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Journal of Materials Science

Erschienen in:

12.10.2018 | Composites

Graphene/phenolic resin-based porous carbon composites with improved conductivity prepared via in situ polymerization in graphene hydrogels

verfasst von: Guoping Yang, Yanhui Wang, Shuyu Zhou, Shaopei Jia, Hanqing Xu, Jianbing Zang

Erschienen in: Journal of Materials Science | Ausgabe 3/2019

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Abstract

Three-dimensional (3D) graphene/phenolic resin-based porous carbon composites with enhanced conductivity were prepared by carbonizing 3D graphene/phenolic resin composites and potassium hydroxide activation. The 3D graphene/phenolic resin composites were prepared via phenolic resin in situ polymerization in graphene hydrogels to protect the structure of 3D graphene. The prepared porous carbon composites exhibit an improved graphitization degree and enhanced conductivity by introducing 3D graphene. As supercapacitor electrode material, the electrochemical performance of the composite electrode materials was better than that of porous carbon prepared by pure phenolic resin due to the improved conductivity. The 3D graphene/phenolic resin-based porous carbon composite shows a high specific capacitance of 215.3 F g⁻¹ at 0.1 A g⁻¹, good rate capability of 72.9% in the range of 0.1–5 A g⁻¹ and excellent cycling stability (only 3.4% loss in specific capacitance after 5000 cycles). The method developed in this work would open up a new route to design and synthesize 3D graphene/porous carbon composites for a variety of applications like supercapacitors, catalysts and fuel cells.

Vorheriger Artikel Electrophoretic deposition of carbon nanotubes onto glass fibers for self-sensing relaxation-induced piezoresistivity of monofilament composites

Nächster Artikel Synthesis and thermal properties of a capric acid-modified expanded vermiculite phase change material

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Titel: Graphene/phenolic resin-based porous carbon composites with improved conductivity prepared via in situ polymerization in graphene hydrogels
verfasst von: Guoping Yang
Yanhui Wang
Shuyu Zhou
Shaopei Jia
Hanqing Xu
Jianbing Zang
Publikationsdatum: 12.10.2018
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 3/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-018-2983-z

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