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Journal of Materials Science
Erschienen in: Journal of Materials Science 23/2018

30.07.2018 | Polymers

Free volume characteristics on water permeation and salt rejection of polyamide reverse osmosis membranes investigated by a pulsed slow positron beam

verfasst von: Jingjing Li, Bangyun Xiong, Chongshan Yin, Xiaowei Zhang, Yawei Zhou, Zheng Wang, Pengfei Fang, Chunqing He

Erschienen in: Journal of Materials Science | Ausgabe 23/2018

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Abstract

Polyamide thin film composite reverse osmosis membranes on porous polysulfone support were prepared using m-phenylenediamine, trimesoyl chloride and dimethyl sulfoxide (DMSO) with various contents as precursors via an interfacial polymerization. The membrane with heterogeneous multilayer structure was depth-profiled by positron annihilation lifetime spectroscopy based on a pulsed slow positron beam and the thickness of the polyamide active layer can be estimated through fitting the results of depth dependence of o-Ps intensity. The free volume characteristics in the polyamide selective layer of the membranes were evaluated and were correlated with the permeation properties. With increasing DMSO content, mean free volume size (VFV) was enlarged, which was responsible for the enhanced water and sodium chloride permeation. However, the salt rejection was significantly decreased with a slight increase in the VFV around a critical value of 88.0 Å3, which was the average size of hydrated sodium and chloride ions. It was well interpreted for that the broadened free volume distribution enables an amount of larger free volumes to be involved in the salt permeation, although little change in VFV was found.
Vorheriger Artikel Ultrathin alumina membranes for the fabrication of blackberry-like gold nanostructure arrays
Nächster Artikel The effect of filler localization on morphology and thermal conductivity of the polyamide/cyclic olefin copolymer blends filled with boron nitride

