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2016 | Buch

Fundamentals of Hydrogen Embrittlement

verfasst von: Michihiko Nagumo

Verlag: Springer Singapore

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This book is the first comprehensive treatment of hydrogen embrittlement of metallic materials, mainly of steels. The subject is increasingly important with regard to recent requirements for hydrogen energy equipment. Recent progress in revealing the nature of hydrogen embrittlement is remarkable, and this book provides students and researchers engaging in hydrogen problems with a comprehensive view of hydrogen embrittlement covering basic behaviors of hydrogen in materials and their various manifestations in degradation of mechanical properties. Previous studies are critically reviewed and recent advances including new ideas on the mechanism of embrittlement are presented. Emphases are put on experimental facts, but their meanings rather than phenomenological appearance are given particular attention. Experiments are noted on adopted conditions since the operating mechanism of hydrogen might differ by materials and environments. For theories, assumptions and premises employed are noted so as to examine their versatility. Because of the interdisciplinary nature of the subject, brief descriptions of fundamental ideas are presented when necessary.

Inhaltsverzeichnis

Frontmatter
Chapter 1. Solid Solution
Abstract
Basic properties of hydrogen in regular lattice are presented mainly for iron and austenitic stainless steels. Atomistic calculations of electronic states and the heat of formation are included.
Michihiko Nagumo
Chapter 2. Hydrogen Trapping and Its Detection
Abstract
Most hydrogen atoms are trapped in various lattice defects. Manifestations of trapping in the apparent hydrogen solubility and diffusivity are presented. Hydrogen thermal desorption analysis is described with particular attention to its proper use by situations. Partitions of hydrogen among different traps are described for both equilibrium and transient states. Recent techniques to visualize hydrogen distributions in metals are also presented.
Michihiko Nagumo
Chapter 3. Interactions of Hydrogen with Lattice Defects
Abstract
Interactions of hydrogen with various lattice defects are described. Binding energies, hydrogen effects on defect densities, fractional occupancies and trapping configurations are presented together with experimental methods to measure. Theoretical backgrounds and calculated values are also included.
Michihiko Nagumo
Chapter 4. Diffusion and Transport of Hydrogen
Abstract
The diffusion coefficients of hydrogen in metals are described together with measuring methods such as electrochemical permeation transients. The effects of diffusion process on diffusion coefficients are presented including stochastic treatments. Experimental bases for the hydrogen transport by dislocations are described.
Michihiko Nagumo
Chapter 5. Deformation Behaviors
Abstract
Hydrogen effects on elastic and plastic behaviors of iron and steels are reviewed for both macroscopic and microscopic observations. Effects of experimental conditions are noticed. Tentative explanations of the results and elastic/atomistic calculations of the dislocation mobility are described. The hydrogen-assisted cracking and hydrogen-enhanced localized plasticity models proposed as the mechanism of hydrogen embrittlement are presented.
Michihiko Nagumo
Chapter 6. Manifestations of Hydrogen Embrittlement
Abstract
Hydrogen degradation in mechanical properties at various testing methods is described. Degradation is expressed in diverse ways, and the effects of experimental conditions are noticed. Hydrogen effects in successive stages leading to fracture are paid attention. Along with phenomenological behaviors, analyses and some model experiments devised to reveal the origin of degradation and the function of hydrogen are presented.
Michihiko Nagumo
Chapter 7. Characteristic Features of Deformation and Fracture in Hydrogen Embrittlement
Abstract
Characteristic features of hydrogen embrittlement that appear in various testing methods are systematically described so as to envisage common functions of hydrogen in failure. The phenomena are diverse, but particular attention is paid to features that appear in processes leading to final fracture. The utilizations of various experimental techniques such as TDA, PAS, TEM and EBSD are presented.
Michihiko Nagumo
Chapter 8. Effects of Microstructural Factors on Hydrogen Embrittlement
Abstract
Effects of microstructural factors on the susceptibility to hydrogen embrittlement in various testing methods are reviewed. Emphases are placed on characteristic features of fracture and deformation microstructures associated with observed degradation. Substructural alterations and the strain-induced creation of lattice defects are also remarked as related to degradation. Some parameters proposed to assess the susceptibility, like the critical hydrogen concentration, are presented.
Michihiko Nagumo
Chapter 9. Mechanistic Aspects of Fracture I ~ Brittle Fracture Models
Abstract
Brittle fracture models proposed as the mechanism of hydrogen embrittlement are presented. Basic notions on the crack instability and its criteria are explained. Hydrogen effects are included in parameters used in the criteria. Involvement of plasticity is crucial even for apparently brittle-like cases, and various expressions for effects of plasticity in the crack instability criteria are described.
Michihiko Nagumo
Chapter 10. Mechanistic Aspects of Fracture II ~ Plasticity-Dominated Fracture Models
Abstract
Plasticity-dominated models proposed as the mechanism of hydrogen embrittlement are presented together with a brief summary of basic notions of ductile fracture. Besides the origin of void nucleation and linking from microscopic aspects, constitutive relations are crucial for mechanistic aspects on plastic instability that leads to fracture. Hydrogen effects expressed as parameters in constitutive relations are described.
Michihiko Nagumo
Metadaten
Titel
Fundamentals of Hydrogen Embrittlement
verfasst von
Michihiko Nagumo
Copyright-Jahr
2016
Verlag
Springer Singapore
Electronic ISBN
978-981-10-0161-1
Print ISBN
978-981-10-0160-4
DOI
https://doi.org/10.1007/978-981-10-0161-1

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