N (2017) J Taiwan Inst Chem E 78:438–446. https://doi.org/10.1016/j.jtice.2017.05.018CrossRef

38.

Armaroli T, Simon LJ, Digne M, Montanari T, Bevilacqua M, Valtchev V, Patarin J, Busca G (2006) Appl Catal A-Gen 306:78–84. https://doi.org/10.1016/j.apcata.2006.03.030CrossRef

39.

Biesinger MC, Payne BP, Grosvenor AP, Lau LWM, Gerson AR, Smart RSC (2011) Appl Surf Sci 257(7):2717–2730. https://doi.org/10.1016/j.apsusc.2010.10.051CrossRef

40.

Yamashita T, Hayes P (2008) Appl Surf Sci 254(8):2441–2449. https://doi.org/10.1016/j.apsusc.2007.09.063CrossRef

41.

Grosvenor AP, Kobe BA, Biesinger MC, McIntyre NS (2004) Surf Interface Anal 36(12):1564–1574. https://doi.org/10.1002/sia.1984CrossRef

42.

Kraushofer F, Jakub Z, Bichler M, Hulva J, Drmota P, Weinold M, Schmid M, Setvin M, Diebold U, Blaha P, Parkinson GS (2018) J Phys Chem C 122(3):1657–1669. https://doi.org/10.1021/acs.jpcc.7b10515CrossRef

43.

Mansour AN, Brizzolara RA (1996) Surf Sci Spectra 4(4):351–356. https://doi.org/10.1116/1.1247832CrossRef

44.

Mansour AN (1994) Surf Sci Spectra 3(3):231–238. https://doi.org/10.1116/1.1247751CrossRef

45.

Wang Y, Sherwood PMA (2002) Surf Sci Spectra 9(1):159–165. https://doi.org/10.1116/11.20030115CrossRef

46.

Sherwood PMA (2002) Surf Sci Spectra 9(1):62–66. https://doi.org/10.1116/11.20030101CrossRef

47.

Blasco T, Corma A, Martínez-Triguero J (2006) J Catal 237(2):267–277. https://doi.org/10.1016/j.jcat.2005.11.011CrossRef

48.

Zhuang J, Ma D, Yang G, Yan Z, Liu X, Liu X, Han X, Bao X, Xie P, Liu Z (2004) J Catal 228(1):234–242. https://doi.org/10.1016/j.jcat.2004.08.034CrossRef

49.

Marques JP, Gener I, Ayrault P, Bordado JC, Lopes JM, Ramôa Ribeiro F, Guisnet M (2003) Micropor Mesopor Mat 60(1):251–262. https://doi.org/10.1016/S1387-1811(03)00382-2CrossRef

50.

Busca G (2017) Micropor Mesopor Mat 254:3–16. https://doi.org/10.1016/j.micromeso.2017.04.007CrossRef

51.

Suganuma S, Nakamura K, Okuda A, Katada N (2017) Mol Catal 435:110–117. https://doi.org/10.1016/j.mcat.2017.03.029CrossRef

52.

Aguayo AT, Gayubo AG, Atutxa A, Olazar M, Bilbao J (2002) Ind Eng Chem Res 41(17):4216–4224. https://doi.org/10.1021/ie020068iCrossRef

53.

Ferreira Madeira F, Gnep NS, Magnoux P, Vezin H, Maury S, Cadran N (2010) Chem Eng J 161(3):403–408. https://doi.org/10.1016/j.cej.2010.01.026CrossRef

54.

Song Y, Zhang L, Li G, Shang Y, Zhao X, Ma T, Zhang L, Zhai Y, Gong Y, Xu J, Deng F (2017) Fuel Process Technol 168:105–115. https://doi.org/10.1016/j.fuproc.2017.08.020CrossRef

Titel: Ethanol Conversion to Short-Chain Olefins Over ZSM-5 Zeolite Catalysts Enhanced with P, Fe, and Ni
verfasst von: Ricardo H. Gil-Horán
Juan C. Chavarría-Hernández
Patricia Quintana-Owen
Aída Gutiérrez-Alejandre
Publikationsdatum: 12.02.2020
Verlag: Springer US
Erschienen in: Topics in Catalysis / Ausgabe 5-6/2020
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI: https://doi.org/10.1007/s11244-020-01229-8

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 5-6/2020

Selective Vanillin Hydrodeoxygenation on Synthetic Takovite Derived NiAlOx Mixed Oxide

Effect of Gold Nanoparticles on MnOx/TiO2 Nanostructures for Improving the CO Oxidation at Low Temperature

Synthesis of 10 and 12 Ring Zeolites (MCM-22, TNU-9 and MCM-68) Modified with Zn and Its Potential Application in the Reaction of Methanol to Light Aromatics and Olefins

Synthesis and Characterization of Aluminophosphates Type-5 and 36 Doubly Modified with Si and Zn and Its Catalytic Application in the Reaction of Methanol to Hydrocarbons (MTH)

Dispersed Nickel-Based Catalyst for Enhanced Oil Recovery (EOR) Under Limited Hydrogen Conditions

Photocatalytic Degradation of 2,4-Dichlorophenol on NiAl-Mixed Oxides Derivatives of Activated Layered Double Hydroxides

Premium Partner

Marktübersichten