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Literatur
1.
Cadotte JE, Petersen RJ, Larson RE, Erickson EE (1980) A new thin-film composite seawater reverse osmosis membrane. Desalination 32:25–31CrossRef
2.
Xu GR, Xu JM, Feng HJ, Zhao HL, Wu SB (2017) Tailoring structures and performance of polyamide thin film composite (PA-TFC) desalination membranes via sublayers adjustment—a review. Desalination 417:19–35CrossRef
3.
Liu Q, Xu G-R (2016) Graphene oxide (GO) as functional material in tailoring polyamide thin film composite (PA-TFC) reverse osmosis (RO) membranes. Desalination 394:162–175CrossRef
4.
Park HB, Kamcev J, Robeson LM, Elimelech M, Freeman BD (2017) Maximizing the right stuff: the trade-off between membrane permeability and selectivity. Science 356:0530CrossRef
5.
Stevens DM, Shu JY, Reichert M, Roy A (2017) Next-generation nanoporous materials: progress and prospects for reverse osmosis and nanofiltration. Ind Eng Chem Res 56:10526–10551CrossRef
6.
Yang H, Wu H, Yao Z, Shi B, Xu Z, Cheng X, Pan F, Liu G et al (2018) Functionally graded membranes from nanoporous covalent organic frameworks for highly selective water permeation. J Mater Chem A 6:583–591CrossRef
7.
8.
Zhao L, Chang PCY, Ho WSW (2013) High-flux reverse osmosis membranes incorporated with hydrophilic additives for brackish water desalination. Desalination 308:225–232CrossRef
9.
Tung KL, Jean YC, Nanda D, Lee KR, Hung WS, Lo CH, Lai JY (2009) Characterization of multilayer nanofiltration membranes using positron annihilation spectroscopy. J Membr Sci 343:147–156CrossRef
10.
Hung WS, De Guzman M, Huang SH, Lee KR, Jean YC, Lai JY (2010) Characterizing free volumes and layer structures in asymmetric thin-film polymeric membranes in the wet condition using the variable monoenergy slow positron beam. Macromolecules 43:6127–6134CrossRef
11.
Wei T, Zhang L, Zhao H, Ma H, Sajib MS, Jiang H, Murad S (2016) Aromatic polyamide reverse-osmosis membrane: an atomistic molecular dynamics simulation. J Phys Chem B 120:10311–10318CrossRef
12.
Mao W, Xiong B, Liu Y, He C (2013) Correlation between defects and conductivity of Sb-doped tin oxide thin films. Appl Phys Lett 103:031915CrossRef
13.
Ohrt C, Rätzke K, Oshima N, Kobayashi Y, O’Rourke BE, Suzuki R, Uedono A, Faupel F (2015) Free volume profiles at polymer–solid interfaces probed by focused slow positron beam. Macromolecules 48:1493–1498CrossRef
14.
Yin C, Wang L, Li J, Zhou Y, Zhang H, Fang P, He C (2017) Positron annihilation characteristics, water uptake and proton conductivity of composite Nafion membranes. Phys Chem Chem Phys 19:15953–15961CrossRef
15.
Xia R, Cao X, Gao M, Zhang P, Zeng M, Wang B, Wei L (2017) Probing sub-nano level molecular packing and correlated positron annihilation characteristics of ionic cross-linked chitosan membranes using positron annihilation spectroscopy. Phys Chem Chem Phys 19:3616–3626CrossRef
16.
Fu YJ, Lai CL, Hu CC, Sun YM, Wu SY, Chen JT, Huang SH, Hung WS et al (2016) Extraordinary transport behavior of gases in isothermally annealed poly(4-methyl-1-pentene) membranes. J Polym Sci, Part B: Polym Phys 54:2368–2376CrossRef
17.
Yin C, Li J, Zhou Y, Zhang H, Fang P, He C (2018) Enhancement in proton conductivity and thermal stability in nafion membranes induced by incorporation of sulfonated carbon nanotubes. ACS Appl Mater Interfaces 10:14026–14035CrossRef
18.
19.
Yin C, Li J, Zhou Y, Zhang H, Fang P, He C (2018) Phase separation and development of proton transport pathways in metal oxide nanoparticle/nafion composite membranes during water uptake. J Phys Chem C 122:9710–9717CrossRef
20.
Tang X, Xiong B, Li Q, Mao W, Xiao W, Fang P, He C (2015) Development of pore interconnectivity/morphology in porous silica films investigated by cyclic voltammetry and slow positron annihilation spectroscopy. Electrochim Acta 168:365–369CrossRef
21.
He C, Wang S, Kobayashi Y, Ohdaira T, Suzuki R (2012) Role of pore morphology in positronium diffusion in mesoporous silica thin films and in positronium emission from the surfaces. Phys Rev B 86:075415CrossRef
22.
Japip S, Wang H, Xiao Y, Shung Chung T (2014) Highly permeable zeolitic imidazolate framework (ZIF)-71 nano-particles enhanced polyimide membranes for gas separation. J Membr Sci 467:162–174CrossRef
23.
Chen Z, Ito K, Yanagishita H, Oshima N, Suzuki R, Kobayashi Y (2011) Correlation study between free-volume holes and molecular separations of composite membranes for reverse osmosis processes by means of variable-energy positron annihilation techniques. J Phys Chem C 115:18055–18060CrossRef
24.
Fujioka T, Oshima N, Suzuki R, Price WE, Nghiem LD (2015) Probing the internal structure of reverse osmosis membranes by positron annihilation spectroscopy: gaining more insight into the transport of water and small solutes. J Membr Sci 486:106–118CrossRef
25.
Fujioka T, Oshima N, Suzuki R, Khan SJ, Roux A, Poussade Y, Drewes JE, Nghiem LD (2013) Rejection of small and uncharged chemicals of emerging concern by reverse osmosis membranes: the role of free volume space within the active skin layer. Sep Purif Technol 116:426–432CrossRef
26.
Albo J, Hagiwara H, Yanagishita H, Ito K, Tsuru T (2014) Structural characterization of thin-film polyamide reverse osmosis membranes. Ind Eng Chem Res 53:1442–1451CrossRef
27.
Kim SH, Kwak SY, Suzuki T (2005) Positron annihilation spectroscopic evidence to demonstrate the flux-enhancement mechanism in morphology-controlled thin-film-composite (TFC) membrane. Environ Sci Technol 39:1764–1770CrossRef
28.
Kim SJ, Kook S, O’Rourke BE, Lee J, Hwang M, Kobayashi Y, Suzuki R, Kim IS (2017) Characterization of pore size distribution (PSD) in cellulose triacetate (CTA) and polyamide (PA) thin active layers by positron annihilation lifetime spectroscopy (PALS) and fractional rejection (FR) method. J Membr Sci 527:143–151CrossRef
29.
Shen L, Zhang X, Zuo J, Wang Y (2017) Performance enhancement of TFC FO membranes with polyethyleneimine modification and post-treatment. J Membr Sci 534:46–58CrossRef
30.
Zhang S, Zhang R, Jean YC, Paul DR, Chung T-S (2012) Cellulose esters for forward osmosis: characterization of water and salt transport properties and free volume. Polymer 53:2664–2672CrossRef
31.
Li X, Chung TS (2013) Effects of free volume in thin-film composite membranes on osmotic power generation. AIChE J 59:4749–4761CrossRef
32.
Shi GM, Chen H, Jean YC, Chung TS (2013) Sorption, swelling, and free volume of polybenzimidazole (PBI) and PBI/zeolitic imidazolate framework (ZIF-8) nano-composite membranes for pervaporation. Polymer 54:774–783CrossRef
33.
Fan JJ, Zhou W, Wang Q, Chu ZJ, Yang LQ, Yang L, Sun J, Zhao L et al (2018) Structure dependence of water vapor permeation in polymer nanocomposite membranes investigated by positron annihilation lifetime spectroscopy. J Membr Sci 549:581–587CrossRef
34.
Tao SJ (1972) Positronium annihilation in molecular substances. J Chem Phys 56:5499–5510CrossRef
35.
Eldrup M, Lightbody D, Sherwood JN (1981) The temperature dependence of positron lifetimes in solid pivalic acid. Chem Phys 63:51–58CrossRef
36.
Consolati G, Panzarasa G, Quasso F (2018) Morphology of free volume holes in an amorphous polyether-polyester polyurethane of biomedical interest. Polym Test 68:208–212CrossRef
37.
Chen H, Hung WS, Lo C-H, Huang SH, Cheng ML, Liu G, Lee KR, Lai JY et al (2007) Free-volume depth profile of polymeric membranes studied by positron annihilation spectroscopy: layer structure from interfacial polymerization. Macromolecules 40:7542–7557CrossRef
38.
Geise GM, Paul DR, Freeman BD (2014) Fundamental water and salt transport properties of polymeric materials. Prog Polym Sci 39:1–42CrossRef
39.
Helfer F, Lemckert C, Anissimov YG (2014) Osmotic power with pressure retarded osmosis: theory, performance and trends—a review. J Membr Sci 453:337–358CrossRef
40.
Li X, Zhang S, Fu F, Chung T-S (2013) Deformation and reinforcement of thin-film composite (TFC) polyamide-imide (PAI) membranes for osmotic power generation. J Membr Sci 434:204–217CrossRef
41.
Marchetti P, Jimenez Solomon MF, Szekely G, Livingston AG (2014) Molecular separation with organic solvent nanofiltration: a critical review. Chem Rev 114:10735–10806CrossRef
42.
Kirkegaard P, Eldrup M, Mogensen OE, Pedersen NJ (1981) Program system for analysing positron lifetime spectra and angular correlation curves. Comput Phys Commun 23:307–335CrossRef
43.
Provencher SW (1982) CONTIN: a general purpose constrained regularization program for inverting noisy linear algebraic and integral equations. Comput Phys Commun 27:229–242CrossRef
44.
Gregory RB, Zhu Y (1990) Analysis of positron annihilation lifetime data by numerical laplace inversion with the program CONTIN. Nucl Instrum Methods Phys Res, Sect A 290:172–182CrossRef
45.
Kobayashi Y, Ito K, Oka T, He C, Mohamed HFM, Suzuki R, Ohdaira T (2008) Application of positron beams to the study of positronium-forming solids. Appl Surf Sci 255:174–178CrossRef
46.
Shantarovich VP, Bekeshev VG, Belov NA, Ronova IA, Nikolaev AY, Gustov VW, Kevdina IB, Filimonov MK (2016) Effect of supercritical carbon dioxide on nanoporous polyhexafluoropropylene. High Energy Chem 50:287–291CrossRef
47.
Shantarovich VP, Bekeshev VG, Pastukhov AV, Davankov VA, Krasil’nikova OK, Belousova EV, Kevdina IB, Filimonov MK et al (2015) When some elementary free volumes in polymers are not seen by positron annihilation experiments. J Phys: Conf Ser 618:012021–012026
48.
Xie W, Ju H, Geise GM, Freeman BD, Mardel JI, Hill AJ, McGrath JE (2011) Effect of free volume on water and salt transport properties in directly copolymerized disulfonated poly(arylene ether sulfone) random copolymers. Macromolecules 44:4428–4438CrossRef
49.
David F, Vokhmin V, Ionova G (2001) Water characteristics depend on the ionic environment. Thermodynamics and modelisation of the aquo ions. J Mol Liq 90:45–62CrossRef
50.
Cohen MH, Turnbull D (1959) Molecular transport in liquids and glasses. J Chem Phys 31:1164–1169CrossRef
51.
Patil PN, Roilo D, Brusa RS, Miotello A, Aghion S, Ferragut R, Checchetto R (2016) Free volumes and gas transport in polymers: amine-modified epoxy resins as a case study. Phys Chem Chem Phys 18:3817–3824CrossRef
52.
Kobayashi Y, Kazama S, Inoue K, Toyama T, Nagai Y, Haraya K, Mohamed HF, O’Rouke BE et al (2014) Positron annihilation in cardo-based polymer membranes. J Phys Chem B 118:6007–6014CrossRef
53.
Mohamed HFM, Abdel-Hady EE, Ohira A (2015) Per-fluorinated sulfonic acid/PTFE copolymer studied by positron annihilation lifetime and gas permeation techniques. J Phys: Conf Ser 618:012031–012034
54.
Pendergast MM, Ghosh AK, Hoek EMV (2013) Separation performance and interfacial properties of nanocomposite reverse osmosis membranes. Desalination 308:180–185CrossRef
55.
Peng F, Jiang Z, Hoek EMV (2011) Tuning the molecular structure, separation performance and interfacial properties of poly(vinyl alcohol)–polysulfone interfacial composite membranes. J Membr Sci 368:26–33CrossRef
56.
Jean YC, Hung WS, Lo CH, Chen H, Liu G, Chakka L, Cheng ML, Nanda D et al (2008) Applications of positron annihilation spectroscopy to polymeric membranes. Desalination 234:89–98CrossRef
57.
Liu J, Jean YC, Yang H (1995) Free-volume hole properties of polymer blends probed by positron annihilation spectroscopy: miscibility. Macromolecules 28:5774–5779CrossRef
58.
Deng Q, Jean YC (1993) Free-volume distributions of an epoxy polymer probed by positron annihilation: pressure dependence. Macromolecules 26:30–34CrossRef
59.
Zhou J, Lu X, Wang Y, Shi J (2002) Molecular dynamics study on ionic hydration. Fluid Phase Equilib 194–197:257–270CrossRef
60.
Singh PS, Ray P, Xie Z, Hoang M (2012) Synchrotron SAXS to probe cross-linked network of polyamide ‘reverse osmosis’ and ‘nanofiltration’ membranes. J Membr Sci 421–422:51–59CrossRef
61.
Ding M, Szymczyk A, Goujon F, Soldera A, Ghoufi A (2014) Structure and dynamics of water confined in a polyamide reverse-osmosis membrane: a molecular-simulation study. J Membr Sci 458:236–244CrossRef
62.
Kou J, Zhou X, Lu H, Wu F, Fan J (2014) Graphyne as the membrane for water desalination. Nanoscale 6:1865–1870CrossRef
63.
Wang J, Kingsbury RS, Perry LA, Coronell O (2017) Partitioning of alkali metal salts and boric acid from aqueous phase into the polyamide active layers of reverse osmosis membranes. Environ Sci Technol 51:2295–2303CrossRef
64.
Dlubek G, Redmann F, Krause-Rehberg R (2002) Humidity-induced plasticization and antiplasticization of polyamide 6: a positron lifetime study of the local free volume. J Appl Polym Sci 84:244–255CrossRef
Metadaten
Titel
Free volume characteristics on water permeation and salt rejection of polyamide reverse osmosis membranes investigated by a pulsed slow positron beam
verfasst von
Jingjing Li
Bangyun Xiong
Chongshan Yin
Xiaowei Zhang
Yawei Zhou
Zheng Wang
Pengfei Fang
Chunqing He
Publikationsdatum
30.07.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 23/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2740-3

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